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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4-Bromo-3-fluorotoluene Manufacturer/High quality/Best price/In stock

Cas:452-74-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Colorless or slightly yellow liquid Conforms Water ≤0.5%

Top purity 4-Bromo-3-fluorotoluene with high quality and best price cas:452-74-4

Cas:452-74-4

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Bromo-3-Fluorotoluene

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Our Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance: Clear light yellow Liquid Storage:Sealed,

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Bromo-3-Fluorotoluene

Cas:452-74-4

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 452-74-4 4-Bromo-3-fluorotoluene Manufacturer

Cas:452-74-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

4-bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

4-Bromo-3-fluorotoluene Basic information Product Name: 4-Bromo-3-fluorotoluene Synonyms: 3-FLUORO-4-BROMO-TOLUENE;4-BROMO-3-FLUOROTOLUENE;4-Bromo-3-fluorotoluene,9

4-Bromo-3-fluorotoluene 452-74-4

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 452-74-4 with fast shipping

Cas:452-74-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

4-Bromo-3-fluorotoluene/ LIDE PHARMA- Factory supply / Best price

Cas:452-74-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Name: 4-Bromo-3-fluorotoluene Synonyms: 3-Fluoro-4-bromotoluene CAS:452-74-4 MF: C7H6BrF Appearance:Colorless to yellowish liquid Storage: Preserve in well-closed, light-resistant and airtight containers. Package: 25kgs/drum Application:Pharma

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-2-fluoro-4-methyl- 452-74-4

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At presen

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:10 Gram

FOB Price: $2.0 / 3.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

4-Bromo-3-fluorotoluene CAS:452-74-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

4-Bromo-3-fluorotoluene CAS:452-74-4

Cas:452-74-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-2-fluoro-4-methyl-

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-bromo-2-fluoro-4-methyl-

Cas:452-74-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Bromo-3-Fluorotoluene

Cas:452-74-4

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Bromo-3-fluorotoluen

Cas:452-74-4

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Bromo-3-Fluorotoluene

Cas:452-74-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

Top supplier 4-Bromo-3-fluorotoluene 452-74-4 in China

Cas:452-74-4

Min.Order:1 Gram

Negotiable

Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless to light yellow liquid Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation:as per y

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 4-Bromo-3-Fluorotoluene CAS No.:452-74-4 Molecule Formula:C7H6BrF Molecule Weight:189.02 Purity: 98.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING I

High Quality 4-Bromo-3-Fluorotoluene on stock

Cas:452-74-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Bromo-3-fluorotoluene Synonyms: 4-BROMO-3-FLUOROTOLUENE;3-FLUORO-4-BROMO-TOLUENE;4-Bromo-3-fluorotoluene,98+%;4-Bromo-3-fluorotoluene 98%;4-Bromo-3-fluoro-1-methylbenzene;4-Bromo-3-flurotoluene;3-FLUORO-4-BROMO-TOLUONE;4-BroMo-3

3-Fluoro-4-bromotoluene 452-74-4 C7H6BrF

Cas:452-74-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-Bromo-3-fluorotoluene

Cas:452-74-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Synthetic route

2,6-dibromo-3-fluorotoluene

2,6-dibromo-3-fluorotoluene

2,4-dibromo-5-fluorotoluene
93765-84-5

2,4-dibromo-5-fluorotoluene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen; sodium acetate In methanol at 75 - 80℃; under 16501.7 Torr; for 10h; Pressure; Solvent; Temperature; Autoclave;92%
2-bromo-5-methylaniline
53078-85-6

2-bromo-5-methylaniline

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Stage #1: 2-bromo-5-methylaniline With hydrogenchloride; sodium tetrafluoroborate; sodium nitrite
Stage #2: Schiemann reaction; Heating;
57.7%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

A

2-Bromo-5-fluorotoluene
452-63-1

2-Bromo-5-fluorotoluene

B

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
With tetrachloromethane; iron Bromierung;
4-methyl-2-nitroaniline
89-62-3

4-methyl-2-nitroaniline

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multistep reaction;
2-bromo-5-methyl benzenediazonium tetrafluoroborate

2-bromo-5-methyl benzenediazonium tetrafluoroborate

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
(heating);
tetrachloromethane
56-23-5

tetrachloromethane

m-Fluorotoluene
352-70-5

m-Fluorotoluene

bromine
7726-95-6

bromine

iron-powder

iron-powder

A

2-Bromo-5-fluorotoluene
452-63-1

2-Bromo-5-fluorotoluene

B

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

m-Fluorotoluene
352-70-5

m-Fluorotoluene

A

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

B

5-fluoro-2-bromo-1-methyl-benzene

5-fluoro-2-bromo-1-methyl-benzene

Conditions
ConditionsYield
With tetrachloromethane; iron Bromierung;
4-Bromo-3-nitrotoluene
5326-34-1

4-Bromo-3-nitrotoluene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 84.9 percent / Fe; CH3COOH
2.1: HCl; NaBF4; NaNO2
2.2: 57.7 percent / Heating
View Scheme
4-methyl-2-nitroacetanilide
612-45-3

4-methyl-2-nitroacetanilide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 99.4 percent / Claisen's base
2.1: H2SO4; NaNO2
2.2: 51.8 percent / Cu2Br2
3.1: 84.9 percent / Fe; CH3COOH
4.1: HCl; NaBF4; NaNO2
4.2: 57.7 percent / Heating
View Scheme
4-methyl-2-nitroaniline
89-62-3

4-methyl-2-nitroaniline

MCN

MCN

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: H2SO4; NaNO2
1.2: 51.8 percent / Cu2Br2
2.1: 84.9 percent / Fe; CH3COOH
3.1: HCl; NaBF4; NaNO2
3.2: 57.7 percent / Heating
View Scheme
methylmagnesium bromide
75-16-1

methylmagnesium bromide

4-bromo-3-fluoroiodobenzene
136434-77-0

4-bromo-3-fluoroiodobenzene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
With C72H63P6Pd3(1+)*I(1-) In tetrahydrofuran; toluene at 20℃; Inert atmosphere; Glovebox; chemoselective reaction;89 %Spectr.
2-Bromo-5-fluorotoluene
452-63-1

2-Bromo-5-fluorotoluene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: iron; bromine / 1,2-dichloro-ethane / 2.5 h / 30 - 35 °C
2: sodium acetate; 5%-palladium/activated carbon; hydrogen / methanol / 10 h / 75 - 80 °C / 16501.7 Torr / Autoclave
View Scheme
m-Fluorotoluene
352-70-5

m-Fluorotoluene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: iron; bromine / 1,2-dichloro-ethane / 10 h / 30 - 35 °C
2: sodium acetate; 5%-palladium/activated carbon; hydrogen / methanol / 10 h / 75 - 80 °C / 16501.7 Torr / Autoclave
View Scheme
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

copper(I) cyanide
544-92-3

copper(I) cyanide

2-fluoro-4-methylbenzonitrile
85070-67-3

2-fluoro-4-methylbenzonitrile

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 24h; Heating;100%
In N,N-dimethyl-formamide for 5h; Heating;94%
In N,N-dimethyl-formamide for 24h; Heating / reflux;88%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3-bromo-4-fluoro-6-methylnitrobenzene
224185-19-7

3-bromo-4-fluoro-6-methylnitrobenzene

Conditions
ConditionsYield
With sulfuric acid; potassium nitrate at 0 - 20℃;100%
With sulfuric acid; potassium nitrate at 0℃;100%
With sulfuric acid; nitric acid at 0℃;92%
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

benzamidine monohydrochloride
1670-14-0

benzamidine monohydrochloride

7-methyl-2-phenylquinazoline-4(3H)-one

7-methyl-2-phenylquinazoline-4(3H)-one

Conditions
ConditionsYield
With palladium diacetate; N-ethyl-N,N-diisopropylamine; catacxium A In N,N-dimethyl acetamide at 140℃; under 7500.75 Torr; for 22h; Inert atmosphere; Autoclave;99%
1,3-thiazole
288-47-1

1,3-thiazole

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

5-(2-fluoro-4-methylphenyl)thiazole

5-(2-fluoro-4-methylphenyl)thiazole

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; catacxium A; Trimethylacetic acid In N,N-dimethyl acetamide at 110℃; for 16h; Inert atmosphere;99%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-fluoro-4-methylphenylboronic acid
170981-26-7

2-fluoro-4-methylphenylboronic acid

Conditions
ConditionsYield
97%
With n-butyllithium; triethyl borate In tetrahydrofuran; hexane at -70 - 20℃; for 19h;75%
With n-butyllithium; Triisopropyl borate In tetrahydrofuran; hexane; toluene at -40℃; for 2h;
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

dicyanozinc
557-21-1

dicyanozinc

2-fluoro-4-methylbenzonitrile
85070-67-3

2-fluoro-4-methylbenzonitrile

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 80℃;96%
tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 80℃; for 3h;96%
trifluoroethylamine
753-90-2

trifluoroethylamine

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

C9H9F4N

C9H9F4N

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); 5-(di(adamantan-1-yl)phosphino)-1′,3′,5′-triphenyl-1′H-1,4′-bipyrazole; potassium phenolate In 1,4-dioxane at 100℃; for 6h; Sealed tube; Inert atmosphere;96%
benzoimidazole
51-17-2

benzoimidazole

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

1-(2-bromo-5-methylphenyl)benzimidazole

1-(2-bromo-5-methylphenyl)benzimidazole

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 150℃;96%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

4-bromo-3-fluorobenzoic acid
153556-42-4

4-bromo-3-fluorobenzoic acid

Conditions
ConditionsYield
With pyridine; potassium permanganate for 40h; Heating;94%
With pyridine; potassium permanganate at 90℃;88%
Stage #1: 4-bromo-3-fluorotoluene With pyridine; potassium permanganate; water at 90℃; for 3h;
Stage #2: With sodium hydroxide In water
Stage #3: With hydrogenchloride In water pH=2;
73%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

sodium cyanoacetate
1071-36-9

sodium cyanoacetate

2-(2-fluoro-4-methylphenyl)acetonitrile
518070-26-3

2-(2-fluoro-4-methylphenyl)acetonitrile

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(η3-allyl-μ-chloropalladium(II)) In 1,3,5-trimethyl-benzene at 20 - 140℃; for 5.16667h; Inert atmosphere; Sealed tube; chemoselective reaction;91%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

1-bromo-4-(bromomethyl)-2-fluorobenzene
127425-73-4

1-bromo-4-(bromomethyl)-2-fluorobenzene

Conditions
ConditionsYield
With N-Bromosuccinimide; dibenzoyl peroxide In acetonitrile for 3h; Reflux;90%
With N-Bromosuccinimide; dibenzoyl peroxide In acetonitrile for 3h; Reflux;90%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3.5h; Reflux;80%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(2-fluoro-4-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1165936-03-7

2-(2-fluoro-4-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With bis[di-t-butyl(p-dimethylaminophenyl)phosphino]palladium (II) Dichloride; potassium propionate In ethyl acetate Suzuki Coupling; Reflux;90%
With 10H-phenothiazine; caesium carbonate In acetonitrile for 24h; Irradiation; Sealed tube; Inert atmosphere;65%
With potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In DMF (N,N-dimethyl-formamide) at 20 - 80℃; for 16h;
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-Hydroxy-4-methylanilin
2835-98-5

2-Hydroxy-4-methylanilin

3,7-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

3,7-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;87%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3,4-dichlophenylboronic acid
151169-75-4

3,4-dichlophenylboronic acid

3',4'-dichloro-2-fluoro-4-methyl-biphenyl
1200722-42-4

3',4'-dichloro-2-fluoro-4-methyl-biphenyl

Conditions
ConditionsYield
With sodium carbonate; palladium 10% on activated carbon In ethanol for 4h; Suzuki Coupling; Reflux; Inert atmosphere;86%
carbon monoxide
201230-82-2

carbon monoxide

2-amino-4-fluorophenol
399-97-3

2-amino-4-fluorophenol

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

8-fluoro-3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one

8-fluoro-3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;85%
potassium 2-(pyridin-2-yl)acetate
106966-98-7

potassium 2-(pyridin-2-yl)acetate

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-(2-fluoro-4-methylbenzyl)pyridine
1251919-74-0

2-(2-fluoro-4-methylbenzyl)pyridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In diethylene glycol dimethyl ether at 150℃; for 24h; Inert atmosphere;82%
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3-amino-4-hydroxytoluene
95-84-1

3-amino-4-hydroxytoluene

3,8-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

3,8-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;81%
3-Sulfolene
77-79-2

3-Sulfolene

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

C11H11F

C11H11F

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); potassium tert-butylate; potassium hydrogencarbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In tetrahydrofuran at 110℃; diastereoselective reaction;81%
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-hydroxy-5-chloro-aniline
95-85-2

2-hydroxy-5-chloro-aniline

8-chloro-3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one

8-chloro-3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;80%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

pentan-3-one
96-22-0

pentan-3-one

3-(2-fluoro-4-methyl-phenyl)-pentan-3-ol
737800-46-3

3-(2-fluoro-4-methyl-phenyl)-pentan-3-ol

Conditions
ConditionsYield
Stage #1: 4-bromo-3-fluorotoluene With n-butyllithium In hexanes; diethyl ether at -78℃; for 2.17h;
Stage #2: pentan-3-one In hexanes; diethyl ether at -78 - 20℃; for 12h;
77%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

C15H15F
1453806-84-2

C15H15F

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water at 70℃; for 24h; Inert atmosphere;75%
2-aminopyridine
504-29-0

2-aminopyridine

carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3-methyl-11H-pyrido[2,1-b]quinazoline-11-one
70354-44-8

3-methyl-11H-pyrido[2,1-b]quinazoline-11-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In N,N-dimethyl acetamide at 120℃; under 11251.1 Torr; for 16h; Inert atmosphere; Autoclave;75%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-chloro-4-methyl-benzaldehyde
50817-80-6

2-chloro-4-methyl-benzaldehyde

2-chloro-2’-fluoro-4,4’-dimethylbenzhydrol

2-chloro-2’-fluoro-4,4’-dimethylbenzhydrol

Conditions
ConditionsYield
Stage #1: 4-bromo-3-fluorotoluene With n-butyllithium In diethyl ether; hexane at -78℃; for 0.166667h;
Stage #2: 2-chloro-4-methyl-benzaldehyde In diethyl ether; hexan-1-ol at -78℃; for 0.333333h;
75%
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2-amino-phenol
95-55-6

2-amino-phenol

3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one
3158-86-9

3-methyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;74%
phenyl benzyl ketone
451-40-1

phenyl benzyl ketone

carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

7-methyl-2,3-diphenyl-4H-chromen-4-one

7-methyl-2,3-diphenyl-4H-chromen-4-one

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; caesium carbonate In N,N-dimethyl acetamide at 120℃; under 7500.75 Torr; for 20h; Autoclave;74%
2-fluoro-4-methylphenylboronic acid
170981-26-7

2-fluoro-4-methylphenylboronic acid

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

2,2'-difluoro-4,4'-dimethyl-1,1'-biphenyl
388-83-0

2,2'-difluoro-4,4'-dimethyl-1,1'-biphenyl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; water; toluene for 15h; Inert atmosphere; Reflux;73%
2-amino-3-methylphenol
2835-97-4

2-amino-3-methylphenol

carbon monoxide
201230-82-2

carbon monoxide

4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

3,9-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

3,9-dimethyldibenzo[b,f][1,4]oxazepin-11(10H)-one

Conditions
ConditionsYield
With palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; catacxium A In dimethyl sulfoxide at 120℃; for 24h;72%
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

copper(l) cyanide

copper(l) cyanide

2-fluoro-4-methylbenzonitrile
85070-67-3

2-fluoro-4-methylbenzonitrile

Conditions
ConditionsYield
In N,N-dimethyl-formamide70%
In DMF (N,N-dimethyl-formamide) for 12h; Heating / reflux;
4-bromo-3-fluorotoluene
452-74-4

4-bromo-3-fluorotoluene

sodium methylate
124-41-4

sodium methylate

1-bromo-2-methoxy-4-methylbenzene
95740-49-1

1-bromo-2-methoxy-4-methylbenzene

Conditions
ConditionsYield
In dimethyl sulfoxide for 16h; Inert atmosphere; Reflux; Schlenk technique;70%
In dimethyl sulfoxide at 130℃; for 12h;65.8%

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