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inquiryAppearance:Dark red oil-soluble liquid Storage:Room temperature Package:25kg/Barrel Application:Colorant Transportation:Express/Sea/Air Port:Any port in china
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inquirysupplier in China Appearance:white powder Storage:Keep away of light,cool place Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:antineoplastic Transportation:BY SEA Port:Shanghai, Ningbo, Tianjin, etc
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CAPSANTHIN Basic information Product Name: CAPSANTHIN Synonyms: PAPRIKA EXTRACT;BETA,KAPPA-CAROTEN-6'-ONE, 3,3'-DIHYDROXY-, (3R,3'S,5'R)-;CAPSANTHIN;3,3'-DIHYDROXY-BE
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inquiryOur Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an
GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
(2E,4E,6E,8E,10E,12E)-14[(1R,4S)-4-hydroxy-1,2,2-trimethylcyclopentyl]-2,7,11-trimethyl-14-oxotetradeca-2,4,6,8,10,12-hexaenal
capsanthin
Conditions | Yield |
---|---|
With sodium methylate | 42% |
capsanthin
Conditions | Yield |
---|---|
(i) LiAlH4, THF, (ii) chloranil, benzene; Multistep reaction; |
neocapsanthin B''
A
capsanthin
B
neocapsanthin A''
C
neocapsanthin A'
D
neocapsanthin B'
E
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Equilibrium constant; |
neocapsanthin A''
A
capsanthin
B
neocapsanthin B''
C
neocapsanthin A'
D
neocapsanthin B'
E
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Equilibrium constant; |
neocapsanthin A'
A
capsanthin
B
neocapsanthin B''
C
neocapsanthin A''
D
neocapsanthin B'
E
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Equilibrium constant; |
neocapsanthin B'
A
capsanthin
B
neocapsanthin B''
C
neocapsanthin A''
D
neocapsanthin A'
E
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Equilibrium constant; |
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
A
capsanthin
B
neocapsanthin B''
C
neocapsanthin A''
D
neocapsanthin A'
E
neocapsanthin B'
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Equilibrium constant; |
(3R,3'S,5'R)-3,3'-diacetoxy-β,κ-caroten-6'-one
A
(3S,5Ξ,8Ξ,3'S,5'R)-5,8-epoxy-3,3'-dihydroxy-5,8-dihydro-β,κ-caroten-6'-one
B
5,6-Epoxycapsanthin
C
capsanthin
D
all-trans-capsanthin 5,6-epoxide
Conditions | Yield |
---|---|
With potassium hydroxide; monoperoxyphthalic acid 1.) Et2O, r.t., 75 h; 2.) MeOH, Et2O, 16 h; Yield given. Multistep reaction; |
(R)-4-ethynyl-3,5,5-trimethylcyclohex-3-en-1-ol
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 10 steps 1.1: Bu3SnH; AIBN / 0.33 h / 130 °C 1.2: Pd2dba3*CHCl3; AsPh3 / dimethylformamide / 50 °C 2.1: 93 percent / DMAP; Et3N 3.1: 28 percent / m-CPBA 4.1: LiAlH4 5.1: MnO2 6.1: SnCl4 7.1: HF 8.1: NaOMe 9.1: ion exchange resin Dowex 50W-X8(H+) 10.1: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 11 steps 1.1: Bu3SnH; AIBN / 0.33 h / 130 °C 1.2: Pd2dba3*CHCl3; AsPh3 / dimethylformamide / 50 °C 2.1: 93 percent / DMAP; Et3N 3.1: 28 percent / m-CPBA 4.1: LiAlH4 5.1: MnO2 6.1: SnCl4 7.1: HF 8.1: NaOMe 9.1: ion exchange resin Dowex 50W-X8(H+) 10.1: 64 percent / PdCl2(MeCN)2; Et3N 11.1: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 11 steps 1.1: Bu3SnH; AIBN / 0.33 h / 130 °C 1.2: Pd2dba3*CHCl3; AsPh3 / dimethylformamide / 50 °C 2.1: 93 percent / DMAP; Et3N 3.1: 28 percent / m-CPBA 4.1: LiAlH4 5.1: MnO2 6.1: SnCl4 7.1: HF 8.1: NaOMe 9.1: ion exchange resin Dowex 50W-X8(H+) 10.1: 70 percent / PdCl2(MeCN)2; Et3N 11.1: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 4 steps 1.1: Bu3SnH; AIBN / 0.33 h / 130 °C 1.2: Pd2dba3*CHCl3; AsPh3 / dimethylformamide / 50 °C 2.1: LiAlH4 3.1: 42 percent / NaOMe View Scheme |
(2E,4E)-6-[(1R,4S)-4-hydroxy-1,2,2-trimethylcyclopentyl]-3-methyl-6-oxohexa-2,4-dienal
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: NaOMe 2: ion exchange resin Dowex 50W-X8(H+) 3: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 4 steps 1: NaOMe 2: ion exchange resin Dowex 50W-X8(H+) 3: 64 percent / PdCl2(MeCN)2; Et3N 4: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 4 steps 1: NaOMe 2: ion exchange resin Dowex 50W-X8(H+) 3: 70 percent / PdCl2(MeCN)2; Et3N 4: 42 percent / NaOMe View Scheme |
(R)-4-((1E,3E)-5-Hydroxy-3-methyl-penta-1,3-dienyl)-3,5,5-trimethyl-cyclohex-3-enol
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 42 percent / NaOMe View Scheme |
ethyl (2E,4E)-5-[(4R)-4-hydroxy-2,6,6-trimethylcyclohexyl-1-enyl]-3-methylpenta-2,4-dienoate
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 9 steps 1: 93 percent / DMAP; Et3N 2: 28 percent / m-CPBA 3: LiAlH4 4: MnO2 5: SnCl4 6: HF 7: NaOMe 8: ion exchange resin Dowex 50W-X8(H+) 9: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 10 steps 1: 93 percent / DMAP; Et3N 2: 28 percent / m-CPBA 3: LiAlH4 4: MnO2 5: SnCl4 6: HF 7: NaOMe 8: ion exchange resin Dowex 50W-X8(H+) 9: 64 percent / PdCl2(MeCN)2; Et3N 10: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 10 steps 1: 93 percent / DMAP; Et3N 2: 28 percent / m-CPBA 3: LiAlH4 4: MnO2 5: SnCl4 6: HF 7: NaOMe 8: ion exchange resin Dowex 50W-X8(H+) 9: 70 percent / PdCl2(MeCN)2; Et3N 10: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 3 steps 1: LiAlH4 2: 42 percent / NaOMe View Scheme |
(2E,4E)-6-[(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1,2,2-trimethyl-cyclopentyl]-3-methyl-6-oxo-hexa-2,4-dienal
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: HF 2: NaOMe 3: ion exchange resin Dowex 50W-X8(H+) 4: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 5 steps 1: HF 2: NaOMe 3: ion exchange resin Dowex 50W-X8(H+) 4: 64 percent / PdCl2(MeCN)2; Et3N 5: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 5 steps 1: HF 2: NaOMe 3: ion exchange resin Dowex 50W-X8(H+) 4: 70 percent / PdCl2(MeCN)2; Et3N 5: 42 percent / NaOMe View Scheme |
(2E,4E)-3-methyl-5-[(1S,4S,6R)-4-tert-butyldimethylsilyloxy-2,2,6-trimethyl-7-oxabicyclo[4.1.0]hept-1-yl]penta-2,4-dienal
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: SnCl4 2: HF 3: NaOMe 4: ion exchange resin Dowex 50W-X8(H+) 5: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 6 steps 1: SnCl4 2: HF 3: NaOMe 4: ion exchange resin Dowex 50W-X8(H+) 5: 64 percent / PdCl2(MeCN)2; Et3N 6: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 6 steps 1: SnCl4 2: HF 3: NaOMe 4: ion exchange resin Dowex 50W-X8(H+) 5: 70 percent / PdCl2(MeCN)2; Et3N 6: 42 percent / NaOMe View Scheme |
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: MnO2 2: SnCl4 3: HF 4: NaOMe 5: ion exchange resin Dowex 50W-X8(H+) 6: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 7 steps 1: MnO2 2: SnCl4 3: HF 4: NaOMe 5: ion exchange resin Dowex 50W-X8(H+) 6: 64 percent / PdCl2(MeCN)2; Et3N 7: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 7 steps 1: MnO2 2: SnCl4 3: HF 4: NaOMe 5: ion exchange resin Dowex 50W-X8(H+) 6: 70 percent / PdCl2(MeCN)2; Et3N 7: 42 percent / NaOMe View Scheme |
ethyl (2E,4E)-5-[(4R)-4-tert-butyldimethylsilyloxy-2,6,6-trimethylcyclohexyl-1-enyl]-3-methylpenta-2,4-dienoate
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 8 steps 1: 28 percent / m-CPBA 2: LiAlH4 3: MnO2 4: SnCl4 5: HF 6: NaOMe 7: ion exchange resin Dowex 50W-X8(H+) 8: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 9 steps 1: 28 percent / m-CPBA 2: LiAlH4 3: MnO2 4: SnCl4 5: HF 6: NaOMe 7: ion exchange resin Dowex 50W-X8(H+) 8: 64 percent / PdCl2(MeCN)2; Et3N 9: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 9 steps 1: 28 percent / m-CPBA 2: LiAlH4 3: MnO2 4: SnCl4 5: HF 6: NaOMe 7: ion exchange resin Dowex 50W-X8(H+) 8: 70 percent / PdCl2(MeCN)2; Et3N 9: 42 percent / NaOMe View Scheme |
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: ion exchange resin Dowex 50W-X8(H+) 2: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 3 steps 1: ion exchange resin Dowex 50W-X8(H+) 2: 64 percent / PdCl2(MeCN)2; Et3N 3: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 3 steps 1: ion exchange resin Dowex 50W-X8(H+) 2: 70 percent / PdCl2(MeCN)2; Et3N 3: 42 percent / NaOMe View Scheme |
(2E,4E)-5-[(1S,4S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-2,2,6-trimethyl-7-oxa-bicyclo[4.1.0]hept-1-yl]-3-methyl-penta-2,4-dienoic acid ethyl ester
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 7 steps 1: LiAlH4 2: MnO2 3: SnCl4 4: HF 5: NaOMe 6: ion exchange resin Dowex 50W-X8(H+) 7: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 8 steps 1: LiAlH4 2: MnO2 3: SnCl4 4: HF 5: NaOMe 6: ion exchange resin Dowex 50W-X8(H+) 7: 64 percent / PdCl2(MeCN)2; Et3N 8: 42 percent / NaOMe View Scheme | |
Multi-step reaction with 8 steps 1: LiAlH4 2: MnO2 3: SnCl4 4: HF 5: NaOMe 6: ion exchange resin Dowex 50W-X8(H+) 7: 70 percent / PdCl2(MeCN)2; Et3N 8: 42 percent / NaOMe View Scheme |
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 64 percent / PdCl2(MeCN)2; Et3N 2: 42 percent / NaOMe View Scheme |
capsanthin
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 70 percent / PdCl2(MeCN)2; Et3N 2: 42 percent / NaOMe View Scheme |
capsanthin
acetyl chloride
(3R,3'S,5'R)-3,3'-diacetoxy-β,κ-caroten-6'-one
Conditions | Yield |
---|---|
With pyridine |
capsanthin
Conditions | Yield |
---|---|
(i) LiAlH4, (ii) HCl, CHCl3; Multistep reaction; |
capsanthin
Conditions | Yield |
---|---|
With aluminum tri-tert-butoxide In acetone; benzene |
diazomethane
capsanthin
(1R,4S)-4-Hydroxy-1,2,2-trimethycyclopentancarbonsaeure-methylester
Conditions | Yield |
---|---|
With dihydrogen peroxide; oxygen; ozone 1.) carbon tetrachloride, acetic acid, water, reflux, 2 h, 2.) ether, 0 deg C; Yield given. Multistep reaction; |
capsanthin
A
neocapsanthin B''
B
neocapsanthin A''
C
neocapsanthin A'
D
neocapsanthin B'
Conditions | Yield |
---|---|
iodine Irradiation; |
capsanthin
A
neocapsanthin B''
B
neocapsanthin A''
C
neocapsanthin A'
D
neocapsanthin B'
E
(2E,4E,6E,8E,10Z,12E,14E,16E,18E)-19-((R)-4-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-1-((1R,4S)-4-hydroxy-1,2,2-trimethyl-cyclopentyl)-4,8,13,17-tetramethyl-nonadeca-2,4,6,8,10,12,14,16,18-nonaen-1-one
Conditions | Yield |
---|---|
In pyridine at 74.6 - 95.3℃; Kinetics; Equilibrium constant; Thermodynamic data; EA, ΔH, ΔS, ΔG; |
Conditions | Yield |
---|---|
at 80℃; |
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