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China Synchem Technology Co.,Ltd

Lumacaftor 3-(Tert-butoxycarbonyl)phenylboronic acid High purity Customization Our Key Technology: 1. Low Temperature Reactions 2. Coupling Reactions 3. Fluorine Chemistry 4. Asymmetric HydrogenationNot dang

3-(Tert-butoxycarbonyl)phenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

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Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3-tert-Butoxycarbonylphenylboronic acid Manufacturer/High quality/Best price/In stock

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 220210-56-0 3-tert-Butoxycarbonylphenylboronic acid Manufacturer

Cas:220210-56-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-(tert-Butoxycarbonyl)-benzeneboronic acid

Cas:220210-56-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/749.html Product Name 3-tert-Butoxycarbonylphenylboronic acid CAS No. 220210-56-

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $23.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM 3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-Tert-Butoxycarbonylphenylboronic Acid CAS 220210-56-0

Cas:220210-56-0

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 220210-56-0 with fast shipping

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam

3-tert-Butoxycarbonylphenylboronic acid CAS220210-56-0

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best s

3-tert-Butoxycarbonylphenylboronic Acid Manufacturer 220210-56-0

Cas:220210-56-0

Min.Order:10 Gram

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Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoic acid, 3-borono-, 1-(1,1-dimethylethyl) ester 220210-56-0

Cas:220210-56-0

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

3-tert-Butoxycarbonylphenylboronic acid CAS:220210-56-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high

3-tert-Butoxycarbonylphenylboronic acid CAS:220210-56-0

Cas:220210-56-0

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid, 3-borono-, 1-(1,1-dimethylethyl) ester

Cas:220210-56-0

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried

3-tert-Butoxycarbonylphenylboronic acid CAS NO.220210-56-0

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzoic acid, 3-borono-, 1-(1,1-dimethylethyl) ester

Cas:220210-56-0

Min.Order:0

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Type:Lab/Research institutions

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: 3-tert-Butoxycarbonylphenylboronic acid Synonyms: 3-(Tert-Butoxycarbonyl)Phenylb;3-(tert-Butoxycarbonyl)benzeneboronic acid 98%;3-(T-BUTOXYCARBONYL)PHENYLBORBONIC ACID;tert-Butyl 3-boronobenzoate;B2006G1;Benzoic acid, 3-borono-, 1-

Lumacaftor intermediate 3-tert-Butoxycarbonylphenylboronic acid Manufactory best quality

Cas:220210-56-0

Min.Order:100 Gram

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Triumph International Development Limilted

Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Air/Couri

3-(tert-Butoxycarbonyl)phenylboronic acid

Cas:220210-56-0

Min.Order:100 Metric Ton

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Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

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Taizhou Crene Biotechnology co.ltd

Our company provides one-stop services of research - development - production for a variety of special prouducts. Not only do we make effective use of our strong technological strength, but also establish of cooperative relations with several well-

3-t-Butoxycarbonylphenylboronic acid 220210-56-0

Cas:220210-56-0

Min.Order:100 Milligram

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Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:4 Kilogram

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Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-(tert-Butoxycarbonyl)phenylboronic acid

Cas:220210-56-0

Min.Order:0

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:100 Gram

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Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-tert-Butoxycarbonylphenylboronic acid/High quality/Best price

Cas:220210-56-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

3-tert-Butoxycarbonylphenylboronicacid

Cas:220210-56-0

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

3-tert-Butoxycarbonylphenylboronic acid Basic information Product Name: 3-tert-Butoxycarbonylphenylboronic acid Synonyms: T-BUTYL 3-BORONOBENZOATE;3-(T-BUTOXYCARBONYL)PHENYLBORONIC ACID;3-(TERT-BUTOXYCARBONYL)BENZENEBORONIC ACID;3-(TERT-BUTOXY

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3-tert-Butoxycarbonylphenylboronic acid

Cas:220210-56-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Synthetic route

3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

4-Bromo-1-naphthylamine
2298-07-9

4-Bromo-1-naphthylamine

tert-butyl 3-(4-aminonaphthalen-1-yl)benzoate

tert-butyl 3-(4-aminonaphthalen-1-yl)benzoate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In 1,4-dioxane; water at 90℃; for 4h;100%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

((1-(3-bromophenyl)cyclopropyl)methoxy)(tert-butyl)dimethylsilane

((1-(3-bromophenyl)cyclopropyl)methoxy)(tert-butyl)dimethylsilane

C27H38O3Si

C27H38O3Si

Conditions
ConditionsYield
With potassium phosphate; monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In toluene at 100℃; for 3h; Inert atmosphere; Glovebox;100%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

pinanediol
18680-27-8

pinanediol

tert-butyl 3-((3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborol-2-yl)benzoate
1154427-21-0

tert-butyl 3-((3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborol-2-yl)benzoate

Conditions
ConditionsYield
With magnesium sulfate In diethyl ether at 20℃; for 3h; Inert atmosphere;99%
In tetrahydrofuran at 20℃; for 0.5h;85%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

5-iodopyrimidine
31462-58-5

5-iodopyrimidine

tert-butyl 3-(pyrimidin-5-yl)benzoate
1595294-71-5

tert-butyl 3-(pyrimidin-5-yl)benzoate

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 90℃; for 0.5h; Suzuki Coupling; Microwave irradiation;99%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

3-bromo-4-methylaniline
7745-91-7

3-bromo-4-methylaniline

tert-butyl 5'-amino-2'-methyl-[1,1'-biphenyl]-3-carboxylate

tert-butyl 5'-amino-2'-methyl-[1,1'-biphenyl]-3-carboxylate

Conditions
ConditionsYield
Stage #1: 3-bromo-4-methylaniline With potassium carbonate In water; toluene at 65℃; Inert atmosphere;
Stage #2: 3-(tert-butoxycarbonyl)phenylboronic acid With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; toluene for 20h; Inert atmosphere; Reflux;
98%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

N-(1-Bromoisoquinolin-3-yl)-1-(2,2-difluorobenzo-[d][1,3]dioxol-5-yl)cyclopropanecarboxamide
1152274-51-5

N-(1-Bromoisoquinolin-3-yl)-1-(2,2-difluorobenzo-[d][1,3]dioxol-5-yl)cyclopropanecarboxamide

tert-butyl 3-(3-(1-(2,2-difluorobenzo[d][1,3]dioxol-5-yl)cyclopropanecarboxamido)isoquinolin-1-yl)benzoate
1152274-55-9

tert-butyl 3-(3-(1-(2,2-difluorobenzo[d][1,3]dioxol-5-yl)cyclopropanecarboxamido)isoquinolin-1-yl)benzoate

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 80℃;97%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

C26H28BrNO
1373125-71-3

C26H28BrNO

C37H41NO3

C37H41NO3

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); tri tert-butylphosphoniumtetrafluoroborate In water; toluene at 90℃; for 14h; Heck-Suzuki cascade reaction; optical yield given as %de; diastereoselective reaction;97%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water In toluene at 90℃; for 1h; Microwave irradiation; Green chemistry;96%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

C39H28IO3P

C39H28IO3P

C50H41O5P

C50H41O5P

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 80℃; for 12h; Inert atmosphere;96%
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In water; toluene at 80℃; for 12h; Inert atmosphere;96%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

7-bromo-Nα-(tert-butoxycarbonyl)-D-tryptophanamide

7-bromo-Nα-(tert-butoxycarbonyl)-D-tryptophanamide

(R)-Nα-tert-butoxycarbonyl-7-(3-(tert-butoxycarbonyl)phenyl)-tryptophanamide

(R)-Nα-tert-butoxycarbonyl-7-(3-(tert-butoxycarbonyl)phenyl)-tryptophanamide

Conditions
ConditionsYield
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; potassium phosphate; sodium tetrachloropalladate(II) In 1,4-dioxane; water at 100℃; for 0.5h; Suzuki-Miyaura Coupling; Sealed tube; Inert atmosphere;96%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(2,2,2-trifluoroethoxy)benzofuran-5-yl trifluoromethanesulfonate

2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(2,2,2-trifluoroethoxy)benzofuran-5-yl trifluoromethanesulfonate

tert-butyl 3-(2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(2,2,2-trifluoroethoxy)benzofuran-5-yl)benzoate

tert-butyl 3-(2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(2,2,2-trifluoroethoxy)benzofuran-5-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,4-dioxane; water at 110℃; Sealed tube; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,4-dioxane; water at 110℃; Inert atmosphere; Sealed tube;95%
2-bromo-3-picoline
3430-17-9

2-bromo-3-picoline

3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

tert-butyl 3-(3-methylpyridin-2-yl)benzoate
1083057-12-8

tert-butyl 3-(3-methylpyridin-2-yl)benzoate

Conditions
ConditionsYield
Stage #1: 2-bromo-3-picoline With potassium carbonate In water; toluene at 65℃; Inert atmosphere;
Stage #2: 3-(tert-butoxycarbonyl)phenylboronic acid With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; toluene for 18h; Inert atmosphere; Reflux;
92%
Stage #1: 2-bromo-3-picoline With potassium carbonate In water; toluene at 65℃; for 1h;
Stage #2: 3-(tert-butoxycarbonyl)phenylboronic acid; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In water; toluene at 80℃; for 2h;
82%
Stage #1: 2-bromo-3-picoline With potassium carbonate In toluene at 65℃; for 1h; Inert atmosphere;
Stage #2: 3-(tert-butoxycarbonyl)phenylboronic acid With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In toluene at 80℃; for 2h; Inert atmosphere;
82%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

methyl vinyl ketone
78-94-4

methyl vinyl ketone

tert-butyl 3-(3-oxobutyl)benzoate

tert-butyl 3-(3-oxobutyl)benzoate

Conditions
ConditionsYield
With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane; water at 60℃; Glovebox;89%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

6-(ethoxy-1,1,2,2,2-d5)-2-(4-fluorophenyl)-3-(methylcarbamoyl)benzofuran-5-yl trifluoromethanesulfonate

6-(ethoxy-1,1,2,2,2-d5)-2-(4-fluorophenyl)-3-(methylcarbamoyl)benzofuran-5-yl trifluoromethanesulfonate

tert-butyl-3-(6-(ethoxy-1,1,2,2,2-d5)-2-(4-fluorophenyl)-3-(methylcarbamoyl)benzofuran-5-yl)benzoate

tert-butyl-3-(6-(ethoxy-1,1,2,2,2-d5)-2-(4-fluorophenyl)-3-(methylcarbamoyl)benzofuran-5-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,3-dioxane; water at 100℃; for 16h; Inert atmosphere; Sealed tube;87.57%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

5-bromo-3-(2-methoxy-phenyl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine
875639-16-0

5-bromo-3-(2-methoxy-phenyl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine

3-[3-(2-methoxy-phenyl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine-5-yl]-benzoic acid tert-butyl ester
875639-30-8

3-[3-(2-methoxy-phenyl)-1-(toluene-4-sulfonyl)-1H-pyrrolo[2,3-b]pyridine-5-yl]-benzoic acid tert-butyl ester

Conditions
ConditionsYield
With sodium hydrogencarbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; acetonitrile at 90℃; for 0.5h; Suzuki Coupling;87%
With sodium hydrogencarbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; acetonitrile at 90℃; for 0.5h; Microwave irradiation;87%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

Fmoc-4-bromo-L-phenylalanine

Fmoc-4-bromo-L-phenylalanine

(2S)-3-(4-{3-[(tert-butoxy)carbonyl]phenyl}phenyl)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid

(2S)-3-(4-{3-[(tert-butoxy)carbonyl]phenyl}phenyl)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoic acid

Conditions
ConditionsYield
With potassium phosphate; 1,1'-bis(di-tertbutylphosphino)ferrocene; palladium diacetate In tetrahydrofuran at 50℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere;85%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

(R)-3-bromo-6-((4-hydroxy-1-(3-phenylbutanoyl)piperidin-4-yl)methyl)-2-methyl-2,6-dihydro-7H-pyrazolo[4,3-d]pyrimidin-7-one

(R)-3-bromo-6-((4-hydroxy-1-(3-phenylbutanoyl)piperidin-4-yl)methyl)-2-methyl-2,6-dihydro-7H-pyrazolo[4,3-d]pyrimidin-7-one

tert-butyl (R)-3-(6-((4-hydroxy-1-(3-phenylbutanoyl)piperidin-4-yl)methyl)-2-methyl-7-oxo-6,7-dihydro-2H-pyrazolo[4,3-d]pyrimidin-3-yl)benzoate

tert-butyl (R)-3-(6-((4-hydroxy-1-(3-phenylbutanoyl)piperidin-4-yl)methyl)-2-methyl-7-oxo-6,7-dihydro-2H-pyrazolo[4,3-d]pyrimidin-3-yl)benzoate

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 120℃; for 0.25h; Suzuki Coupling; Inert atmosphere; Microwave irradiation; Sealed tube;85%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

2-amino-5-bromo-3-(4'-chlorophenyl)pyridine

2-amino-5-bromo-3-(4'-chlorophenyl)pyridine

tert-butyl 3-[6-amino-5-(4-chlorophenyl)pyridin-3-yl]benzoate

tert-butyl 3-[6-amino-5-(4-chlorophenyl)pyridin-3-yl]benzoate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium carbonate In 1,4-dioxane; water Suzuki-Miyaura Coupling;84%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

C28H21ClO4P2

C28H21ClO4P2

C39H34O6P2

C39H34O6P2

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; tri-tert-butyl phosphine In 1,4-dioxane at 80℃; for 10h; Suzuki-Miyaura Coupling; Inert atmosphere;83%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

2-amino-5-bromo-3-phenylmethylpyrazine
174680-55-8

2-amino-5-bromo-3-phenylmethylpyrazine

tert-butyl 3-(5-amino-6-benzylpyrazin-2-yl)benzoate

tert-butyl 3-(5-amino-6-benzylpyrazin-2-yl)benzoate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; caesium carbonate In 1,4-dioxane at 75℃; for 0.5h;79%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

4-bromo-5-(methylthio)-1,3-diphenyl-1H-pyrazole
32859-25-9

4-bromo-5-(methylthio)-1,3-diphenyl-1H-pyrazole

tert-butyl 3-(5-(methylthio)-1,3-diphenyl-1H-pyrazol-4-yl)benzoate

tert-butyl 3-(5-(methylthio)-1,3-diphenyl-1H-pyrazol-4-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene Inert atmosphere;78%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

methyl 1-(3-bromo-5-methylphenyl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(3-bromo-5-methylphenyl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(3'-(tert-butoxycarbonyl)-5-methyl-[1,1,-biphenyl]-3-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(3'-(tert-butoxycarbonyl)-5-methyl-[1,1,-biphenyl]-3-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium carbonate In 1,4-dioxane; water at 90℃; for 6h; Inert atmosphere;77%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

3'-formyl-4'-methoxybiphenyl-3-carboxylic acid tert-butyl ester

3'-formyl-4'-methoxybiphenyl-3-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,4-dioxane; water for 4h; Suzuki Coupling; Inert atmosphere; Sealed tube; Heating;74%
5-bromo-2-aminopyrimidine
7752-82-1

5-bromo-2-aminopyrimidine

3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

tert-butyl 3-(2-aminopyrimidin-5-yl)benzoate

tert-butyl 3-(2-aminopyrimidin-5-yl)benzoate

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 120℃; for 3h;73.5%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

methyl 1-(6-bromopyridin-2-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(6-bromopyridin-2-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(6-(3-(tert-butoxycarbonyl)phenyl)pyridin-2-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

methyl 1-(6-(3-(tert-butoxycarbonyl)phenyl)pyridin-2-yl)-5-(2-(1-methyl-1H-1,2,3-triazol-4-yl)cyclopropyl)-1H-pyrazole-4-carboxylate

Conditions
ConditionsYield
With sodium carbonate In methanol; toluene at 110℃; for 2h; Inert atmosphere;73.3%
4-chloro-3-methylpyridine
1681-36-3

4-chloro-3-methylpyridine

3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

tert-butyl 3-(3-methylpyridin-4-yl)benzoate
1189328-78-6

tert-butyl 3-(3-methylpyridin-4-yl)benzoate

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 80℃; for 60h;71.4%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

2-bromo-3-chloropyridine
96424-68-9

2-bromo-3-chloropyridine

tert-butyl 3-(3-chloropyridin-2-yl)benzoate

tert-butyl 3-(3-chloropyridin-2-yl)benzoate

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate In 1,2-dimethoxyethane; water at 80℃;71%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

ethyl 2-(4-fluorophenyl)-6-nitro-5-(trifluoromethylsulfonyloxy)benzofuran-3-carboxylate
691857-51-9

ethyl 2-(4-fluorophenyl)-6-nitro-5-(trifluoromethylsulfonyloxy)benzofuran-3-carboxylate

ethyl 5-(3-(tert-butoxycarbonyl)phenyl)-2-(4-fluorophenyl)-6-nitrobenzofuran-3-carboxylate
1217339-14-4

ethyl 5-(3-(tert-butoxycarbonyl)phenyl)-2-(4-fluorophenyl)-6-nitrobenzofuran-3-carboxylate

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 20 - 90℃;69%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 90℃;69%
3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(3,3,3-trifluoropropyl)benzofuran-5-yl trifluoromethanesulfonate

2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(3,3,3-trifluoropropyl)benzofuran-5-yl trifluoromethanesulfonate

tert-butyl 3-(2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(3,3,3-trifluoropropyl)benzofuran-5-yl)benzoate

tert-butyl 3-(2-(4-fluorophenyl)-3-(methylcarbamoyl)-6-(3,3,3-trifluoropropyl)benzofuran-5-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In 1,4-dioxane; water at 90℃; for 16h;67.7%
2,6-dichloropyridine-3-carboxylic acid
38496-18-3

2,6-dichloropyridine-3-carboxylic acid

3-(tert-butoxycarbonyl)phenylboronic acid
220210-56-0

3-(tert-butoxycarbonyl)phenylboronic acid

6-(3-(tert-butoxycarbonyl)phenyl)-2-chloronicotinic acid
1391833-29-6

6-(3-(tert-butoxycarbonyl)phenyl)-2-chloronicotinic acid

Conditions
ConditionsYield
Stage #1: 2,6-dichloropyridine-3-carboxylic acid; 3-(tert-butoxycarbonyl)phenylboronic acid With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In dimethoxyethane-1,2; water at 90℃;
Stage #2: With hydrogenchloride In dimethoxyethane-1,2; water; ethyl acetate pH=3 - 4;
67%

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