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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: 1-Phenyl-2-propyn-1-one Synonyms: 3-oxo-3-phenylpropyne;1-PHENYLPROP-2-YN-1-ONE;1-Phenyl-2-propyn-1-one;1-Oxo-2-propynylbenzene;Benzoylacetylene;Propinoylbenzene;Propiolophenone;2-PROPYN-1-ONE,1-PHENYL CAS: 3623-15-

3623-15-2 1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 3623-15-2 with best quality

Cas:3623-15-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality moderate price & quick delivery Appearance:powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to make other chemic

2-Propyn-1-one,1-phenyl-

Cas:3623-15-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1-Phenylprop-2-yn-1-one 5g

Cas:3623-15-2

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

1-Phenyl-2-propyn-1-oneAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals a

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

1-Phenyl-2-propyn-1-one cas 3623-15-2Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1-Phenyl-2-propyn-1-one cas 3623-15-2

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

3623-15-2

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

1-Phenylprop-2-yn-1-one

Cas:3623-15-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and

1-phenylprop-2-yn-1-one

Cas:3623-15-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

1-Phenylprop-2-yn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Trading Company

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Sigma-Aldrich Chemie GmbH

Package:250 mg in glass bottle

1-Phenyl-2-propyn-1-one

Cas:3623-15-2

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With Jones reagent In acetone at 0℃; Jones Oxidation; Inert atmosphere;100%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 20℃; for 5h;99%
With sodium hypochlorite pentahydrate; 4-acetamido-2,2,6,6-tetramethylpiperidine-N-hydroxyammonium tetrafluoroborate In water; acetonitrile at 20℃; for 0.75h;99%
(E)-1-methoxy-4-(4-phenylbut-1-en-3-yn-1-yl)benzene
41790-90-3, 61172-18-7

(E)-1-methoxy-4-(4-phenylbut-1-en-3-yn-1-yl)benzene

A

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

B

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With oxygen; 5,15,10,20-tetraphenylporphyrin In chloroform Irradiation;A 83%
B 85%
(E)-1,4-Diphenylbut-1-en-3-yne
13343-79-8

(E)-1,4-Diphenylbut-1-en-3-yne

A

benzaldehyde
100-52-7

benzaldehyde

B

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With oxygen; 5,15,10,20-tetraphenylporphyrin In chloroform for 75h; Irradiation;A 80%
B 84%
propargyl benzene
10147-11-2

propargyl benzene

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With tert.-butylhydroperoxide; [copper(II)(salqu)] In acetonitrile at 70℃; for 4h;77%
With tetrachloromethane; di-tert-butyl chromate; acetic acid Reagens 4: Acetanhydrid;
With selenium(IV) oxide; ethanol
bis(p-chlorophenyl) diselenide
20541-49-5

bis(p-chlorophenyl) diselenide

1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

A

(Z)-2-(4-Chloro-phenylselanyl)-3-phenyl-propenal
105423-64-1

(Z)-2-(4-Chloro-phenylselanyl)-3-phenyl-propenal

B

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With sulfuric acid; tetraethylammonium perchlorate In water; acetonitrile at 65℃; for 14h; electrochemical oxidation;A 74%
B 12%
1,1-dichloro-3-ethoxy-3-phenylpropene
87406-35-7

1,1-dichloro-3-ethoxy-3-phenylpropene

A

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

B

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

C

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

D

(E)1-chloro-3,3-diethoxy-3-phenylpropene

(E)1-chloro-3,3-diethoxy-3-phenylpropene

Conditions
ConditionsYield
With sodium ethanolate In ethanol at 80℃; for 18h;A 72%
B n/a
C 18%
D 9%
benzaldehyde
100-52-7

benzaldehyde

acetylenemagnesium bromide
4301-14-8

acetylenemagnesium bromide

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Stage #1: benzaldehyde; acetylenemagnesium bromide In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere;
Stage #2: With chromium(VI) oxide; sulfuric acid In acetone at 0℃; for 3h; Inert atmosphere;
69%
Stage #1: benzaldehyde; acetylenemagnesium bromide Inert atmosphere;
Stage #2: With Jones reagent Inert atmosphere;
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

1,1-dichloro-3-ethoxy-3-phenylpropene
87406-35-7

1,1-dichloro-3-ethoxy-3-phenylpropene

B

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

C

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

D

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With sodium ethanolate for 18h; Heating; Further byproducts given;A 22%
B 2%
C 2%
D 59%
1-phenyl-2-(1H-tetrazol-5-yl)ethanone
355116-17-5

1-phenyl-2-(1H-tetrazol-5-yl)ethanone

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With lead(IV) acetate In 1,4-dioxane at 0℃; for 0.5h;53%
benzaldehyde
100-52-7

benzaldehyde

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

A

3-(trimethylsilyl)-1-phenyl-2-propyn-1-one
13829-77-1

3-(trimethylsilyl)-1-phenyl-2-propyn-1-one

B

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With indium(III) bromide; triethylamine In diethyl ether at 20℃; for 1h; Inert atmosphere; Sealed tube;
Stage #2: benzaldehyde In diethyl ether at 40℃; for 24h; Inert atmosphere; Sealed tube;
A 40%
B 10%
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

ethyl 3-phenyl-2-propenoate
103-36-6

ethyl 3-phenyl-2-propenoate

B

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

C

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

D

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With potassium hydroxide for 18h; Heating; Further byproducts given;A 2%
B 33%
C 5%
D 14%
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

3-Oxo-3-phenylpropanal 1-(diethylacetal)
36234-10-3

3-Oxo-3-phenylpropanal 1-(diethylacetal)

B

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

C

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

D

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With potassium hydroxide for 18h; Heating; Further byproducts given;A 2%
B 33%
C 5%
D 14%
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

phenylpropargyl aldehyde diethyl acetal
6142-95-6

phenylpropargyl aldehyde diethyl acetal

B

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

C

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

D

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With potassium hydroxide for 18h; Heating; Further byproducts given;A 8%
B 33%
C 5%
D 14%
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

3-ethoxy-3-phenyl-2-propenal
60355-48-8

3-ethoxy-3-phenyl-2-propenal

B

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

C

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

D

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With potassium hydroxide for 18h; Heating; Further byproducts given;A 2%
B 33%
C 5%
D 14%
ethanol
64-17-5

ethanol

1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

B

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

C

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

D

(E)1-chloro-3,3-diethoxy-3-phenylpropene

(E)1-chloro-3,3-diethoxy-3-phenylpropene

Conditions
ConditionsYield
With potassium hydroxide for 18h; Heating; Further byproducts given;A 33%
B 5%
C 14%
D 3%
1,1,1,3-tetrachloro-3-phenylpropane
23691-27-2

1,1,1,3-tetrachloro-3-phenylpropane

A

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

B

(Z)-β-chloro-1-phenyl propenone
15724-79-5

(Z)-β-chloro-1-phenyl propenone

C

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

D

(E)1-chloro-3,3-diethoxy-3-phenylpropene

(E)1-chloro-3,3-diethoxy-3-phenylpropene

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 18h; Heating; Further byproducts given;A 33%
B 5%
C 14%
D 3%
1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

A

3-phenyl-3-keto-propanol-di(1-phenyl-2-propyn-1-yl) acetal
86476-37-1

3-phenyl-3-keto-propanol-di(1-phenyl-2-propyn-1-yl) acetal

B

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
at 5℃; electrolysis: nickel net anode, cylindrical stainless steel cathode; electrolyte: 0.1M KOH/t-butanol - water (1:1);A 28%
B 4%
at 5℃; electrolysis: nickel net anode, cylindrical stainless steel cathode; electrolyte: KOH/t-butanol - water (1:1);A 28%
B 4%
tetrachloromethane
56-23-5

tetrachloromethane

propargyl benzene
10147-11-2

propargyl benzene

di-tert-butyl chromate
1189-85-1

di-tert-butyl chromate

acetic anhydride
108-24-7

acetic anhydride

acetic acid
64-19-7

acetic acid

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

3-(trimethylsilyl)-1-phenyl-2-propyn-1-one
13829-77-1

3-(trimethylsilyl)-1-phenyl-2-propyn-1-one

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With borax
With borax In methanol
Multi-step reaction with 2 steps
1: potassium carbonate / methanol / 2 h
2: chromium(VI) oxide; sulfuric acid / acetone; water / 0.33 h / 0 °C
View Scheme
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

1,1-dichloro-3-ethoxy-3-phenylpropene
87406-35-7

1,1-dichloro-3-ethoxy-3-phenylpropene

A

1-phenyl-propynone-diethylacetal
87406-33-5

1-phenyl-propynone-diethylacetal

B

1-phenyl-3-deuterioprop-2-yn-1-one
81060-96-0

1-phenyl-3-deuterioprop-2-yn-1-one

C

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

D

(E)1-chloro-3,3-diethoxy-3-phenylpropene

(E)1-chloro-3,3-diethoxy-3-phenylpropene

E

C11H11(2)HCl2O

C11H11(2)HCl2O

F

C13H16(2)HClO2

C13H16(2)HClO2

Conditions
ConditionsYield
With sodium ethanolate for 8h; Mechanism; Heating;
C9H5(3)HO
134817-20-2

C9H5(3)HO

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With water; hydrogenphosphate In tetrahydrofuran at 25℃; Rate constant;
C21H33BN2O

C21H33BN2O

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; hexane Ambient temperature; Yield given;
3,5,6,6-tetramethyl-3-(1-phenyl-3-methylsilanyl-1-trimethylsilanyloxyprop-2-ynyl)-3,6-dihydro[1,4]oxazin-2-one
245343-75-3

3,5,6,6-tetramethyl-3-(1-phenyl-3-methylsilanyl-1-trimethylsilanyloxyprop-2-ynyl)-3,6-dihydro[1,4]oxazin-2-one

A

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

B

3,5,6,6-tetramethyl-3,6-dihydro-[1,4]oxazin-2-one
245343-67-3

3,5,6,6-tetramethyl-3,6-dihydro-[1,4]oxazin-2-one

Conditions
ConditionsYield
With water; pyridinium p-toluenesulfonate Hydrolysis;
selenium(IV) oxide
7446-08-4

selenium(IV) oxide

ethanol
64-17-5

ethanol

propargyl benzene
10147-11-2

propargyl benzene

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

benzaldehyde
100-52-7

benzaldehyde

Fmoc-L-tert-leucine on Wang resin

Fmoc-L-tert-leucine on Wang resin

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0 - 20 °C
2: IBX / ethyl acetate; tetrahydrofuran / 80 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0 - 20 °C
2: IBX / ethyl acetate / 80 °C
View Scheme
benzaldehyde
100-52-7

benzaldehyde

(E)-n-C6H13CH=CHZrCp2Cl

(E)-n-C6H13CH=CHZrCp2Cl

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: diethyl ether / 0 °C
2: MnO2 / CH2Cl2 / 20 °C
View Scheme
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

α-methoxy-phenylacetic acid

α-methoxy-phenylacetic acid

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 72 percent / NaH / tetrahydrofuran / Heating
2: 86 percent / NaN3; AlCl3 / tetrahydrofuran / 5 h / Heating
3: 53 percent / Pb(OAc)4 / dioxane / 0.5 h / 0 °C
View Scheme
Benzoylacetonitrile
614-16-4

Benzoylacetonitrile

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 86 percent / NaN3; AlCl3 / tetrahydrofuran / 5 h / Heating
2: 53 percent / Pb(OAc)4 / dioxane / 0.5 h / 0 °C
View Scheme
benzoyl chloride
98-88-4

benzoyl chloride

(+-)-<4-isopropyl-benzylamino>-phenyl-acetonitrile

(+-)-<4-isopropyl-benzylamino>-phenyl-acetonitrile

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 °C
2: 3N HCl / tetrahydrofuran; hexane / Ambient temperature
View Scheme
((S)-1-carbamimidoyl-2-phenyl-ethyl)-carbamic acid tert-butyl ester
872459-79-5

((S)-1-carbamimidoyl-2-phenyl-ethyl)-carbamic acid tert-butyl ester

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

[(S)-2-phenyl-1-(4-phenyl-pyrimidin-2-yl)-ethyl]-carbamic acid tert-butyl ester
872459-80-8

[(S)-2-phenyl-1-(4-phenyl-pyrimidin-2-yl)-ethyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
With sodium carbonate In acetonitrile at 120℃; for 0.666667h; Microwave irradiation;100%
pyridinium tetrafluoroborate

pyridinium tetrafluoroborate

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C14H12NO(1+)*BF4(1-)

C14H12NO(1+)*BF4(1-)

Conditions
ConditionsYield
In methanol at 65℃;100%
(1Z,4RS,5RS)-4-(benzoylamino)-5-phenyl-1-(3,4,5-trimethoxybenzylidene)pyrazolidin-3-on-1-azomethine imine

(1Z,4RS,5RS)-4-(benzoylamino)-5-phenyl-1-(3,4,5-trimethoxybenzylidene)pyrazolidin-3-on-1-azomethine imine

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

rac-N-((1S,6R,7R)-2-benzoyl-5-oxo-7-phenyl-1-(3,4,5-trimethoxyphenyl)-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-6-yl)benzamide

rac-N-((1S,6R,7R)-2-benzoyl-5-oxo-7-phenyl-1-(3,4,5-trimethoxyphenyl)-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-6-yl)benzamide

Conditions
ConditionsYield
With copper In dichloromethane at 20℃; stereoselective reaction;100%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

N-methyl-p-toluenesulfonylamide
640-61-9

N-methyl-p-toluenesulfonylamide

(E)-N,4-dimethyl-N-(3-oxo-3-phenylprop-1-en-1-yl)benzenesulfonamide

(E)-N,4-dimethyl-N-(3-oxo-3-phenylprop-1-en-1-yl)benzenesulfonamide

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide In tetrahydrofuran; water at 20℃; Inert atmosphere;100%
With potassium carbonate In tetrahydrofuran at 80℃; Inert atmosphere;80%
phenylmethanethiol
100-53-8

phenylmethanethiol

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

3,3-bis(benzylmercapto)propiophenone
74896-60-9

3,3-bis(benzylmercapto)propiophenone

Conditions
ConditionsYield
With tributylphosphine In tetrahydrofuran99%
With 1-butyl-3-methylimidazolium hydroxide; 1-n-butyl-3-methylimidazolim bromide for 0.333333h;95%
benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

2,4-diphenylpyrimidine
25095-48-1

2,4-diphenylpyrimidine

Conditions
ConditionsYield
With sodium carbonate In acetonitrile at 120℃; for 0.666667h; microwave irradiation;99%
With sodium carbonate In acetonitrile at 120℃; for 0.666667h; Microwave irradiation;98%
3,5-dimethoxyphenol
500-99-2

3,5-dimethoxyphenol

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

chrysinidin dimethylether hexafluorophosphate

chrysinidin dimethylether hexafluorophosphate

Conditions
ConditionsYield
With hexafluorophosphoric acid In acetic acid at 20℃; for 48h;99%
With hexafluorophosphoric acid In acetic acid at 20℃;99%
C14H9NOS
161952-32-5

C14H9NOS

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C23H15NO2S
1253801-90-9

C23H15NO2S

Conditions
ConditionsYield
With triphenylphosphine In toluene at 20℃; Inert atmosphere; regioselective reaction;99%
2-benzoyl-3-phenylacrylonitrile
20413-05-2

2-benzoyl-3-phenylacrylonitrile

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C25H17NO2
1253801-70-5

C25H17NO2

Conditions
ConditionsYield
With triphenylphosphine In acetonitrile at 20℃; Inert atmosphere; regioselective reaction;99%
2-benzoyl-3-(2-furyl)prop-2-enenitrile
61222-94-4

2-benzoyl-3-(2-furyl)prop-2-enenitrile

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C23H15NO3
1253801-80-7

C23H15NO3

Conditions
ConditionsYield
With triphenylphosphine In toluene at 20℃; Inert atmosphere; regioselective reaction;99%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

(E)-2-Benzoyl-3-(4-bromo-phenyl)-acrylonitrile

(E)-2-Benzoyl-3-(4-bromo-phenyl)-acrylonitrile

C25H16BrNO2
1253801-82-9

C25H16BrNO2

Conditions
ConditionsYield
With triphenylphosphine In toluene at 20℃; Inert atmosphere; regioselective reaction;99%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

3-phenyloxindole
3456-79-9, 123742-97-2

3-phenyloxindole

C23H17NO2

C23H17NO2

Conditions
ConditionsYield
With C35H52N4O4; scandium tris(trifluoromethanesulfonate) In tetrahydrofuran; dichloromethane at 30℃; for 5h; Michael Addition; Molecular sieve; enantioselective reaction;99%
3-(4-fluorophenyl)indolin-2-one
282549-48-8

3-(4-fluorophenyl)indolin-2-one

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C23H16FNO2

C23H16FNO2

Conditions
ConditionsYield
With C35H52N4O4; scandium tris(trifluoromethanesulfonate) In tetrahydrofuran; dichloromethane at 30℃; for 3h; Michael Addition; Molecular sieve; enantioselective reaction;99%
3-(m-tolyl)indolin-2-one
1255502-42-1

3-(m-tolyl)indolin-2-one

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C24H19NO2

C24H19NO2

Conditions
ConditionsYield
With C35H52N4O4; scandium tris(trifluoromethanesulfonate) In tetrahydrofuran; dichloromethane at 30℃; for 5h; Michael Addition; Molecular sieve; enantioselective reaction;99%
3-(naphthalen-2-yl)indolin-2-one
1235862-81-3

3-(naphthalen-2-yl)indolin-2-one

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

C27H19NO2

C27H19NO2

Conditions
ConditionsYield
With C35H52N4O4; scandium tris(trifluoromethanesulfonate) In tetrahydrofuran; dichloromethane at 30℃; for 5h; Michael Addition; Molecular sieve; enantioselective reaction;99%
aminomalonic acid diethyl ester
6829-40-9

aminomalonic acid diethyl ester

1-benzyl-7-fluoroindoline-2,3-dione
1190109-45-5

1-benzyl-7-fluoroindoline-2,3-dione

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

(S)-diethyl 3'-benzoyl-1-benzyl-7-fluoro-2-oxospiro[indoline-3,2'-pyrrole]-5',5'(1'H)-dicarboxylate

(S)-diethyl 3'-benzoyl-1-benzyl-7-fluoro-2-oxospiro[indoline-3,2'-pyrrole]-5',5'(1'H)-dicarboxylate

Conditions
ConditionsYield
With (R)-3,3'-bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate In toluene at 25℃; for 36h; Molecular sieve; enantioselective reaction;99%
N-hydroxyphthalimide
524-38-9

N-hydroxyphthalimide

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

3-benzoyl-3a-hydroxy-3aH-1-oxa-8a-azacyclopenta[a]indene-8-one
1447925-07-6

3-benzoyl-3a-hydroxy-3aH-1-oxa-8a-azacyclopenta[a]indene-8-one

Conditions
ConditionsYield
With triphenylphosphine In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;99%
With triphenylphosphine In N,N-dimethyl-formamide at 20℃; for 1h;99%
C14H15Cl2NO4

C14H15Cl2NO4

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

diethyl 4-benzoyl-5-(3,4-dichlorophenyl)-1H-pyrrole-2,2(5H)-dicarboxylate
1325732-02-2

diethyl 4-benzoyl-5-(3,4-dichlorophenyl)-1H-pyrrole-2,2(5H)-dicarboxylate

Conditions
ConditionsYield
With (S,Sp)-R-Phosferrox; copper(II) acetate monohydrate; triethylamine In dichloromethane at 0℃; for 0.5h; Inert atmosphere; Molecular sieve; enantioselective reaction;99%
tert-butyl (E)-oct-2-en-1-yl-L-prolinate

tert-butyl (E)-oct-2-en-1-yl-L-prolinate

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

(R)-2-benzoyl-7a-((S)-oct-1-en-3-yl)-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

(R)-2-benzoyl-7a-((S)-oct-1-en-3-yl)-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

Conditions
ConditionsYield
In acetonitrile at 20℃; for 72h; Inert atmosphere; Darkness; enantioselective reaction;99%
tert-butyl allyl-L-prolinate

tert-butyl allyl-L-prolinate

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

(R)-7a-allyl-2-benzoyl-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

(R)-7a-allyl-2-benzoyl-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

Conditions
ConditionsYield
In acetonitrile at 60℃; for 48h; Inert atmosphere; Darkness; enantioselective reaction;99%
tert-butyl (E)-(3-(4-bromophenyl)allyl)-L-prolinate

tert-butyl (E)-(3-(4-bromophenyl)allyl)-L-prolinate

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

(R)-2-benzoyl-7a-((R)-1-(4-bromophenyl)allyl)-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

(R)-2-benzoyl-7a-((R)-1-(4-bromophenyl)allyl)-5,6,7,7a-tetrahydro-1H-pyrrolizin-1-one

Conditions
ConditionsYield
In acetonitrile at 20℃; for 72h; Inert atmosphere; Darkness; enantioselective reaction;99%
thiophenol
108-98-5

thiophenol

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

1-phenyl-3,3-bis(phenylthio)propan-1-one
42426-92-6

1-phenyl-3,3-bis(phenylthio)propan-1-one

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium hydroxide; 1-n-butyl-3-methylimidazolim bromide for 0.25h;98%
With lithium tert-butoxide In ethanol at 20℃; for 0.166667h;88%
With sodium acetate In tetrahydrofuran; water at 70℃; for 2.5h;80%
With N-benzyl-trimethylammonium hydroxide In methanol
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

3-phenyl-4-amino-5-mercapto-1,2,4-triazole
22706-11-2

3-phenyl-4-amino-5-mercapto-1,2,4-triazole

4-amino-3-(benzoylvinylthio)-5-phenyl-1,2,4-triazole
121033-63-4

4-amino-3-(benzoylvinylthio)-5-phenyl-1,2,4-triazole

Conditions
ConditionsYield
In methanol at 20℃; for 3h;98%
In methanol at 65℃; for 5h;84%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

ethanethiol
75-08-1

ethanethiol

β,β-diethylthioethyl phenyl ketone
74896-59-6

β,β-diethylthioethyl phenyl ketone

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium hydroxide; 1-n-butyl-3-methylimidazolim bromide for 0.333333h;98%
In ammonia for 1h;96%
With sodium acetate In tetrahydrofuran; water at 70℃; for 3h;75%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

1,3,5-tribenzoylbenzene
25871-69-6

1,3,5-tribenzoylbenzene

Conditions
ConditionsYield
dmap; acetylacetone In dichloromethane at 20℃; for 2h;98%
With t-butyl azide In 1,4-dioxane at 100℃; for 30h;64.3%
In N,N-dimethyl-formamide for 3h; Heating;57%
phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

phenyl(1H-1,2,3-triazol-4-yl)methanone
5955-92-0

phenyl(1H-1,2,3-triazol-4-yl)methanone

Conditions
ConditionsYield
With sodium azide In N,N-dimethyl acetamide at 55℃; for 0.666667h; microwave irradiation;98%
With sodium azide In N,N-dimethyl acetamide at 100℃; for 2h; Cycloaddition;95%
With sodium azide In N,N-dimethyl acetamide at 20 - 100℃; for 14h; Cycloaddition;95%
ethyl 3-aminobut-2-enoate
626-34-6

ethyl 3-aminobut-2-enoate

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

ethyl 2-methyl-6-phenylnicotinate
1702-14-3

ethyl 2-methyl-6-phenylnicotinate

Conditions
ConditionsYield
In acetic acid; toluene at 170℃; for 0.166667h; Product distribution; Further Variations:; Solvents; microwave irradiation; Bohlmann-Rahtz synthesis;98%
acetoacetamido
5977-14-0

acetoacetamido

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

2-methyl-6-phenylpyridine-3-carboxamide

2-methyl-6-phenylpyridine-3-carboxamide

Conditions
ConditionsYield
With ammonium acetate In ethanol for 24h; Bohlmann-Rahtz reaction; Heating;98%
With ammonium acetate In ethanol for 24h; Heating;98%
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

phenyl propargyl ketone
3623-15-2

phenyl propargyl ketone

2-(1,3-dithiolan-2-yl)-1-phenylethan-1-one
5653-29-2

2-(1,3-dithiolan-2-yl)-1-phenylethan-1-one

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium hydroxide; 1-n-butyl-3-methylimidazolim bromide for 0.25h;98%
With sodium acetate In tetrahydrofuran; water at 70℃; for 3.5h;74%

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