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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Anisomycin

Cas:22862-76-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

shanghai Tauto Biotech Co., Ltd

17-year experience in Phytochemicals Each product has passed very strict tests (NMR\MS\HPLC) Agents in 13 countries Certified by ISO 9001:2008 quality management system Leader Supplier of Botanical Reference Materials in China

Wuningmeisu C

Cas:22862-76-6

Min.Order:10 Milligram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price API 99% ANISOMYCIN 22862-76-6 GMP Manufacturer

Cas:22862-76-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Anisomycin

Cas:22862-76-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

high quality ANISOMYCIN

Cas:22862-76-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

ANISOMYCIN

Cas:22862-76-6

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 22862-76-6 with best quality

Cas:22862-76-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

ANISOMYCIN CAS22862-76-6

Cas:22862-76-6

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1,In No Less five years exporting experience. 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Onchem specialized in APIs, chemical intermediate

Hotsale Anisomycin 98%min with lower price

Cas:22862-76-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

About Product Details Items Specifications Test Results Appearance White to white crystalline powde

Supply High Quality ANISOMYCIN CAS 22862-76-6 For research Use only

Cas:22862-76-6

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

ANISOMYCIN CAS:22862-76-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

ANISOMYCIN CAS:22862-76-6

Cas:22862-76-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3,4-Pyrrolidinediol,2-[(4-methoxyphenyl)methyl]-, 3-acetate, (2R,3S,4S)-

Cas:22862-76-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

We can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need C

Anisomycin manufacturer with low price

Cas:22862-76-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

3,4-Pyrrolidinediol,2-[(4-methoxyphenyl)methyl]-, 3-acetate, (2R,3S,4S)-

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

3,4-PYRROLIDINEDIOL,2-[(4-METHOXYPHENYL)METHYL]-, 3-ACETATE, (2R,3S,4S)-

Cas:22862-76-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Anisomycin

Cas:22862-76-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Anisomycin

Cas:22862-76-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

AnisomycinAppearance:Solid powder Storage:Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years). Package:according to customers' requirements Application:Inhibitor Transportation:By air(EMS or EUB or FedEx o

Anisomycin

Cas:22862-76-6

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shenzhen JYMed Technology Co.,Ltd.

high quality with GMP grade, EP, USP standard etc large scale with Competitive price Our products includes: Generic bulk peptide APIs, Cosmetic peptide, custom peptides and veterinary peptides. Application:Antibiotics

Anisomycin factory price-whole sale

Cas:22862-76-6

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

ANISOMYCIN

Cas:22862-76-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Anisomycin;Flagecidin;(2S,3R,4R)-2-(4-methoxybenzyl)-4-hydroxypyrrolidin-3-ylacetate

Cas:22862-76-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Anisomycin, from Streptomyces griseolus.99%

Cas:22862-76-6

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

22862-76-6 CAS NO.22862-76-6

Cas:22862-76-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Anisomycin from Streptomyces griseolus

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Anisomycin

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

Anisomycin

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Anisomycin

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Other

inquiry

Sinoway Industrial Co., Ltd.

Why is SINOWAY:1) Specialized in pharmaceutical and healthcare industrial since 19872) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days.4) We have warehouse in USA with quickly shipment . Application:API

99% up by HPLC ANISOMYCIN 22862-76-6

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Anisomycin from Streptomyces griseolus A43980 25mg

Cas:22862-76-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

AnisoMycin

Cas:22862-76-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

(2R,3S,4S)-3-acetoxy-N-(benzyloxycarbonyl)-4-hydroxy-2-(4-methoxybenzyl)pyrrolidine
27958-08-3

(2R,3S,4S)-3-acetoxy-N-(benzyloxycarbonyl)-4-hydroxy-2-(4-methoxybenzyl)pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethanol under 760 Torr; for 0.25h;95%
(2R,3S,4S)-3-Acetoxy-1-(tert-butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyl)pyrrolidine
180081-83-8

(2R,3S,4S)-3-Acetoxy-1-(tert-butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)-2-(4-methoxybenzyl)pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogenchloride In methanol at 20℃;88%
C19H27NO6
1262850-97-4

C19H27NO6

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogenchloride In methanol78%
(2R,3S,4S)-3-acetoxy-1-benzyl-4-hydroxy-2-(4-methoxybenzyl)-pyrrolidine
933992-79-1

(2R,3S,4S)-3-acetoxy-1-benzyl-4-hydroxy-2-(4-methoxybenzyl)-pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogenchloride; hydrogen; palladium on activated charcoal In methanol; water for 3h; Yield given;
(2R,3S,4S)-3-acetoxy-4-allyloxy-1-benzyl-2-(p-methoxybenzyl)pyrrolidine
87796-48-3

(2R,3S,4S)-3-acetoxy-4-allyloxy-1-benzyl-2-(p-methoxybenzyl)pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogenchloride; hydrogen; palladium on activated charcoal 1.) MeOH, reflux, 2.) MeOH; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: HCl, water / palladium-charcoal 10percent / methanol / 48 h / Heating
2: HCl, H2 / palladium-charcoal 10percent / methanol; H2O / 3 h
View Scheme
Acetic acid (1S,2R)-2-azido-1-((R)-2-bromo-1-hydroxy-ethyl)-3-(4-methoxy-phenyl)-propyl ester
173266-54-1

Acetic acid (1S,2R)-2-azido-1-((R)-2-bromo-1-hydroxy-ethyl)-3-(4-methoxy-phenyl)-propyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With sodium acetate In methanol for 10h; Heating; Yield given;
C21H21NO5

C21H21NO5

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
With hydrogen; palladium dihydroxide In methanol; acetic acid at 20℃; under 3878.71 Torr; for 24h;76 mg
(4R,5S,6S)-5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine
951385-80-1

(4R,5S,6S)-5-(tert-butyldimethylsilyloxy)-4-(4-methoxybenzyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 89 percent / Bu4NF / tetrahydrofuran / 1 h / 20 °C
2: 98 percent / pyridine / CH2Cl2
3: O3; O2 / methanol / -78 °C
4: 76 mg / H2 / Pd(OH)2 / methanol; acetic acid / 24 h / 20 °C / 3878.71 Torr
View Scheme
C20H21NO3
951385-97-0

C20H21NO3

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 98 percent / pyridine / CH2Cl2
2: O3; O2 / methanol / -78 °C
3: 76 mg / H2 / Pd(OH)2 / methanol; acetic acid / 24 h / 20 °C / 3878.71 Torr
View Scheme
(4R,5S,6S)-4-(4-methoxybenzyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazin-5-yl acetate
951385-93-6

(4R,5S,6S)-4-(4-methoxybenzyl)-2-phenyl-6-vinyl-5,6-dihydro-4H-1,3-oxazin-5-yl acetate

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: O3; O2 / methanol / -78 °C
2: 76 mg / H2 / Pd(OH)2 / methanol; acetic acid / 24 h / 20 °C / 3878.71 Torr
View Scheme
(2S,3S)-pentene-1,2,3-triol
114489-31-5

(2S,3S)-pentene-1,2,3-triol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 9 steps
1: DBU / acetonitrile / -30 °C
2: 1.) I2, NaHCO3, 2.) aq. HCl / 1.) MeCN, 0 deg C, 2.) MeOH, 20 deg C
3: NaHCO3 / methanol / 0 °C
5: NaHCO3 / methanol / 0 °C
6: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
7: imidazole / dimethylformamide / 20 °C
8: DMAP, Et3N / CH2Cl2 / 20 °C
9: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
(2S,3S)-4-Amino-5-iodo-pentane-1,2,3-triol

(2S,3S)-4-Amino-5-iodo-pentane-1,2,3-triol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: NaHCO3 / methanol / 0 °C
3: NaHCO3 / methanol / 0 °C
4: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
5: imidazole / dimethylformamide / 20 °C
6: DMAP, Et3N / CH2Cl2 / 20 °C
7: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
(S,S)-2,2-dimethyl-4-(tert-butyldimethylsilyloxy)methyl-5-hydroxymethyl-1,3-dioxolane
207123-20-4

(S,S)-2,2-dimethyl-4-(tert-butyldimethylsilyloxy)methyl-5-hydroxymethyl-1,3-dioxolane

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 10 steps
1: aq. HCl / tetrahydrofuran / 20 °C
2: DBU / acetonitrile / -30 °C
3: 1.) I2, NaHCO3, 2.) aq. HCl / 1.) MeCN, 0 deg C, 2.) MeOH, 20 deg C
4: NaHCO3 / methanol / 0 °C
6: NaHCO3 / methanol / 0 °C
7: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
8: imidazole / dimethylformamide / 20 °C
9: DMAP, Et3N / CH2Cl2 / 20 °C
10: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
(2S,3S,4R)-4-Amino-5-(4-methoxy-phenyl)-pentane-1,2,3-triol
1053733-83-7

(2S,3S,4R)-4-Amino-5-(4-methoxy-phenyl)-pentane-1,2,3-triol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: NaHCO3 / methanol / 0 °C
2: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
3: imidazole / dimethylformamide / 20 °C
4: DMAP, Et3N / CH2Cl2 / 20 °C
5: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
(2R,3S,4S)-1-(tert-Butoxycarbonyl)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine
180081-82-7

(2R,3S,4S)-1-(tert-Butoxycarbonyl)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: imidazole / dimethylformamide / 20 °C
2: DMAP, Et3N / CH2Cl2 / 20 °C
3: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
[(1R,2S,3S)-2,3,4-Trihydroxy-1-(4-methoxy-benzyl)-butyl]-carbamic acid tert-butyl ester
180081-81-6

[(1R,2S,3S)-2,3,4-Trihydroxy-1-(4-methoxy-benzyl)-butyl]-carbamic acid tert-butyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
2: imidazole / dimethylformamide / 20 °C
3: DMAP, Et3N / CH2Cl2 / 20 °C
4: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
(2R,3S,4S)-1-(tert-Butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)-3-hydroxy-2-(4-methoxybenzyl)pyrrolidine
249617-08-1

(2R,3S,4S)-1-(tert-Butoxycarbonyl)-4-(tert-butyldimethylsilyloxy)-3-hydroxy-2-(4-methoxybenzyl)pyrrolidine

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: DMAP, Et3N / CH2Cl2 / 20 °C
2: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
2,2,2-Trichloro-acetimidic acid (1S,2S)-2-(2,2,2-trichloro-acetimidoyloxy)-1-(2,2,2-trichloro-acetimidoyloxymethyl)-but-3-enyl ester
180081-74-7

2,2,2-Trichloro-acetimidic acid (1S,2S)-2-(2,2,2-trichloro-acetimidoyloxy)-1-(2,2,2-trichloro-acetimidoyloxymethyl)-but-3-enyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: 1.) I2, NaHCO3, 2.) aq. HCl / 1.) MeCN, 0 deg C, 2.) MeOH, 20 deg C
2: NaHCO3 / methanol / 0 °C
4: NaHCO3 / methanol / 0 °C
5: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
6: imidazole / dimethylformamide / 20 °C
7: DMAP, Et3N / CH2Cl2 / 20 °C
8: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
((1S,2S,3S)-2,3,4-Trihydroxy-1-iodomethyl-butyl)-carbamic acid tert-butyl ester
180081-77-0

((1S,2S,3S)-2,3,4-Trihydroxy-1-iodomethyl-butyl)-carbamic acid tert-butyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 6 steps
2: NaHCO3 / methanol / 0 °C
3: DEAD, Ph3P, PPTS / tetrahydrofuran / 0 °C
4: imidazole / dimethylformamide / 20 °C
5: DMAP, Et3N / CH2Cl2 / 20 °C
6: 88 percent / aq. HCl / methanol / 20 °C
View Scheme
divinylcarbinol
922-65-6

divinylcarbinol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 13 steps
1: D-(-)-DIPT, TBHP, Ti(O-i-Pr)4 / CH2Cl2 / -20 °C
2: Et3N, DMAP / CH2Cl2
3: 85 percent / copper(I) iodide / tetrahydrofuran / -10 °C
4: 94 percent / pyridine / CH2Cl2 / Ambient temperature
5: NaN3 / dimethylformamide / 7 h / 80 °C
6: 2N aq. HCl / 0.5 h
7: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
8: 89 percent / imidazole / dimethylformamide / 0 °C
9: pyridine / CH2Cl2 / 2 h / Ambient temperature
10: pyridine / 4 h / Ambient temperature
11: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
12: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
13: NaOAc / methanol / 10 h / Heating
View Scheme
(2S,3R)-1,2-epoxy-4-penten-3-ol
102490-00-6

(2S,3R)-1,2-epoxy-4-penten-3-ol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 12 steps
1: Et3N, DMAP / CH2Cl2
2: 85 percent / copper(I) iodide / tetrahydrofuran / -10 °C
3: 94 percent / pyridine / CH2Cl2 / Ambient temperature
4: NaN3 / dimethylformamide / 7 h / 80 °C
5: 2N aq. HCl / 0.5 h
6: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
7: 89 percent / imidazole / dimethylformamide / 0 °C
8: pyridine / CH2Cl2 / 2 h / Ambient temperature
9: pyridine / 4 h / Ambient temperature
10: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
11: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
12: NaOAc / methanol / 10 h / Heating
View Scheme
(3S,4S)-trimethylsilyloxy oxirane
173328-15-9

(3S,4S)-trimethylsilyloxy oxirane

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 11 steps
1: 85 percent / copper(I) iodide / tetrahydrofuran / -10 °C
2: 94 percent / pyridine / CH2Cl2 / Ambient temperature
3: NaN3 / dimethylformamide / 7 h / 80 °C
4: 2N aq. HCl / 0.5 h
5: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
6: 89 percent / imidazole / dimethylformamide / 0 °C
7: pyridine / CH2Cl2 / 2 h / Ambient temperature
8: pyridine / 4 h / Ambient temperature
9: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
10: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
11: NaOAc / methanol / 10 h / Heating
View Scheme
(2S,3R)-1-(4-Methoxy-phenyl)-3-trimethylsilanyloxy-pent-4-en-2-ol
173266-46-1

(2S,3R)-1-(4-Methoxy-phenyl)-3-trimethylsilanyloxy-pent-4-en-2-ol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 10 steps
1: 94 percent / pyridine / CH2Cl2 / Ambient temperature
2: NaN3 / dimethylformamide / 7 h / 80 °C
3: 2N aq. HCl / 0.5 h
4: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
5: 89 percent / imidazole / dimethylformamide / 0 °C
6: pyridine / CH2Cl2 / 2 h / Ambient temperature
7: pyridine / 4 h / Ambient temperature
8: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
9: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
10: NaOAc / methanol / 10 h / Heating
View Scheme
(3R,4R)-4-Azido-5-(4-methoxy-phenyl)-pent-1-en-3-ol
173266-47-2

(3R,4R)-4-Azido-5-(4-methoxy-phenyl)-pent-1-en-3-ol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
2: 89 percent / imidazole / dimethylformamide / 0 °C
3: pyridine / CH2Cl2 / 2 h / Ambient temperature
4: pyridine / 4 h / Ambient temperature
5: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
6: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
7: NaOAc / methanol / 10 h / Heating
View Scheme
{(R)-1-[(R)-1-Azido-2-(4-methoxy-phenyl)-ethyl]-allyloxy}-trimethyl-silane

{(R)-1-[(R)-1-Azido-2-(4-methoxy-phenyl)-ethyl]-allyloxy}-trimethyl-silane

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: 2N aq. HCl / 0.5 h
2: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
3: 89 percent / imidazole / dimethylformamide / 0 °C
4: pyridine / CH2Cl2 / 2 h / Ambient temperature
5: pyridine / 4 h / Ambient temperature
6: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
7: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
8: NaOAc / methanol / 10 h / Heating
View Scheme
(2S,3S,4R)-4-Azido-5-(4-methoxy-phenyl)-pentane-1,2,3-triol

(2S,3S,4R)-4-Azido-5-(4-methoxy-phenyl)-pentane-1,2,3-triol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 89 percent / imidazole / dimethylformamide / 0 °C
2: pyridine / CH2Cl2 / 2 h / Ambient temperature
3: pyridine / 4 h / Ambient temperature
4: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
5: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
6: NaOAc / methanol / 10 h / Heating
View Scheme
Acetic acid (1S,2R)-2-azido-3-(4-methoxy-phenyl)-1-(S)-oxiranyl-propyl ester
173266-52-9

Acetic acid (1S,2R)-2-azido-3-(4-methoxy-phenyl)-1-(S)-oxiranyl-propyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
2: NaOAc / methanol / 10 h / Heating
View Scheme
Methanesulfonic acid (1S,2R)-1-(4-methoxy-benzyl)-2-trimethylsilanyloxy-but-3-enyl ester
173266-56-3

Methanesulfonic acid (1S,2R)-1-(4-methoxy-benzyl)-2-trimethylsilanyloxy-but-3-enyl ester

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 9 steps
1: NaN3 / dimethylformamide / 7 h / 80 °C
2: 2N aq. HCl / 0.5 h
3: 95 percent / OsO4, K3Fe(CN)6, K2CO3, DHQ-CLB, water / 2-methyl-propan-2-ol
4: 89 percent / imidazole / dimethylformamide / 0 °C
5: pyridine / CH2Cl2 / 2 h / Ambient temperature
6: pyridine / 4 h / Ambient temperature
7: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
8: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
9: NaOAc / methanol / 10 h / Heating
View Scheme
(2S,3S,4R)-4-Azido-1-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-phenyl)-pentane-2,3-diol

(2S,3S,4R)-4-Azido-1-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-phenyl)-pentane-2,3-diol

(-)-anisomycin
22862-76-6

(-)-anisomycin

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: pyridine / CH2Cl2 / 2 h / Ambient temperature
2: pyridine / 4 h / Ambient temperature
3: 91 percent / n-Bu4NF / tetrahydrofuran / 1 h / 0 °C
4: 90 percent / lithium bromide / acetic acid; tetrahydrofuran / 24 h / Ambient temperature
5: NaOAc / methanol / 10 h / Heating
View Scheme
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

(-)-anisomycin
22862-76-6

(-)-anisomycin

C19H27NO6
1262850-97-4

C19H27NO6

Conditions
ConditionsYield
With sodium hydrogencarbonate In tetrahydrofuran; water at 20℃; for 3h;100%
(-)-anisomycin
22862-76-6

(-)-anisomycin

propargyl bromide
106-96-7

propargyl bromide

(2R,3S,4S)-3-acetoxy-4-hydroxy-2-(4-methoxybenzyl)-1-propargylpyrrolidine

(2R,3S,4S)-3-acetoxy-4-hydroxy-2-(4-methoxybenzyl)-1-propargylpyrrolidine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 9h;95%
(-)-anisomycin
22862-76-6

(-)-anisomycin

benzyl bromide
100-39-0

benzyl bromide

(2R,3S,4S)-3-acetoxy-1-benzyl-4-hydroxy-2-(4-methoxybenzyl)-pyrrolidine
933992-79-1

(2R,3S,4S)-3-acetoxy-1-benzyl-4-hydroxy-2-(4-methoxybenzyl)-pyrrolidine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 4h;89%

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