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hangzhou verychem science and technology co.ltd

White powder Package:200/Kilograms Application:Fine chemical intermediates Transportation:By sea Port:Shanghai/tianjin

Tris(2-cyanoethyl)phosphine

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Tris(2-cyanoethyl)phosphine

Cas:4023-53-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Tris(2-Cyanoethyl)Phosphine supplier in China

Cas:4023-53-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Tris(2-Cyanoethyl)Phosphine

Cas:4023-53-4

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Tris-(2-cyanoethyl)-phosphine

Cas:4023-53-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--4023-53-4--TRIS(2-CYANOETHYL)PHOSPHINE factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable busine

TIANFUCHEM--4023-53-4--TRIS(2-CYANOETHYL)PHOSPHINE factory price

Cas:4023-53-4

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

High purity 3,3',3''-phosphinidynetris-Propanenitrile 4023-53-4

Cas:4023-53-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Propanenitrile,3,3',3''-phosphinidynetris- 4023-53-4

Cas:4023-53-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

TRIS(2-CYANOETHYL)PHOSPHINE CAS:4023-53-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi

TRIS(2-CYANOETHYL)PHOSPHINE CAS:4023-53-4

Cas:4023-53-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Propanenitrile,3,3',3''-phosphinidynetris-

Cas:4023-53-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:1 Kilogram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Propanenitrile,3,3',3''-phosphinidynetris-

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Tris(2-Cyanoethyl)Phosphine

Cas:4023-53-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

High purity 3,3',3''-phosphinidynetris-Propanenitrile 4023-53-4

Cas:4023-53-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

High purity 3,3',3''-phosphinidynetris-Propanenitrile 4023-53-4

Cas:4023-53-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Product Name: TCEP tris (2-Cyanoethyl) phosphine synonyms:Tris-(2-cyanoethyl)phophine;Tris(2-cyanoethyl)phosphine; 3,3',3''-Phosphinetriyltripropanenitrile;AURORA KA-1114; CAS No.: 4023-53-4 Molecular for

TCEP tris (2-Cyanoethyl) phosphine

Cas:4023-53-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Tris(2-cyanoethyl)phosphine

Cas:4023-53-4

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Propanenitrile,3,3',3''-phosphinidynetris-

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Tris-(2-cyanoethyl)-phosphine

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Cyclopropanecarboxylic acid chloride

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Other

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Tris(2-cyanoethyl)phosphine

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Tris-(2-cyanoethyl)-phosphine

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

TRIS(2-CYANOETHYL)PHOSPHINE

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Propanenitrile,3,3',3''-phosphinidynetris-

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Tris(2-cyanoethyl)phosphine

Cas:4023-53-4

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

acrylonitrile
107-13-1

acrylonitrile

A

bis(2-cyanoethyl)phosphine
4023-49-8

bis(2-cyanoethyl)phosphine

B

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

C

tris(2-cyanoethyl)phosphine oxide
1439-41-4

tris(2-cyanoethyl)phosphine oxide

Conditions
ConditionsYield
With potassium hydroxide; phosphan In water; acetonitrile for 1h; Ambient temperature;A 15 % Spectr.
B 45%
C 15 % Spectr.
With phosphorus; potassium hydroxide In water; acetonitrile at 20 - 70℃; for 0.166667h; Irradiation; sonication;A 10 % Spectr.
B 30 % Spectr.
C 60 % Spectr.
acrylonitrile
107-13-1

acrylonitrile

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

Conditions
ConditionsYield
With potassium hydroxide; phosphan; acetonitrile
With phosphan
acrylonitrile
107-13-1

acrylonitrile

A

bis(2-cyanoethyl)phosphine
4023-49-8

bis(2-cyanoethyl)phosphine

B

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

C

3-phosphanyl-propionitrile
6783-71-7

3-phosphanyl-propionitrile

Conditions
ConditionsYield
With {(tris(cyanomethyl)phosphine)3platinum}; phosphan In acetonitrile at 20℃; for 1h; Product distribution; Mechanism;
With aluminum oxide; potassium hydroxide; phosphan Product distribution; influence of varying degrees of dryness of solid support;
With phosphan; In acetonitrile
bis(2-cyanoethyl)phosphine
4023-49-8

bis(2-cyanoethyl)phosphine

acrylonitrile
107-13-1

acrylonitrile

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

Conditions
ConditionsYield
In acetonitrile
acrylonitrile
107-13-1

acrylonitrile

acetonitrile
75-05-8

acetonitrile

phosphine

phosphine

aqueous KOH-solution

aqueous KOH-solution

A

bis(2-cyanoethyl)phosphine
4023-49-8

bis(2-cyanoethyl)phosphine

B

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

C

3-phosphanyl-propionitrile
6783-71-7

3-phosphanyl-propionitrile

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[Pt(C8H12)(C3H4NO)2]
188638-31-5

[Pt(C8H12)(C3H4NO)2]

[Pt(C3H4NO)2(P(CH2CH2CN)3)2]
188638-33-7

[Pt(C3H4NO)2(P(CH2CH2CN)3)2]

Conditions
ConditionsYield
In dichloromethane pptn. with light petroleum, filtration, washing (light petroleum), drying (vac.); elem. anal.;100%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

3-(perfluorooctyl)propyl iodide
200112-75-0

3-(perfluorooctyl)propyl iodide

tris-(2-cyano-ethyl)-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-undecyl)-phosphonium; iodide

tris-(2-cyano-ethyl)-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-undecyl)-phosphonium; iodide

Conditions
ConditionsYield
at 130 - 160℃; for 11h;99.8%
[Fe2(CO)6(μ-PhC=CH2)(μ-PPh2)]

[Fe2(CO)6(μ-PhC=CH2)(μ-PPh2)]

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

Fe2(CO)5(P(CH2CH2CN)3)(HCCHC6H5)P(C6H5)2
337380-82-2

Fe2(CO)5(P(CH2CH2CN)3)(HCCHC6H5)P(C6H5)2

Conditions
ConditionsYield
In toluene byproducts: CO; (N2); refluxing a soln. of iron complex and phosphine in toluene for 20 min, cooling to room temp.; chromy (deactivated Al2O3, Et2O/light petroleum 2:3); elem. anal.;98%
bis(benzonitrile)palladium(II) dichloride
15617-18-2, 39958-10-6, 14220-64-5

bis(benzonitrile)palladium(II) dichloride

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

trans-PdCl2(tris(cyanoethyl)phosphine)2
204461-54-1, 68494-75-7

trans-PdCl2(tris(cyanoethyl)phosphine)2

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; dropwise addn. of 2 equiv. of phosphine to Pd-complex soln., stirring for 10 min (pptn.); filtration, washing (CH2Cl2), drying (vac.); elem. anal.;98%
(1,5-cyclooctadiene)dimethylplatinum(II)

(1,5-cyclooctadiene)dimethylplatinum(II)

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

cis-PtMe2(tris(cyanoethyl)phosphine)2
204391-74-2

cis-PtMe2(tris(cyanoethyl)phosphine)2

Conditions
ConditionsYield
In acetone N2-atmosphere; dropwise addn. of ligand soln. to 0.5 equiv. of Pt-complex soln., stirring for 10 min; concn., pptn. on Et2O addn., filtration, washing (Et2O), drying (vac.); elem. anal.;97%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

{tris(2-cyanoethyl)phosphine}gold(I) chloride
148100-44-1

{tris(2-cyanoethyl)phosphine}gold(I) chloride

Conditions
ConditionsYield
In dichloromethane; acetonitrile N2; equimolar amounts; stirring for 1 h at room temperature;; precipitation upon addn. of diethyl ether;;95%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

bis(4-formylphenyl) azidothiophosphonate
156457-81-7

bis(4-formylphenyl) azidothiophosphonate

C23H22N4O4P2S

C23H22N4O4P2S

Conditions
ConditionsYield
In acetonitrile Ambient temperature;94%
dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

trans-PtCl2(tris(cyanoethyl)phosphine)2
20699-88-1

trans-PtCl2(tris(cyanoethyl)phosphine)2

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; dropwise addn. of ligand soln. to 0.5 equiv. of Pt-complex soln. (pptn.); filtration, washing (CH2Cl2), drying (vac.);93%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[PdCl(η(3)-allyl)]2

[PdCl(η(3)-allyl)]2

PdCl(tris(cyanoethyl)phosphine)(η(3)-allyl)

PdCl(tris(cyanoethyl)phosphine)(η(3)-allyl)

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring stoich. amts. for 10 min; concn., pptn. on Et2O addn., filtration, washing (Et2O), drying (vac.); elem. anal.;93%
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium
12092-47-6

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

RhCl(tris(cyanoethyl)phosphine)(COD)
204391-82-2

RhCl(tris(cyanoethyl)phosphine)(COD)

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring Rh-complex with 2 equiv. of phosphine for 15 min; concn., pptn. on Et2O addn.; elem. anal.;93%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

trans-PdCl2(tris(cyanoethyl)phosphine)2
204461-54-1, 68494-75-7

trans-PdCl2(tris(cyanoethyl)phosphine)2

Pd(tris(cyanoethyl)phosphine)3
200437-22-5

Pd(tris(cyanoethyl)phosphine)3

Conditions
ConditionsYield
With LiOMe In methanol; ethanol N2-atmosphere; addn. of 4 equiv. of 0.1 M LiOMe (in MeOH) to EtOH, then addn. of 1 equiv. of Pd-complex and 2 equiv. phosphine, refluxing for 2 h (pptn.); filtration, washing (Et2O), drying (vac.); elem. anal.;92%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

3-bromo-1,2-naphthoquinone
7474-83-1

3-bromo-1,2-naphthoquinone

A

tris(2-cyanoethyl)phosphine oxide
1439-41-4

tris(2-cyanoethyl)phosphine oxide

B

3-bromo-1,2-dihydroxynaphthalene
61978-07-2

3-bromo-1,2-dihydroxynaphthalene

Conditions
ConditionsYield
With water In dichloromethane for 24h; Inert atmosphere;A 92%
B 80%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

tetrakis(acetato)dimolybdenum(II)
14221-06-8, 744215-74-5

tetrakis(acetato)dimolybdenum(II)

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[Mo2Cl4(tris(β-cyanoethyl)phosphine)2]x

[Mo2Cl4(tris(β-cyanoethyl)phosphine)2]x

Conditions
ConditionsYield
In toluene N2-atmosphere; dropwise addn. of excess Me3SiCl to stoich. mixt. of Mo-compd. and ligand, stirring at room temp. for >= 2 d (pptn.); collection (filtration), washing (PhMe, 40°C; hexanes at room temp.; Et2O), drying (vac., room temp., >=12 h); elem. anal.;90%
In tetrahydrofuran N2-atmosphere; dropwise addn. of excess Me3SiCl to stoich. mixt. of Mo-compd. and ligand, stirring at room temp. for >= 2 d (pptn.); collection (filtration), washing (PhMe, 40°C; hexanes at room temp.; Et2O), drying (vac., room temp., >=12 h);90%
In benzene N2-atmosphere; dropwise addn. of excess Me3SiCl to stoich. mixt. of Mo-compd. and ligand, stirring at room temp. for >= 2 d (pptn.); collection (filtration), washing (PhMe, 40°C; hexanes at room temp.; Et2O), drying (vac., room temp., >=12 h);90%
nickel(II) chloride hexahydrate

nickel(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

cobalt(II) chloride hexahydrate

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

[Ni0.5Co0.5Cl2(P(CH2CH2CN)3)2]x

Conditions
ConditionsYield
In ethanol; acetone EtOH:acetone:triethyl orthoformate=6:5:1, equimolar amts. of metal salts, excess of ligand, ambient temp. (pptn., then dissoln. of Ni-complex, crystn. of mixt. of products on slow evapn.); mixt. of products not separated;A 8%
B 90%
C 2%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

{Co(CNC(CH3)3)4H2O}(2+)*2(ClO4)(1-)={Co(CNC(CH3)3)4H2O}(ClO4)2

{Co(CNC(CH3)3)4H2O}(2+)*2(ClO4)(1-)={Co(CNC(CH3)3)4H2O}(ClO4)2

{Co(CNC(CH3)3)3(P(C2H4CN)3)2}(1+)*(ClO4)(1-)={Co(CNC(CH3)3)3(P(C2H4CN)3)2}(ClO4)
101190-22-1

{Co(CNC(CH3)3)3(P(C2H4CN)3)2}(1+)*(ClO4)(1-)={Co(CNC(CH3)3)3(P(C2H4CN)3)2}(ClO4)

Conditions
ConditionsYield
In acetonitrile at 0°C;; recrystallization from methylene dichloride and ether, elem. anal.;89%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

tris-(2-carboxyethyl)-phosphine hydrochloride
51805-45-9

tris-(2-carboxyethyl)-phosphine hydrochloride

Conditions
ConditionsYield
With hydrogenchloride for 2h; Heating;88%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

tris(bicyclo[2.2.1]heptene)platinum(0)

tris(bicyclo[2.2.1]heptene)platinum(0)

{(tris(cyanomethyl)phosphine)3platinum}
132199-05-4

{(tris(cyanomethyl)phosphine)3platinum}

Conditions
ConditionsYield
In acetone; toluene N2-atmosphere; dropwise addn. of 3 equiv. of phosphine (in Me2CO) to Pt-complex soln. (in PhMe, pptn.), stirring for 3 h; filtration, dissoln. in Me2CO, pptn. on PhMe addn.; elem. anal.;86%
tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

silver nitrate

silver nitrate

bis[tris(2-cyanoethyl)phosphine]silver(I) nitrate
172915-72-9

bis[tris(2-cyanoethyl)phosphine]silver(I) nitrate

Conditions
ConditionsYield
In ethanol; acetonitrile addn. of AgNO3 (in hot MeCN) to 2 equiv. of ligand (in warm EtOH); crystn. on slow cooling (in dark); elem. anal.;85%
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

Tris(pyrazolyl)methane
80510-03-8

Tris(pyrazolyl)methane

[Cu{tris(pyrazol-1-yl)methane}(tris(2-cyanoethyl)phosphine)][BF4]

[Cu{tris(pyrazol-1-yl)methane}(tris(2-cyanoethyl)phosphine)][BF4]

Conditions
ConditionsYield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; tris(2-cyanoethyl)phosphine In acetonitrile for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: Tris(pyrazolyl)methane In acetonitrile for 4h; Schlenk technique; Inert atmosphere;
85%
{Ni(η-CH3C5H4)((C6H5)2PCH2CH2P(C6H5)2)}NCS

{Ni(η-CH3C5H4)((C6H5)2PCH2CH2P(C6H5)2)}NCS

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

{Ni(η-CH3C5H4)((C6H5)2PCH2CH2P(C6H5)2)(P(CH2CH2CN)3)}NCS

{Ni(η-CH3C5H4)((C6H5)2PCH2CH2P(C6H5)2)(P(CH2CH2CN)3)}NCS

Conditions
ConditionsYield
In acetone addn. of phosphine soln. to stirred Ni complex soln. under N2; stirring, 4h; concentratin; addn. of hexane; pptn.; filtration; washing (Et2O); elem. anal.;84%
tetrachloronitridotechnatate(VI) tetra-n-butylammonium

tetrachloronitridotechnatate(VI) tetra-n-butylammonium

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

(Bu4N){TcNCl3(tri(2-cyanoethyl)phosphine)}

(Bu4N){TcNCl3(tri(2-cyanoethyl)phosphine)}

Conditions
ConditionsYield
In acetone refluxing (1 h); pptn. on concn., addn. of MeOH and cooling; elem. anal.;83%
copper(l) iodide
7681-65-4

copper(l) iodide

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[CuI(tris(2-cyanoethyl)phosphine)]n

[CuI(tris(2-cyanoethyl)phosphine)]n

Conditions
ConditionsYield
In acetonitrile for 0.333333h; Reflux; Inert atmosphere;83%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

[Cu(tris(2-cyanoethyl)phosphine)2]n(PF6)n

[Cu(tris(2-cyanoethyl)phosphine)2]n(PF6)n

Conditions
ConditionsYield
In acetonitrile for 1h; Reflux; Inert atmosphere;83%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

trans-RhCl(CO)(tris(cyanoethyl)phosphine)2 * 0.5 Me2CO

trans-RhCl(CO)(tris(cyanoethyl)phosphine)2 * 0.5 Me2CO

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring Rh-complex with 4 equiv. of phosphine for 40 min; evapn.; elem. anal.;82%
chloro(1,5-cyclooctadiene)iridium(I) dimer

chloro(1,5-cyclooctadiene)iridium(I) dimer

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

IrCl(tris(cyanoethyl)phosphine)(COD)
204391-83-3

IrCl(tris(cyanoethyl)phosphine)(COD)

Conditions
ConditionsYield
In acetone N2-atmosphere; stirring Ir-complex with 2 equiv. of phosphine for 15 min; concn., pptn. on Et2O addn.; elem. anal.;82%
dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

PtCl2(CO)P(CH2CH2CN)3
111046-55-0

PtCl2(CO)P(CH2CH2CN)3

Conditions
ConditionsYield
With carbon monoxide In chloroform CO was bubbled through a soln. of Pt-complex in CHCl3 for 1 h, a soln. of the phosphine in hot CHCl3 was added dropwise over 30 min with stirring; ppt. was washed with CHCl3, recrystd. from acetone-propan-2-ol; elem. anal.;81%
[RuCl(η(5)-C5H4Me)(PPh3)2]
55272-36-1

[RuCl(η(5)-C5H4Me)(PPh3)2]

tris(2-cyanoethyl)phosphine
4023-53-4

tris(2-cyanoethyl)phosphine

(C5H4CH3)RuCl(P(CH2CH2CN)3)2

(C5H4CH3)RuCl(P(CH2CH2CN)3)2

Conditions
ConditionsYield
In acetone N2 atmosphere; refluxing (1 h); concn. of aoln., pptn. (addn. of chloroform); elem. anal.;79%
In toluene N2 atmosphere; refluxing (1.5 h), pptn.; dissolution (acetone), repptn. (addn. of chloroform); elem. anal.;79%

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