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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 4-nitrobenzoate Manufacturer/High quality/Best price/In stock

Cas:619-50-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Methyl 4-Nitrobenzoate

Cas:619-50-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Nitrobenzoic acid methyl ester

Cas:619-50-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Name Methyl 4-nitrobenzoate CAS 619-50-1 Assay 99% Appearance

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

619-50-1 Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

China Gold Supplier CAS 619-50-1 with fast shipping

Cas:619-50-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:10 Gram

FOB Price: $0.5 / 1.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzoic acid, 4-nitro-,methyl ester

Cas:619-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Methyl 4-nitrobenzoate CAS:619-50-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

Methyl 4-nitrobenzoate CAS:619-50-1

Cas:619-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid, 4-nitro-,methyl ester

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:619-50-1

Cas:619-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance: light yellow to yellow fine crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your requ

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Methyl 4-nitrobenzoate Chemical Properties Melting point 94-96 °C (lit.) 94-96 °C Boiling point 314.24°C (rough estimate) density 1.4283 (rough estimate) refractive index 1.5468 (estimate) Fp 94-96°C storage temp.

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

TIANFUCHEM--High purity Methyl 4-nitrobenzoate factory price

Cas:619-50-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: Methyl P-Nitrobenzoate CAS No.:619-50-1 Molecule Formula:C8H6NO4 Molecule Weight:180.14 Purity: 99.0% Package: 25kg/drum Description:Yellow powder Manufacture Standards:Enterprise Standard TESTING ITE

Best Quality Methyl P-Nitrobenzoate

Cas:619-50-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

TIANFUCHEM--High purity Methyl 4-nitrobenzoate factory price

Cas:619-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

TIANFUCHEM--High purity Methyl 4-nitrobenzoate factory price

Cas:619-50-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 4-nitrobenzoate

Cas:619-50-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

Benzoic acid, 4-nitro-,methyl ester

Cas:619-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

TIANFUCHEM--High purity Methyl 4-nitrobenzoate factory price

Cas:619-50-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Changzhou Anchor Biological Technology Co., Ltd.

Our company is engaged in customizing the benzene ring and pyridine derivative organic intermediates, and the quantity is flexible according to customer's needs. It mainly provides high-quality intermediates for domestic and foreign pharmaceutical an

Methyl 4-nitrobenzoate Manufacturer/High quality/Best price/In stock CAS NO.619-50-1

Cas:619-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Benzoic acid, 4-nitro-,methyl ester

Cas:619-50-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyl 4-nitrobenzoate cas no. 619-50-1 98%

Cas:619-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methanol
67-56-1

methanol

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With dmap; 2-chloro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl)pyridinium trifluoromethanesulfonate; triethylamine In N,N-dimethyl-formamide at 20℃; for 1h;100%
Stage #1: 4-nitro-benzoic acid With 1H-imidazole; iodine; triphenylphosphine In dichloromethane at 20℃; for 0.0833333h; Garegg-Samuelsson type reaction;
Stage #2: methanol In dichloromethane at 20℃; Garegg-Samuelsson type reaction;
100%
With dmap; 2-chloro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl)pyridinium trifluoromethanesulfonate; triethylamine In N,N-dimethyl-formamide at 20℃; for 1h;100%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

carbon monoxide
201230-82-2

carbon monoxide

triethylmethoxystannane
1067-21-6

triethylmethoxystannane

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With iodophenylbis(triphenylphosphine)palladium under 760 Torr; for 1h;100%
diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
In methanol; toluene at 20℃; for 2h;100%
In ethyl acetate60%
In methanol; diethyl ether; hexane at 20℃; for 2h; Inert atmosphere;178 mg
1-(dimethoxymethyl)pyrrolidine
5564-73-8

1-(dimethoxymethyl)pyrrolidine

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 30℃; for 25h;100%
methanol
67-56-1

methanol

diethyl N-(4-nitrobenzoyloxy)-4-fluorobenzimidoylphosphonate

diethyl N-(4-nitrobenzoyloxy)-4-fluorobenzimidoylphosphonate

A

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

B

diethyl [N-(hydroxy)imino](p-fluorophenyl)methylphosphonate
154109-07-6

diethyl [N-(hydroxy)imino](p-fluorophenyl)methylphosphonate

Conditions
ConditionsYield
for 6h; Inert atmosphere; Reflux;A 100%
B 100%
methanol
67-56-1

methanol

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With water; iodine; sodium nitrite at 20 - 70℃; chemoselective reaction;99%
With ammonium peroxydisulfate at 60℃; for 2.5h;99%
With potassium hydroxide; iodine at 0℃; for 0.0166667h;98%
methanol
67-56-1

methanol

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With sodium carbonate; palladium; silver(l) oxide at 80℃; for 48h; Molecular sieve;99%
With dihydrogen peroxide for 3h; Irradiation;95%
With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 20h;94%
methanol
67-56-1

methanol

ethyl 4-nitrobenzoate
99-77-4

ethyl 4-nitrobenzoate

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
scandium tris(trifluoromethanesulfonate) at 64℃; for 168h;98%
With dipotassium hydrogenphosphate for 5h; Reflux;98%
With potassium ethoxide
acrylonitrile; triphenylphosphine at 25℃; for 24h;71 % Chromat.
N,N-dimethoxyamine
88470-26-2

N,N-dimethoxyamine

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
In benzene for 3h; Heating;98%
In benzene Product distribution; Mechanism; Heating; other nucleophiles; var. reaction conditions;98%
In benzene for 3h; Mechanism; Heating;98%
dimethyl dicarbonate
4525-33-1

dimethyl dicarbonate

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
magnesium(II) perchlorate In nitromethane at 40℃; for 16h;98%
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In N,N-dimethyl-formamide at 20℃; for 48h; Sealed tube; Inert atmosphere; Irradiation;
methanol
67-56-1

methanol

p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

carbon monoxide
201230-82-2

carbon monoxide

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In N,N-dimethyl-formamide at 80℃; under 2327.23 Torr;98%
With triethylamine at 100℃; under 3750.38 Torr; for 1.5h; Inert atmosphere;95%
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In N,N-dimethyl-formamide at 100℃; under 5250.53 Torr; continuous flow reactor;81%
N-methyl-N-nitrosotoluene-p-sulfonamide
80-11-5

N-methyl-N-nitrosotoluene-p-sulfonamide

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; methanol; water at 20℃;98%
Stage #1: N-methyl-N-nitrosotoluene-p-sulfonamide With potassium hydroxide In methanol; water; N,N-dimethyl-formamide Flow reactor;
Stage #2: 4-nitro-benzoic acid In methanol; diethyl ether; water; N,N-dimethyl-formamide at 0 - 25℃; Sonication;
90%
methanol
67-56-1

methanol

N-amino-(4-nitrophenyl)carboxamide
636-97-5

N-amino-(4-nitrophenyl)carboxamide

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate at 20℃; for 0.25h; Esterification;97%
With Oxone at 20℃; for 6h; oxidative esterification;84%
poly(p-methyltriazenestyrene)

poly(p-methyltriazenestyrene)

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
In 1,2-dimethoxyethane for 16h;97%
methyl chloroformate
79-22-1

methyl chloroformate

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With dmap; triethylamine In acetonitrile97%
tetramethylorthosilicate
681-84-5

tetramethylorthosilicate

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride; (t-Bu2POH)2PdCl2 In acetonitrile at 50℃; for 24h;97%
phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With diethylazodicarboxylate In tetrahydrofuran for 2h;96%
With diethylazodicarboxylate In tetrahydrofuran for 2h; Mechanism; other phosphite, other carboxylic acid, phenols, imides and C-H acids;92%
methanol
67-56-1

methanol

formaldehyd
50-00-0

formaldehyd

1,3-diphenylpropanedione
120-46-7

1,3-diphenylpropanedione

A

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

B

bis-1,5(4-nitrophenyl)-1,5-pentanedione
21600-84-0

bis-1,5(4-nitrophenyl)-1,5-pentanedione

Conditions
ConditionsYield
hydroxocobalt(III) Schiff base at 60℃; for 1.5h; Product distribution; Mechanism; var. 4-subst. educts; var. reaction conditions;A 92%
B 96%
methanol
67-56-1

methanol

1-(4-nitrophenyl)propan-1-one
3758-70-1

1-(4-nitrophenyl)propan-1-one

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With N,N-dimethyl-formamide dimethyl acetal for 16h; Heating;95%
methyl 2-hydroxy-5-nitrobenzoate
17302-46-4

methyl 2-hydroxy-5-nitrobenzoate

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

A

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

B

5-nitrosalicylic acid
96-97-9

5-nitrosalicylic acid

Conditions
ConditionsYield
Stage #1: 4-nitro-benzoic acid With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl 2-hydroxy-5-nitrobenzoate at 110℃; for 24h; Temperature;
A 95%
B n/a
methanol
67-56-1

methanol

N,N-(Boc)2-4-nitrobenzamide

N,N-(Boc)2-4-nitrobenzamide

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With C26H28N3O3S(1+)*F6P(1-); nickel diacetate; potassium carbonate; triethylamine at 25℃; for 2h;95%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With sulfuric acid at 80 - 85℃; for 9.5h; Neat (no solvent);94.2%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 0.0180556h; microwave irradiation;90%
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry;86%
methanol
67-56-1

methanol

4-nitro-benzoyl chloride
122-04-3

4-nitro-benzoyl chloride

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane for 0.166667h;94%
With pyridine at 70℃; for 3h;91%
at 25℃; Thermodynamic data; ΔH;
benzyl alcohol
100-51-6

benzyl alcohol

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With 4-methyl-morpholine; 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride at 20℃; for 2.5h; Esterification;94%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In N,N-dimethyl-formamide at 80℃; under 2327.23 Torr;94%
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; under 11251.1 Torr; continuous flow reactor;77%
With palladium diacetate; triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; hydrazine In tetrahydrofuran; 1,4-dioxane at 100℃; under 11251.1 Torr; Temperature; Flow reactor;77%
With ruthenium(III) trichloride hydrate; 1,4-bis(2'-diphenylphosphino-3'-methylimidazolium)butane triflate; triethylamine In 1-methyl-pyrrolidin-2-one at 140℃; under 15001.5 Torr; for 16h; Autoclave;80 %Chromat.
methanol
67-56-1

methanol

1-(4-nitrophenyl)-3-phenyl-1-propanone
54914-77-1

1-(4-nitrophenyl)-3-phenyl-1-propanone

A

3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

B

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With N,N-dimethyl-formamide dimethyl acetal for 16h; Heating;A n/a
B 93%
4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: 4-nitrobenzyl chloride With sodium chlorite; sodium dihydrogenphosphate; Me-AZADO+Cl- In dichloromethane; water at 25℃; for 1.5h;
Stage #2: With 2-methyl-but-2-ene In dichloromethane; water
Stage #3: diazomethane With hydrogenchloride; sodium hydroxide Product distribution / selectivity; more than 3 stages;
93%
Stage #1: 4-nitrobenzyl chloride With sodium chlorite; sodium dihydrogenphosphate; 2,2,6,6-tetramethylpiperidin-1-oxoammonium chloride In dichloromethane; water at 25℃; for 1.5h;
Stage #2: With 2-methyl-but-2-ene In dichloromethane; water
Stage #3: diazomethane With hydrogenchloride; sodium hydroxide Product distribution / selectivity; more than 3 stages;
63%
4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol; N–nitrosaccharin at 60℃; for 19h; Reagent/catalyst; Inert atmosphere; Schlenk technique;93%
With Iron(III) nitrate nonahydrate In toluene at 80℃; for 18h; Inert atmosphere;86%
With dipotassium peroxodisulfate; bismuth (III) nitrate pentahydrate In benzene at 70℃; for 12h; Inert atmosphere;74%
With copper(I) oxide; tetrabutylammonium nitrite In acetonitrile at 20℃;53%
methanol
67-56-1

methanol

N-(4-nitrobenzoyl)oxazolidinone
25393-54-8

N-(4-nitrobenzoyl)oxazolidinone

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

Conditions
ConditionsYield
With [t-Bu2SnCl(OH)]2 In toluene at 85℃; for 14h;92%
ethanol
64-17-5

ethanol

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

ethyl 4-nitrobenzoate
99-77-4

ethyl 4-nitrobenzoate

Conditions
ConditionsYield
With tert-butylamine for 10h; Heating;100%
Stage #1: ethanol With platinum(IV) oxide; hydrogen at 60℃; under 750.075 - 1500.15 Torr; for 2h; Autoclave; Green chemistry;
Stage #2: 4-nitrobenzoic acid methyl ester at 60℃; Autoclave; Inert atmosphere; Green chemistry; chemoselective reaction;
93%
With dichlorobis(1-butylimidazolium) zinc at 70 - 80℃;93%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

N-[(4-methoxycarbonyl)phenyl]hydroxylamine
24226-29-7

N-[(4-methoxycarbonyl)phenyl]hydroxylamine

Conditions
ConditionsYield
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; for 5h; Inert atmosphere;100%
With 5% rhodium-on-charcoal; hydrazine hydrate In tetrahydrofuran at 0℃; Inert atmosphere;100%
With rhodium contaminated with carbon; hydrazine hydrate In tetrahydrofuran at 0℃; for 5h; Inert atmosphere;100%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

4-methoxycarbonyl aniline
619-45-4

4-methoxycarbonyl aniline

Conditions
ConditionsYield
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran; water at 20℃; for 0.5h;100%
With potassium fluoride; polymethylhydrosiloxane; palladium diacetate In tetrahydrofuran at 20℃; for 0.5h;100%
With sodium tetrahydroborate; water In ethanol at 25℃; for 1h; Solvent; chemoselective reaction;100%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

acetonitrile
75-05-8

acetonitrile

methyl 4-(ethylamino)benzoate
79663-14-2

methyl 4-(ethylamino)benzoate

Conditions
ConditionsYield
With palladium 10% on activated carbon; ammonium acetate; hydrogen In methanol at 20℃; under 760.051 Torr; for 24h;100%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

Conditions
ConditionsYield
With AlBrCl3(1-)*C5H5N*H(1+) at 140℃; for 3h;99%
With methanesulfonic acid; 1-methylimidazolium hydrobromide at 120℃; for 2h;96%
With iron(III) sulfate; water In toluene at 110℃; for 4h; Ionic liquid;95%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

benzyl alcohol
100-51-6

benzyl alcohol

benzyl 4-nitrobenzoate
14786-27-7

benzyl 4-nitrobenzoate

Conditions
ConditionsYield
With lanthanum(III) nitrate hexahydrate; TOP at 110℃; for 5h; Reagent/catalyst; Molecular sieve;99%
With N,N'-biscyclohexyl-imidazol-2-ylidene; 4 A molecular sieve In tetrahydrofuran at 20℃; for 0.25h;96%
1,3-dicyclohexyl-imidazol-2-ylidene In tetrahydrofuran at 20℃; for 0.25h;96%
1-octadecanol
112-92-5

1-octadecanol

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

octadecyl 4-nitro-benzoate
56426-96-1

octadecyl 4-nitro-benzoate

Conditions
ConditionsYield
Stage #1: 1-octadecanol; 4-nitrobenzoic acid methyl ester In xylene for 0.5h; Heating;
Stage #2: With TiO(acac)2 In xylene for 4.5h; Heating;
99%
1.3-propanedithiol
109-80-8

1.3-propanedithiol

4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

1,3-di(4-methoxycarbonylphenylthio)propane

1,3-di(4-methoxycarbonylphenylthio)propane

Conditions
ConditionsYield
With caesium carbonate In dimethyl sulfoxide at 25℃; for 1.5h;99%
With magnesium methanolate In N,N-dimethyl-formamide at 80℃; for 8h;78%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

butan-1-ol
71-36-3

butan-1-ol

butyl p-nitrobenzoate
120-48-9

butyl p-nitrobenzoate

Conditions
ConditionsYield
With Zn4(OCOCF3)6O In di-isopropyl ether for 40h; Heating;99%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

hexan-1-ol
111-27-3

hexan-1-ol

4-nitrophenyl hexanoate
6268-24-2

4-nitrophenyl hexanoate

Conditions
ConditionsYield
With tetrabutylammonium acetate; oxiranyl-methanol In hexane for 2h; Reflux;99%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

dimethyl 4,4'-azoxydibenzoate
23663-92-5

dimethyl 4,4'-azoxydibenzoate

Conditions
ConditionsYield
With potassium hydroxide In water; isopropyl alcohol at 30℃; under 760.051 Torr; for 10h; Inert atmosphere;98%
With manganese; acetic acid In tetrahydrofuran; water at 20℃; for 15h;70%
With triethylsilane; indium(III) bromide In N,N-dimethyl-formamide at 60℃; for 12h;64%
With bismuth; sodium hydroxide; sodium tetrahydroborate; oxygen 1.) methanol, room temperature, 0.5 h, 2.) methanol, room temperate, 4 h; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: 78 percent / Sb, NaBH4 / methanol / 1 h / Ambient temperature
2: 88 percent / NaOH, O2 / 4 h / Ambient temperature
View Scheme
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

propan-1-ol-3-amine
156-87-6

propan-1-ol-3-amine

N-(3-Hydroxy-propyl)-4-nitro-benzamid
90690-76-9

N-(3-Hydroxy-propyl)-4-nitro-benzamid

Conditions
ConditionsYield
With ammonium nitrate In neat (no solvent) at 20℃; for 12h; Green chemistry;98%
In toluene at 97℃; for 4h; Acylation;79%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

N,N-diethylethylenediamine
100-36-7

N,N-diethylethylenediamine

N-(2-(diethylamino)ethyl)-4-nitrobenzamide
1664-52-4

N-(2-(diethylamino)ethyl)-4-nitrobenzamide

Conditions
ConditionsYield
With ammonium nitrate In neat (no solvent) at 20℃; for 12h; Green chemistry;98%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

4-nitrobenzamide
619-80-7

4-nitrobenzamide

Conditions
ConditionsYield
With ammonia In methanol at 70℃;98%

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