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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 5-Bromo-2-anisaldehyde CAS No. 25016-01-7

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 25016-01-7 with competitive price

Cas:25016-01-7

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzaldehyde,5-bromo-2-methoxy-

Cas:25016-01-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

5-Bromo-2-anisaldehyde 99%

Cas:25016-01-7

Min.Order:1 Kilogram

FOB Price: $21.0 / 30.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High quality 5-Bromo-2-anisaldehyde CAS 25016-01-7 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made i

High quality 5-Bromo-2-anisaldehyde CAS 25016-01-7

Cas:25016-01-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:25016-01-7

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Kilogram

FOB Price: $30.0 / 40.0

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5-Bromo-o-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

favourable price of 25016-01-7 98% 5-Bromo-2-anisaldehyde in china

Cas:25016-01-7

Min.Order:10 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

favourable price of 25016-01-7 98% 5-Bromo-2-anisaldehyde in chinaAppearance:powder Storage:Store in cool and dry place. Package:according to customers' requirements Application:pharmaceutical intermediates raw material Transportation:By air(EMS

favourable price of 25016-01-7 98% 5-Bromo-2-anisaldehyde in china

Cas:25016-01-7

Min.Order:1 Gram

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM CAS NO.25016-01-7 5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermediat

5-Bromo-2-methoxybenzaldehyde

Cas:25016-01-7

Min.Order:1 Kilogram

FOB Price: $5.0 / 15.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 5-Bromo-2-anisaldehyde Synonyms: AKOS B005855;AKOS BBS-00003157;5-BROMO-O-ANISALDEHYDE;5-BROMO-2-ANISALDEHYDE;5-BROMO-2-METHOXYBENZALDEHYDE;AURORA KA-5723;ASISCHEM R38855;JR-13438, 5-Bromo-2-methoxybenzaldehyde, 98% CAS: 25016-

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

5-Bromo-2-methoxybenzaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Manufacturers

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

favourable price of 25016-01-7 98% 5-Bromo-2-anisaldehyde in china

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

5-Bromo-2-methoxybenzaldehyde cas no. 25016-01-7 98%

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Port:Shanghai

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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DB BIOTECH CO., LTD

Q1: Are you a manufacturer Answer: Yes, we are factory founded on 2012.Q2: How to contact with us Click "contact supplier" And then send us message the product you interest in, you will get reply within 12 hours.Q3:Which kind of payment terms do you

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 5-Bromo-2-methoxybenzaldehyde 500g

Cas:25016-01-7

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

5-bromo-2-methoxy benzaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemsigma International Co.,Ltd.

bulk productionChemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical manufacturing for overseas customers, in the field of API, pharmaceutical intermediates, chemical intermediates, fine chem

5-Bromo-2-methoxybenzaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:intermediate

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

5-Bromo-2-anisaldehyde cas 25016-01-7Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

5-Bromo-2-anisaldehyde cas 25016-01-7

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:Light yellow crystalline powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

5-Bromo-2-anisaldehyde

Cas:25016-01-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

5-bromosalicyclaldehyde
1761-61-1

5-bromosalicyclaldehyde

methyl iodide
74-88-4

methyl iodide

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;100%
Stage #1: 5-bromosalicyclaldehyde With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.25h; Inert atmosphere;
Stage #2: methyl iodide In N,N-dimethyl-formamide; mineral oil at 0 - 21℃; Inert atmosphere;
98%
With potassium carbonate In N,N-dimethyl-formamide at 25℃; for 15h;98%
5-bromo-2-methoxy-benzyl alcohol
80866-82-6

5-bromo-2-methoxy-benzyl alcohol

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; copper diacetate In neat (no solvent) at 80℃; for 18h; Green chemistry;97%
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In dimethyl sulfoxide; ethyl acetate at 0 - 20℃; Inert atmosphere;
ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With N-Bromosuccinimide; 1-n-butyl-3-methylimidazolim bromide for 0.25h; Ionic liquid; regioselective reaction;95%
With iodine pentoxide; potassium bromide In water at 20℃; for 23h; regioselective reaction;94%
With poly(N-bromobenzene-1,3-disulfonylamide) In dichloromethane at 40℃; for 1.5h;89%
dimethyl sulfate
77-78-1

dimethyl sulfate

5-bromosalicyclaldehyde
1761-61-1

5-bromosalicyclaldehyde

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In acetone for 2h;95%
With potassium carbonate In acetone at 20℃;93%
With sodium carbonate In acetone for 8h; Inert atmosphere; Reflux;92%
(2-methoxyphenyl)methanol
612-16-8

(2-methoxyphenyl)methanol

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With bis(collidine)bromine(I) hexafluorophosphate In dichloromethane at 20℃; for 5h;95%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In dichloromethane at 25℃; for 0.5h; chemoselective reaction;66 %Chromat.
2-methyl-4-bromoanisole
14804-31-0

2-methyl-4-bromoanisole

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With carbon tetrabromide; oxygen In acetonitrile at 20℃; for 3.5h; Irradiation; Green chemistry;91%
With pyridine; dipotassium peroxodisulfate; copper(I) sulfate In water; acetonitrile at 65 - 70℃; for 3h;51%
Multi-step reaction with 2 steps
1: N-Bromosuccinimide / tetrachloromethane / 5 h / 20 - 30 °C / Irradiation
2: 4-methylmorpholine N-oxide / 2 h / 20 °C / Reflux
View Scheme
2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
Stage #1: 2,4-dibromoanisole With n-butyllithium In diethyl ether at -78℃; for 0.25h;
Stage #2: N,N-dimethyl-formamide In diethyl ether at -78℃; for 0.25h;
90%
acetone
67-64-1

acetone

dimethyl sulfate
77-78-1

dimethyl sulfate

5-bromosalicyclaldehyde
1761-61-1

5-bromosalicyclaldehyde

A

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

B

(E)-4-(5-Bromo-2-methoxy-phenyl)-but-3-en-2-one
943768-51-2

(E)-4-(5-Bromo-2-methoxy-phenyl)-but-3-en-2-one

C

4-(5-Bromo-2-methoxy-phenyl)-4-hydroxy-butan-2-one

4-(5-Bromo-2-methoxy-phenyl)-4-hydroxy-butan-2-one

Conditions
ConditionsYield
With potassium carbonate for 15h; Heating;A 5%
B n/a
C 88%
With potassium carbonate for 15h; Heating;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene With 2-(N,N-dimethylaminomethyl)phenyllithium In tert-butyl methyl ether; cyclohexane at 60℃; Inert atmosphere;
Stage #2: N,N-dimethyl-formamide at 20℃; for 3h;
73.8%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With silver trifluoromethanesulfonate In dichloromethane at -78℃; for 0.166667h; Inert atmosphere; regioselective reaction;61%
titanium tetrachloride In dichloromethane
methanol
67-56-1

methanol

m-bromobenzoic aldehyde
3132-99-8

m-bromobenzoic aldehyde

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With dipotassium peroxodisulfate; palladium diacetate; 3-trifluoromethylaniline In dichloromethane at 60℃; for 24h; Sealed tube;30%
tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

5-bromosalicyclaldehyde
1761-61-1

5-bromosalicyclaldehyde

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With potassium carbonate at 150 - 160℃; for 4h;16%
methanol
67-56-1

methanol

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

A

2,4-dibromoanisole
21702-84-1

2,4-dibromoanisole

B

methyl 5-bromo-2-methoxybenzoate
7120-41-4

methyl 5-bromo-2-methoxybenzoate

C

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With Oxone; sodium bromide In water at 20℃; for 24h;A 15%
B 15%
C 5%
4-bromo-2-(chloromethyl)-1-methoxybenzene
7017-52-9

4-bromo-2-(chloromethyl)-1-methoxybenzene

A

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

B

5-bromo-2-methoxybenzoic acid
2476-35-9

5-bromo-2-methoxybenzoic acid

Conditions
ConditionsYield
With copper(II) nitrate; acetic acid
2-methoxybenzyl bromide
52289-93-7

2-methoxybenzyl bromide

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With sodium periodate; hydrogen cation; lithium bromide Heating;
Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

2-fluoronaphthalene
323-09-1

2-fluoronaphthalene

A

7-fluoro-1-naphthaldehyde

7-fluoro-1-naphthaldehyde

B

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
titanium tetrachloride In dichloromethane
4-bromo-2-(bromomethyl)-1-methoxybenzene
184970-28-3

4-bromo-2-(bromomethyl)-1-methoxybenzene

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

Conditions
ConditionsYield
With 4-methylmorpholine N-oxide at 20℃; for 2h; Reflux;118.27 mg
dicyanozinc
557-21-1

dicyanozinc

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-cyano-2-methoxybenzaldehyde
21962-53-8

5-cyano-2-methoxybenzaldehyde

Conditions
ConditionsYield
tetrakis(triphenylphosphine) palladium(0) In DMF (N,N-dimethyl-formamide) at 20℃; for 3h;99%
With water; tri tert-butylphosphoniumtetrafluoroborate; zinc; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In 1-methyl-pyrrolidin-2-one at 20℃; for 24h;98%
ethyl (diethoxyphosphoryl)methanesulfonate
73300-75-1

ethyl (diethoxyphosphoryl)methanesulfonate

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

C11H13BrO4S

C11H13BrO4S

Conditions
ConditionsYield
Stage #1: ethyl (diethoxyphosphoryl)methanesulfonate With n-butyllithium In tetrahydrofuran; hexanes at -78℃; for 0.25h;
Stage #2: 5-bromo-2-methoxybenzaldehyde In tetrahydrofuran; hexanes at -78 - 20℃; for 1h;
99%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-bromo-2-methoxy-3-nitrobenzaldehyde
213620-52-1

5-bromo-2-methoxy-3-nitrobenzaldehyde

Conditions
ConditionsYield
With sulfuric acid; nitric acid at -15℃; for 2h;99%
vinyl magnesium bromide
1826-67-1

vinyl magnesium bromide

benzoyl chloride
98-88-4

benzoyl chloride

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

C17H15BrO3
1465765-08-5

C17H15BrO3

Conditions
ConditionsYield
Stage #1: vinyl magnesium bromide; 5-bromo-2-methoxybenzaldehyde In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: benzoyl chloride In tetrahydrofuran at 0 - 20℃; for 15h; Inert atmosphere;
99%
diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

ethyl-3-(5-bromo-2-methoxyphenyl) acrylate

ethyl-3-(5-bromo-2-methoxyphenyl) acrylate

Conditions
ConditionsYield
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran at 0 - 5℃; for 0.5h; Inert atmosphere;
Stage #2: 5-bromo-2-methoxybenzaldehyde In tetrahydrofuran at 20℃; for 1.5h; Inert atmosphere;
98.99%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-bromo-2-methoxy-benzyl alcohol
80866-82-6

5-bromo-2-methoxy-benzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In tetrahydrofuran; water98%
With sodium tetrahydroborate In tetrahydrofuran; methanol for 3h;97.2%
With sodium tetrahydroborate In methanol; water at 20℃; for 24h;94%
ethylene glycol
107-21-1

ethylene glycol

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

2-(5-bromo-2-methoxy-phenyl)-1,3-dioxolane
156603-10-0

2-(5-bromo-2-methoxy-phenyl)-1,3-dioxolane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene Reflux;98%
With toluene-4-sulfonic acid In toluene Heating;65%
With toluene-4-sulfonic acid In toluene for 2h;
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

(E)-3-(3-formyl-4-methoxyphenyl)acrylic acid tert-butyl ester

(E)-3-(3-formyl-4-methoxyphenyl)acrylic acid tert-butyl ester

Conditions
ConditionsYield
With 1,3-disubstituted imidazolium bromide; potassium carbonate; palladium diacetate In 1,4-dioxane at 105℃; for 17h; Heck reaction;98%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-bromo-2-methoxybenzonitrile
144649-99-0

5-bromo-2-methoxybenzonitrile

Conditions
ConditionsYield
With ammonium iodide In dimethyl sulfoxide at 20℃; for 5h; Electrolysis;98%
With formic acid; hydroxylamine hydrochloride; sodium acetate for 15h; Reflux;97%
With sodium hydroxide; formic acid; hydroxylamine hydrochloride; sodium formate
With sodium hydroxide; hydroxylamine hydrochloride; sodium acetate; acetic anhydride; acetic acid
With sodium hydroxide; hydroxylamine hydrochloride; sodium acetate; acetic anhydride; acetic acid
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

4-bromo-2-(diethoxymethyl)-1-methoxybenzene
67868-79-5

4-bromo-2-(diethoxymethyl)-1-methoxybenzene

Conditions
ConditionsYield
With zirconium(IV) chloride In ethanol at 20℃;98%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

(1S,2S,3S,5R)-(+)-isopinocampheylamine
13293-47-5

(1S,2S,3S,5R)-(+)-isopinocampheylamine

(1S,2S,3S,5R)-N-(5-bromo-2-methoxybenzyl)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine

(1S,2S,3S,5R)-N-(5-bromo-2-methoxybenzyl)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-amine

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methoxybenzaldehyde; (1S,2S,3S,5R)-(+)-isopinocampheylamine In methanol
Stage #2: With sodium cyanoborohydride; acetic acid In methanol
98%
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

C10H13BrO3

C10H13BrO3

Conditions
ConditionsYield
Stage #1: 5-bromo-2-methoxybenzaldehyde With sodium tetrahydroborate In methanol at 0 - 20℃;
Stage #2: chloromethyl methyl ether With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;
98%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

(5-bromo-2-methoxyphenyl)(4-fluorophenyl)methanol
1282796-09-1

(5-bromo-2-methoxyphenyl)(4-fluorophenyl)methanol

Conditions
ConditionsYield
Stage #1: 1-Bromo-4-fluorobenzene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 3h;
Stage #2: 5-bromo-2-methoxybenzaldehyde In tetrahydrofuran; hexane at 20℃;
97%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

(E)-ethyl 3-(5-bromo-2-methoxyphenyl)acrylate
540778-82-3

(E)-ethyl 3-(5-bromo-2-methoxyphenyl)acrylate

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran96%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

(2-methylsulfanylphenyl)boronic acid
168618-42-6

(2-methylsulfanylphenyl)boronic acid

4-methoxy-2'-(methylthio)biphenyl-3-carbaldehyde
923281-46-3

4-methoxy-2'-(methylthio)biphenyl-3-carbaldehyde

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water for 18h; Heating / reflux;96%
[(p-methylphenyl)sulfonylmethyl]isonitrile
38622-91-2, 36635-61-7

[(p-methylphenyl)sulfonylmethyl]isonitrile

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

C10H8BrNO2
1091618-40-4

C10H8BrNO2

Conditions
ConditionsYield
With potassium carbonate In methanol for 22h; Reflux;96%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

2-(5-bromo-2-methoxyphenyl)-5,5-dimethyl-1,3-dioxane

2-(5-bromo-2-methoxyphenyl)-5,5-dimethyl-1,3-dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene Reflux; Dean-Stark;96%
cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-(5-Bromo-2-methoxy-benzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione
117646-13-6

5-(5-Bromo-2-methoxy-benzylidene)-2,2-dimethyl-[1,3]dioxane-4,6-dione

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 12h; Ambient temperature;95%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

(diisopropoxyphosphorylmethanesulfonylmethanesulfonylmethyl)phosphonic acid diisopropyl ester
312512-49-5

(diisopropoxyphosphorylmethanesulfonylmethanesulfonylmethyl)phosphonic acid diisopropyl ester

bis(4-bromo-2-(2-methanesulfonyl-vinyl)-1-methoxy-benzene)

bis(4-bromo-2-(2-methanesulfonyl-vinyl)-1-methoxy-benzene)

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; lithium bromide In tetrahydrofuran Horner-Emmons-Wadsworth reaction;95%
N-methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide
129986-67-0

N-methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

3-(5-bromo-2-methoxyphenyl)-N-methoxy-N-methylacrylamide

3-(5-bromo-2-methoxyphenyl)-N-methoxy-N-methylacrylamide

Conditions
ConditionsYield
In dichloromethane at 20℃; for 5h;95%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

(E)-methyl 3-(5-bromo-2-methoxyphenyl)acrylate
1528736-46-0

(E)-methyl 3-(5-bromo-2-methoxyphenyl)acrylate

Conditions
ConditionsYield
In toluene Reflux;95%
In toluene Inert atmosphere; Reflux;95%
6-aminocoumarin
14415-44-2

6-aminocoumarin

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

6-(5-bromo-2-methoxybenzylideneamino)-2H-chromen-2-one

6-(5-bromo-2-methoxybenzylideneamino)-2H-chromen-2-one

Conditions
ConditionsYield
With piperidine In ethanol for 6h; Heating;94%
[2,5-bis(tetrahydro-2H-pyran-2-yloxy)phenyl]boronic acid
1189060-59-0

[2,5-bis(tetrahydro-2H-pyran-2-yloxy)phenyl]boronic acid

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

5-[2,5-bis(tetrahydro-2H-pyran-2-yloxy)phenyl]salicylaldehyde
1189060-60-3

5-[2,5-bis(tetrahydro-2H-pyran-2-yloxy)phenyl]salicylaldehyde

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride; palladium diacetate; sodium hydrogencarbonate; triphenylphosphine In ethanol; water; toluene at 100℃; for 3.5h; Suzuki coupling; Inert atmosphere;94%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

urea
57-13-6

urea

5-ethoxycarbonyl-4-(2-methoxy-5-bromophenyl)-6-methyl-3,4-dihydropyrimidin-2-(1H)-one
313508-33-7

5-ethoxycarbonyl-4-(2-methoxy-5-bromophenyl)-6-methyl-3,4-dihydropyrimidin-2-(1H)-one

Conditions
ConditionsYield
With HPA-montmorillonite-KSF In neat (no solvent) for 1h; Biginelli Pyrimidone Synthesis; Reflux; Green chemistry;94%
With Zn0.9Ni0.1Al2O4 In ethanol for 4h; Biginelli Pyrimidone Synthesis; Reflux;52%
5-bromo-2-methoxybenzaldehyde
25016-01-7

5-bromo-2-methoxybenzaldehyde

tetramethylammonium trifluoromethanethiolate

tetramethylammonium trifluoromethanethiolate

2-Methoxy-5-(trifluoromethylthio)benzaldehyde

2-Methoxy-5-(trifluoromethylthio)benzaldehyde

Conditions
ConditionsYield
With palladium(l) tri-tert-butylphosphine iodide dimer In toluene at 80℃;94%

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