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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Protoporphyrin IX dimethyl ester Manufacturer/High quality/Best price/In stock

Cas:5522-66-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Cas:5522-66-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Cas:5522-66-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Protoporphyrin IX, dimethyl ester

Cas:5522-66-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Hope Chem Co., Ltd

1. Product advantages: exquisite appearance and unique functions. 2. Product Advantages: Our products are the best,fast speed ,in large stock 3. High-quality products and thoughtful service are your greatest satisfaction. 4. The product

Protoporphyrin IX dimethylester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Protoporphyrin IX diMethyl ester

Cas:5522-66-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

5522-66-7 Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Protoporphyrin IX dimethyl ester cas no. 5522-66-7 97%

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Protoporphyrin dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Protoporphyrin IX diMethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethenyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Dimethyl 3,3'-(3,8,13,17-tetramethyl-7,12-divinylporphyrin-2,18-diyl)dipropionate

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

DB BIOTECH CO., LTD

best seller Application:API

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Protoporphyrin IX dimethyl ester cas 5522-66-7Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Protoporphyrin IX dimethyl ester cas 5522-66-7

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:50mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any por

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

5522-66-7

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Protoporphyrin IX dimethyl ester

Cas:5522-66-7

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methanol
67-56-1

methanol

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With pyridine; diammonium iron(II) sulfate hexahydrate; acetyl chloride In dichloromethane for 1h; Cooling;99%
methanol
67-56-1

methanol

protoporphyrin IX
553-12-8

protoporphyrin IX

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
at 20℃; for 6h; Fischer-Speier Esterification;98%
With sulfuric acid at -10℃; for 18h; Inert atmosphere; Schlenk technique; Darkness;95%
With trimethyl orthoformate; sulfuric acid for 0.75h; Ambient temperature;71 % Chromat.
protoporphyrin IX
553-12-8

protoporphyrin IX

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With sulfuric acid In methanol for 12h; Darkness;79%
methanol
67-56-1

methanol

protoporphyrin IX disodium salt
50865-01-5

protoporphyrin IX disodium salt

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With sulfuric acid at 0℃;54%
dimethyl 7,12-diiodo-3,8,13,17-tetramethylporphyrin-2,18-dipropionate
123411-35-8

dimethyl 7,12-diiodo-3,8,13,17-tetramethylporphyrin-2,18-dipropionate

pinacol vinylboronate
75927-49-0

pinacol vinylboronate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate In tetrahydrofuran at 80℃; for 18h; Suzuki-Miyaura Coupling; Inert atmosphere;38%
protoporphyrin IX
553-12-8

protoporphyrin IX

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
at 190℃; im Hochvakuum;
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
at 155℃; im Hochvakuum;
With hydrogen bromide; acetic acid
acetic acid
64-19-7

acetic acid

3-(1-ethoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

3-(1-ethoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

8-(1-acetoxyethyl)-3-(1-ethoxyethyl)deuteroporphyrin dimethyl ester
75162-69-5

8-(1-acetoxyethyl)-3-(1-ethoxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

2(4)-(1-hydroxyethyl)-4(2)-vinyldeuteroporphyrin dimethyl ester
75162-77-5, 93175-17-8, 93175-18-9, 127997-63-1

2(4)-(1-hydroxyethyl)-4(2)-vinyldeuteroporphyrin dimethyl ester

B

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

C

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

D

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

8-(1-hydroxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

8-(1-hydroxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

D

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

8-(1-ethoxyethyl)-3-(1-hydroxyethyl)deuteroporphyrin dimethyl ester
75162-70-8

8-(1-ethoxyethyl)-3-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With 1.) 18 H2SO4 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

8-(1-acetoxyethyl)-3-(1-hydroxyethyl)deuteroporphyrin dimethyl ester
75162-61-7

8-(1-acetoxyethyl)-3-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

3-(1-ethoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

3-(1-ethoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

3-(1-acetoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-(1-hydroxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

O,O'-diacetyl-hematoporphyrin-dimethyl ester
75162-60-6, 81677-46-5, 81677-47-6, 81677-48-7, 81677-49-8

O,O'-diacetyl-hematoporphyrin-dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
acetic acid
64-19-7

acetic acid

hematoporphyrin
14459-29-1

hematoporphyrin

A

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester
66154-82-3

8-(1-acetoxyethyl)-3-vinyldeuteroporphyrin dimethyl ester

B

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-vinyldeuteroporphyrin dimethyl ester

C

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

D

3-(1-acetoxyethyl)-8-(1-ethoxyethyl)deuteroporphyrin dimethyl ester

3-(1-acetoxyethyl)-8-(1-ethoxyethyl)deuteroporphyrin dimethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) 20 min, RT; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given;
2C34H32N4O4(2-)*C4H4N2*2Fe(2+)

2C34H32N4O4(2-)*C4H4N2*2Fe(2+)

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Yield given. Multistep reaction;
methanol
67-56-1

methanol

coproporphyrinogen lV
59969-39-0

coproporphyrinogen lV

A

2,8-divinyl-13,17-bis-(2-methoxycarbonylethyl)-3,7,12,18-tetramethyl-1,4-divinylporphyn
59969-40-3

2,8-divinyl-13,17-bis-(2-methoxycarbonylethyl)-3,7,12,18-tetramethyl-1,4-divinylporphyn

B

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C

8,13,17-tris(2-methoxycarbonylethyl)-3,7,12,18-tetramethyl-2-vinylporphyrin
60297-35-0

8,13,17-tris(2-methoxycarbonylethyl)-3,7,12,18-tetramethyl-2-vinylporphyrin

D

coproporphyrin lV tetramethyl ester
13306-30-4

coproporphyrin lV tetramethyl ester

Conditions
ConditionsYield
With sulfuric acid 1.) beef-liver mitochondria, 0.2M Tris-HCl buffer (pH 7.8), 38 deg C, 22 h, 2.) 25 deg C; Multistep reaction;
coproporphyrinogen III
2624-63-7

coproporphyrinogen III

A

8,13,17-tris(2-methoxycarbonylethyl)-2,7,12,18-tetramethyl-3-vinylporphyrin
42607-17-0

8,13,17-tris(2-methoxycarbonylethyl)-2,7,12,18-tetramethyl-3-vinylporphyrin

B

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C

coproporphyrin III tetramethyl ester
5522-63-4

coproporphyrin III tetramethyl ester

Conditions
ConditionsYield
for 0.5h; coproporphyrinogen-III oxidase (from Euglena gracilis);
(2-trimethylethylsilylethoxy)methyl chloride
76513-69-4

(2-trimethylethylsilylethoxy)methyl chloride

diacetyldeuteroporphyrin IX dimethyl ester
10591-31-8

diacetyldeuteroporphyrin IX dimethyl ester

A

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

B

C84H110N8O13Si2
136214-95-4

C84H110N8O13Si2

Conditions
ConditionsYield
Yield given. Multistep reaction;
2,4-bis(2-bromoethyl)deuteroporphyrin IX dimethyl ester

2,4-bis(2-bromoethyl)deuteroporphyrin IX dimethyl ester

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
In pyridine Heating; nitrogen atmosphere;0.031 g
benzyl 4-acetyl-3,5-dimethylpyrrole-2-carboxylate
2386-27-8

benzyl 4-acetyl-3,5-dimethylpyrrole-2-carboxylate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 10 steps
1: 90 percent / POCl3 / dimethylformamide / 0.75 h / 40 °C
2: 96 percent / KOH / H2O; dimethylformamide / 0.25 h / 20 °C
3: 99 percent / bromine / CCl4 / 1 h / 20 °C
4: 70 percent / aq. ethanol / 1 h / Heating
5: 89 percent / 1.) boron trifluoride ether complex 2.)sodium tetrahydroborate / tetrahydrofuran / 1 h / 20 °C / nitrogen atmosphere
6: 1.) 40percent HBr 2.) benzoyl chloride / 1.) glac.AcOH, 8 h, 20 degC 2.) DMF, 24 h, 20 degC
7: 90 percent / HBr / diethyl ether / 0.17 h
8: 88 percent / HBr / methanol / 0.17 h
9: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
10: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
Multi-step reaction with 11 steps
1: 90 percent / POCl3 / dimethylformamide / 0.75 h / 40 °C
2: 96 percent / KOH / H2O; dimethylformamide / 0.25 h / 20 °C
3: 99 percent / bromine / CCl4 / 1 h / 20 °C
4: 70 percent / aq. ethanol / 1 h / Heating
5: 89 percent / 1.) boron trifluoride ether complex 2.)sodium tetrahydroborate / tetrahydrofuran / 1 h / 20 °C / nitrogen atmosphere
6: hydrogen / Pd/C, triethylamine / tetrahydrofuran
7: KI,I2 / H2O / 0.5 h / 50 °C
8: 57 percent / hydrogen / Pd/C, triethylamine / tetrahydrofuran
9: 88 percent / HBr / methanol / 0.17 h
10: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
11: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
3-(2-bromoethyl)-4-methylpyrrole-2-carboxaldehyde
78344-84-0

3-(2-bromoethyl)-4-methylpyrrole-2-carboxaldehyde

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 88 percent / HBr / methanol / 0.17 h
2: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
3: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
benzyl 4-(2-bromoethyl)-3,5-dimethylpyrrole-2-carboxylate
72562-17-5

benzyl 4-(2-bromoethyl)-3,5-dimethylpyrrole-2-carboxylate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 1.) 40percent HBr 2.) benzoyl chloride / 1.) glac.AcOH, 8 h, 20 degC 2.) DMF, 24 h, 20 degC
2: 90 percent / HBr / diethyl ether / 0.17 h
3: 88 percent / HBr / methanol / 0.17 h
4: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
5: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
Multi-step reaction with 6 steps
1: hydrogen / Pd/C, triethylamine / tetrahydrofuran
2: KI,I2 / H2O / 0.5 h / 50 °C
3: 57 percent / hydrogen / Pd/C, triethylamine / tetrahydrofuran
4: 88 percent / HBr / methanol / 0.17 h
5: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
6: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
4-(2-bromoethyl)-3,5-dimethylpyrrole-2-carboxaldehyde
78344-82-8

4-(2-bromoethyl)-3,5-dimethylpyrrole-2-carboxaldehyde

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 90 percent / HBr / diethyl ether / 0.17 h
2: 88 percent / HBr / methanol / 0.17 h
3: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
4: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
3-(2-Bromo-ethyl)-5-iodo-4-methyl-1H-pyrrole-2-carbaldehyde
78344-90-8

3-(2-Bromo-ethyl)-5-iodo-4-methyl-1H-pyrrole-2-carbaldehyde

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 57 percent / hydrogen / Pd/C, triethylamine / tetrahydrofuran
2: 88 percent / HBr / methanol / 0.17 h
3: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
4: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
4-(2-Bromo-ethyl)-5-formyl-3-methyl-1H-pyrrole-2-carboxylic acid
78344-89-5

4-(2-Bromo-ethyl)-5-formyl-3-methyl-1H-pyrrole-2-carboxylic acid

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: KI,I2 / H2O / 0.5 h / 50 °C
2: 57 percent / hydrogen / Pd/C, triethylamine / tetrahydrofuran
3: 88 percent / HBr / methanol / 0.17 h
4: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
5: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
benzyl 4-ethynyl-3,5-dimethylpyrrole-2-carboxylate
78344-79-3

benzyl 4-ethynyl-3,5-dimethylpyrrole-2-carboxylate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: 99 percent / bromine / CCl4 / 1 h / 20 °C
2: 70 percent / aq. ethanol / 1 h / Heating
3: 89 percent / 1.) boron trifluoride ether complex 2.)sodium tetrahydroborate / tetrahydrofuran / 1 h / 20 °C / nitrogen atmosphere
4: 1.) 40percent HBr 2.) benzoyl chloride / 1.) glac.AcOH, 8 h, 20 degC 2.) DMF, 24 h, 20 degC
5: 90 percent / HBr / diethyl ether / 0.17 h
6: 88 percent / HBr / methanol / 0.17 h
7: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
8: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
Multi-step reaction with 9 steps
1: 99 percent / bromine / CCl4 / 1 h / 20 °C
2: 70 percent / aq. ethanol / 1 h / Heating
3: 89 percent / 1.) boron trifluoride ether complex 2.)sodium tetrahydroborate / tetrahydrofuran / 1 h / 20 °C / nitrogen atmosphere
4: hydrogen / Pd/C, triethylamine / tetrahydrofuran
5: KI,I2 / H2O / 0.5 h / 50 °C
6: 57 percent / hydrogen / Pd/C, triethylamine / tetrahydrofuran
7: 88 percent / HBr / methanol / 0.17 h
8: 0.044 g / bromine, iodine, triethylamine / various solvent(s) / 0.17 h / Heating
9: 0.031 g / pyridine / Heating; nitrogen atmosphere
View Scheme
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,3'-[7,12-bis-(1,2-dihydroxy-ethyl)-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-diyl]-bis-propionic acid dimethyl ester
60185-97-9

3,3'-[7,12-bis-(1,2-dihydroxy-ethyl)-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-diyl]-bis-propionic acid dimethyl ester

Conditions
ConditionsYield
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In 1,4-dioxane; water for 24h;97.5%
gallium(III) trichloride

gallium(III) trichloride

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

gallium(III) protoporphyrin IX chloride

gallium(III) protoporphyrin IX chloride

Conditions
ConditionsYield
With 2,6-dimethylpyridine In neat (no solvent) at 150℃; under 760.051 Torr; for 1.5h; Inert atmosphere; Glovebox;85%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

ethylene glycol
107-21-1

ethylene glycol

3,8-di[1-(2-hydroxyethyloxy)-2-iodo]ethyldeutero-porphyrin IX dimethyl ester

3,8-di[1-(2-hydroxyethyloxy)-2-iodo]ethyldeutero-porphyrin IX dimethyl ester

Conditions
ConditionsYield
With iodine; bis-[(trifluoroacetoxy)iodo]benzene In 1,2-dichloro-ethane at 20℃; for 2h; Solvent;84%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

(E,E)-3,282-dibromo-protoporphyrin IX dimethyl ester

(E,E)-3,282-dibromo-protoporphyrin IX dimethyl ester

Conditions
ConditionsYield
With pyridinium perbromide hydrobromide In chloroform at 61℃; for 3h; Reagent/catalyst;84%
ethanol
64-17-5

ethanol

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,8-di(1-ethoxy-2-iodoethyl)deuteroporphyrin IX dimethyl ester

3,8-di(1-ethoxy-2-iodoethyl)deuteroporphyrin IX dimethyl ester

Conditions
ConditionsYield
With iodine; bis-[(trifluoroacetoxy)iodo]benzene In 1,2-dichloro-ethane at 20℃; for 2h; Solvent;80%
zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

zinc protoporphyrin IX dimethyl ester
15304-09-3

zinc protoporphyrin IX dimethyl ester

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 2h; Reflux;75%
With silica gel Milling;
gallium(III) trichloride

gallium(III) trichloride

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C36H36ClGaN4O4

C36H36ClGaN4O4

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 170℃; for 0.166667h; Microwave irradiation;68%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,8-di-[3'(R,S)-(1'-pyrazolinyl)]-deuteroporphyrin IX dimethyl ester

3,8-di-[3'(R,S)-(1'-pyrazolinyl)]-deuteroporphyrin IX dimethyl ester

Conditions
ConditionsYield
In diethyl ether; dichloromethane at 20℃; for 96h;54%
2-fluoroethanol
371-62-0

2-fluoroethanol

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C38H44F2N4O6

C38H44F2N4O6

Conditions
ConditionsYield
Stage #1: 3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester With hydrogen bromide; acetic acid at 20℃; for 36h;
Stage #2: 2-fluoroethanol at 20℃; for 4h;
Stage #3: With water; sodium hydroxide In tetrahydrofuran at 20℃; for 2h;
51.53%
1-(2-hydroxyethyl)-1H-pyrrole-2,5-dione
1585-90-6

1-(2-hydroxyethyl)-1H-pyrrole-2,5-dione

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

A

21,22[N,N-dicarbonil-N-4-(2-hydroxyethyl)phenyl]-13,17-bis[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-8-vinyl-2,21,22,23-tetrahydrobenzo[b]porphyrin

21,22[N,N-dicarbonil-N-4-(2-hydroxyethyl)phenyl]-13,17-bis[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-8-vinyl-2,21,22,23-tetrahydrobenzo[b]porphyrin

B

21,22[N,N-dicarbonil-N-4-(2-hydroxyethyl)phenyl]-8,12-bis[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-8-vinyl-2,21,22,23-tetrahydrobenzo[b]porphyrin

21,22[N,N-dicarbonil-N-4-(2-hydroxyethyl)phenyl]-8,12-bis[2-(methoxycarbonyl)ethyl]-2,7,12,18-tetramethyl-8-vinyl-2,21,22,23-tetrahydrobenzo[b]porphyrin

Conditions
ConditionsYield
In toluene at 125℃; for 24h; Diels-Alder Cycloaddition;A 33%
B 44%
1-[4-(1,3-dithiolan-2-yl)phenyl]-1H-pyrrole-2,5-dione

1-[4-(1,3-dithiolan-2-yl)phenyl]-1H-pyrrole-2,5-dione

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C49H49N5O6S2

C49H49N5O6S2

C49H49N5O6S2

C49H49N5O6S2

Conditions
ConditionsYield
With BTH In toluene at 125℃; for 24h; Solvent; Temperature; Time; Diels-Alder Cycloaddition;A 37%
B 37%
bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

air

air

C37H36ClIrN4O5

C37H36ClIrN4O5

Conditions
ConditionsYield
In o-xylene for 4h; Reflux;37%
4-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)benzaldehyde
32487-80-2

4-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)benzaldehyde

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

C47H45N5O7

C47H45N5O7

C47H45N5O7

C47H45N5O7

Conditions
ConditionsYield
In toluene at 125℃; for 14h; Time; Diels-Alder Cycloaddition; Sealed tube;A 36%
B 35%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

recorcinol
108-46-3

recorcinol

2,4-Bis(1-resorcinylethyl)deuteroporphyrin Bis(methyl ester)
77773-68-3

2,4-Bis(1-resorcinylethyl)deuteroporphyrin Bis(methyl ester)

Conditions
ConditionsYield
at 115 - 120℃; for 4h;35%
eschenmoser's salt
33797-51-2

eschenmoser's salt

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

A

3-[(1Z,4Z,9Z,15Z)-7-((E)-3-Dimethylamino-propenyl)-18-(2-methoxycarbonyl-ethyl)-3,8,13,17-tetramethyl-12-vinyl-porphyrin-2-yl]-propionic acid methyl ester

3-[(1Z,4Z,9Z,15Z)-7-((E)-3-Dimethylamino-propenyl)-18-(2-methoxycarbonyl-ethyl)-3,8,13,17-tetramethyl-12-vinyl-porphyrin-2-yl]-propionic acid methyl ester

B

3,8-bis<3-(dimethylamino)-1-propenyl>-13,17-bis<2-(methoxycarbonyl)ethyl>-2,7,12,18-tetramethylporphin

3,8-bis<3-(dimethylamino)-1-propenyl>-13,17-bis<2-(methoxycarbonyl)ethyl>-2,7,12,18-tetramethylporphin

Conditions
ConditionsYield
In chloroform for 1h; Heating;A n/a
B 35%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

ethyl β-(phenylsulfonyl)propiolate
80404-53-1

ethyl β-(phenylsulfonyl)propiolate

A

C47H48N4O8S
100228-57-7

C47H48N4O8S

B

C47H48N4O8S

C47H48N4O8S

Conditions
ConditionsYield
In dichloromethane for 20h; Heating;A 34%
B 34%
In dichloromethane for 20h;A 34%
B 34%
dimethyl acetylenedicarboxylate
4458-43-9

dimethyl acetylenedicarboxylate

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

A

C42H44N4O8
94238-43-4

C42H44N4O8

B

C42H44N4O8
94238-24-1

C42H44N4O8

Conditions
ConditionsYield
In 1,2-dichloro-ethane for 72h; Heating;A 20%
B 20%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

diethyl acetylenedicarboxylate
762-21-0

diethyl acetylenedicarboxylate

A

C44H48N4O8
100205-63-8

C44H48N4O8

B

C44H48N4O8
100205-64-9

C44H48N4O8

Conditions
ConditionsYield
In toluene for 144h; Heating;A 20%
B 19%
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

A

8-devinyl-8-[3'(R,S)-(1'-pyrazolinyl)]-protoporphyrin IX dimethyl ester

8-devinyl-8-[3'(R,S)-(1'-pyrazolinyl)]-protoporphyrin IX dimethyl ester

B

3-devinyl-3-[3'(R,S)-(1'-pyrazolinyl)]-protoporphyrin IX dimethyl ester

3-devinyl-3-[3'(R,S)-(1'-pyrazolinyl)]-protoporphyrin IX dimethyl ester

Conditions
ConditionsYield
In diethyl ether; dichloromethane at 20℃; for 48h;A 19%
B 20%
diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,8-bis-(2-methoxycarbonyl-cyclopropyl)-deuteroporphyrin-dimethyl ester

3,8-bis-(2-methoxycarbonyl-cyclopropyl)-deuteroporphyrin-dimethyl ester

Conditions
ConditionsYield
anschliessend Verestern mit Diazomethan;
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

protoporphyrin IX
553-12-8

protoporphyrin IX

Conditions
ConditionsYield
With potassium hydroxide; ethanol
With methanol; sodium hydroxide
With hydrogenchloride
With hydrogenchloride at 25℃; for 2h; Hydrolysis;
With potassium hydroxide In methanol for 24h; Heating;
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

mesoporphyrin IX dimethyl ester
1263-63-4

mesoporphyrin IX dimethyl ester

Conditions
ConditionsYield
With methanol; platinum Hydrogenation.beim anschliessenden Behandeln mit Luft;
With polymethacrylic acid methyl ester-catalyst; water; palladium Hydrogenation;
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

3,8-diformyldeuteroporphyrin IX dimethyl ester
15341-25-0

3,8-diformyldeuteroporphyrin IX dimethyl ester

Conditions
ConditionsYield
With osmium(VIII) oxide; water
With potassium permanganate
Multi-step reaction with 2 steps
1: 97.5 percent / OsO4, 4-methylmorpholine N-oxide / dioxane; H2O / 24 h
2: 80 percent / aq. periodoc acid / tetrahydrofuran / 1 h
View Scheme
Multi-step reaction with 2 steps
1: 1.) conc.H2SO4, O3 / 1.) -60 deg C; 2.) 1 h each at -30 deg C, 0 deg C, RT
2: conc. H2SO4 / 0 °C
View Scheme
Multi-step reaction with 2 steps
1: bis-[(trifluoroacetoxy)iodo]benzene; iodine; water / 1,2-dichloro-ethane; tetrahydrofuran / 2 h / 20 °C
2: toluene-4-sulfonic acid; sodium periodate / tetrahydrofuran; water / 4 h / 20 °C
View Scheme
3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester
5522-66-7

3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-21H,23H-porphine-2,18-diyl)-bis-propionic acid dimethyl ester

hematoporphyrin
14459-29-1

hematoporphyrin

Conditions
ConditionsYield
With hydrogen bromide; acetic acid anschliessend Behandeln mit H2O; hematoporphyrin-IX;

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