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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Ethanethioamide,N-phenyl-

Cas:637-53-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic THIOACETANILIDE 637-53-6 Manufacturer

Cas:637-53-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

High purity CAS 637-53-6 THIOACETANILIDE in stock Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediates (Fluorene,Ca

High purity CAS 637-53-6 THIOACETANILIDE in stock

Cas:637-53-6

Min.Order:1 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 637-53-6 with competitive price

Cas:637-53-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanethioamide,N-phenyl-

Cas:637-53-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethanethioamide,N-phenyl-

Cas:637-53-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

THIOACETANILIDE

Cas:637-53-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Thioacetanilide

Cas:637-53-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Thioacetanilide

Cas:637-53-6

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Thioacetanilide

Cas:637-53-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Thioacetanilide

Cas:637-53-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Ethanethioamide,N-phenyl- cas 637-53-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Ethanethioamide,N-phenyl- cas 637-53-6

Cas:637-53-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

THIOACETANILIDE

Cas:637-53-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

THIOACETANILIDE

Cas:637-53-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

THIOACETANILIDE

Cas:637-53-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

THIOACETANILIDE

Cas:637-53-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the N-Phenylethanthioamid, CAS:637-53-6 with the most competitive price and the best qual

N-Phenylethanthioamid

Cas:637-53-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

thioacetanilide

Cas:637-53-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

SPECS

1.2 gram in stock of Specs ID AQ-012/40221353.

Ethanethioamide,N-phenyl-

Cas:637-53-6

Min.Order:0

Negotiable

Type:Other

inquiry

Organo Fine Chemical

Thioacetanilide 99%

Thioacetanilide 99%

Cas:637-53-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

mercury(II) diacetate
1600-27-7

mercury(II) diacetate

bis(thioacetanilide)mercury(II)

bis(thioacetanilide)mercury(II)

A

thioacetanilide
637-53-6

thioacetanilide

B

N-acetyl-N-phenylacetamide
1563-87-7

N-acetyl-N-phenylacetamide

Conditions
ConditionsYield
In dichloromethane for 3h; Ambient temperature;A n/a
B 100%
Acetanilid
103-84-4

Acetanilid

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With 2,4-bis(4-(5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluorodecyloxy)phenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide In tetrahydrofuran at 55℃; for 6h;97%
With 2,4-{[3-[(CH2)5C8F17]-4-MeO-phenyl]}2-P2S2 2,4-disulfide for 0.05h; microwave irradiation;96%
With Lawessons reagent for 0.0333333h; microwave irradiation;96%
acetophenone oxime
613-91-2

acetophenone oxime

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
Stage #1: acetophenone oxime With triethylamine; p-toluenesulfonyl chloride In acetonitrile at 0 - 20℃; Inert atmosphere;
Stage #2: With thiourea In acetonitrile for 2h; Reflux; Inert atmosphere;
90%
With tetraphosphorus decasulfide In benzene at 80℃; for 0.5h; Beckmann Rearrangement;90%
With trichlorothiophosphine; water; triethylamine at 0 - 75℃; Beckmann rearrangement; chemoselective reaction;78%
acetophenone
98-86-2

acetophenone

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate; O,O-Diethyl hydrogen phosphorodithioate In 1,4-dioxane at 80 - 90℃; for 2h; Inert atmosphere;89%
aniline
62-53-3

aniline

Thioacetic acid S-(5,5-dimethyl-2-thioxo-2λ5-[1,3,2]dioxaphosphinan-2-yl) ester
157841-92-4

Thioacetic acid S-(5,5-dimethyl-2-thioxo-2λ5-[1,3,2]dioxaphosphinan-2-yl) ester

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
Stage #1: Thioacetic acid S-(5,5-dimethyl-2-thioxo-2λ5-[1,3,2]dioxaphosphinan-2-yl) ester With 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane In benzene for 3h; Heating;
Stage #2: aniline With triethylamine In benzene cooling; Further stages.;
87.8%
aniline
62-53-3

aniline

thioacetic acid
507-09-5

thioacetic acid

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With 1H-imidazole; iodine; chloro-diphenylphosphine In dichloromethane for 0.75h; Reflux;85%
With 1,2-bis(5-methylisoxazol-3-yl)hydrazine; triphenylphosphine In acetonitrile for 4.5h; Mitsunobu reaction; Reflux;83%
morpholine
110-91-8

morpholine

2-thioxo-4-thiazolidinone
141-84-4

2-thioxo-4-thiazolidinone

Acetanilid
103-84-4

Acetanilid

A

2-morpholin-4-yl-2-thiazole-4(5H)-one
16781-67-2

2-morpholin-4-yl-2-thiazole-4(5H)-one

B

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With MCM-41 mesoporous silica In ethanol; water at 80 - 90℃; for 8h; Green chemistry;A n/a
B 70%
methyllithium
917-54-4

methyllithium

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -78℃; for 0.5h;70%
copper diacetate
142-71-2

copper diacetate

bis(thioacetanilide)mercury(II)

bis(thioacetanilide)mercury(II)

A

thioacetanilide
637-53-6

thioacetanilide

B

N-acetyl-N-phenylacetamide
1563-87-7

N-acetyl-N-phenylacetamide

Conditions
ConditionsYield
In dichloromethane for 120h; Ambient temperature;A n/a
B 59%
acetic acid
64-19-7

acetic acid

aniline
62-53-3

aniline

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With O,O-Diethyl hydrogen phosphorodithioate In toluene for 8h; Heating;51%
C16H16N2S2
10319-73-0

C16H16N2S2

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform at 5℃; for 15h;33%
Lawessons reagent
19172-47-5

Lawessons reagent

N-Phenylacetohydroxamic acid
1795-83-1

N-Phenylacetohydroxamic acid

A

N-hydroxy-N-phenyl-thioacetamide

N-hydroxy-N-phenyl-thioacetamide

B

C15H16NO4PS

C15H16NO4PS

C

thioacetanilide
637-53-6

thioacetanilide

D

Acetanilid
103-84-4

Acetanilid

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Further byproducts given. Title compound not separated from byproducts;A 5%
B n/a
C 28%
D 50 % Spectr.
(4-acetamidophenyl)disulfide
16766-09-9

(4-acetamidophenyl)disulfide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
at 240 - 260℃;
N-phenyl-3-thio-malonamic acid
10394-24-8

N-phenyl-3-thio-malonamic acid

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With water Heating;
beim Erhitzen;
dithioacetic acid
594-03-6

dithioacetic acid

phenyl isocyanate
103-71-9

phenyl isocyanate

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With toluene
dithioacetic acid
594-03-6

dithioacetic acid

phenyl isocyanate
103-71-9

phenyl isocyanate

toluene
108-88-3

toluene

A

carbon oxide sulfide
463-58-1

carbon oxide sulfide

B

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
methyl magnesium iodide
917-64-6

methyl magnesium iodide

diethyl ether
60-29-7

diethyl ether

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
durch nachfolgende Behandlung des Reaktionspr. mit Wasser und verd. Schwefelsaeure;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With diethyl ether und Behandeln des Aetherrueckstandes mit Eiswasser und verd.Schwefelsaeure;
dithioacetic acid
594-03-6

dithioacetic acid

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With toluene
dithioacetic acid
594-03-6

dithioacetic acid

phenyl isothiocyanate
103-72-0

phenyl isothiocyanate

toluene
108-88-3

toluene

A

carbon disulfide
75-15-0

carbon disulfide

B

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
diethyl ether
60-29-7

diethyl ether

N-phenylacetimidoyl chloride
874-69-1

N-phenylacetimidoyl chloride

thioacetamide
62-55-5

thioacetamide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
reagiert analog mit N-Phenyl-benzimidchlorid;
N-phenylacetimidoyl chloride
874-69-1

N-phenylacetimidoyl chloride

thioacetamide
62-55-5

thioacetamide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With diethyl ether
diethyl ether
60-29-7

diethyl ether

N-phenyl-benzimidoyl chloride
4903-36-0

N-phenyl-benzimidoyl chloride

benzenecarbothioamide
2227-79-4

benzenecarbothioamide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
O-Ethyl thioacetate
926-67-0

O-Ethyl thioacetate

diethyl ether
60-29-7

diethyl ether

aniline
62-53-3

aniline

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
O-Ethyl thioacetate
926-67-0

O-Ethyl thioacetate

aniline
62-53-3

aniline

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With diethyl ether
diethyl ether
60-29-7

diethyl ether

N-phenylacetimidoyl chloride
874-69-1

N-phenylacetimidoyl chloride

benzenecarbothioamide
2227-79-4

benzenecarbothioamide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
N-phenylacetimidoyl chloride
874-69-1

N-phenylacetimidoyl chloride

benzenecarbothioamide
2227-79-4

benzenecarbothioamide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With diethyl ether
Acetanilid
103-84-4

Acetanilid

A

thioacetanilide
637-53-6

thioacetanilide

B

N,N'-diphenylacetamidine
621-09-0, 141417-91-6, 1086215-03-3

N,N'-diphenylacetamidine

Conditions
ConditionsYield
With tetraphosphorus decasulfide
(E)-1-phenylethanone oxime
10341-75-0

(E)-1-phenylethanone oxime

benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
With pyridine beim Behandeln anschliessend mit H2S;
O-Ethyl thioacetate
926-67-0

O-Ethyl thioacetate

anilinomagnesium bromide

anilinomagnesium bromide

thioacetanilide
637-53-6

thioacetanilide

Conditions
ConditionsYield
thioacetanilide
637-53-6

thioacetanilide

Acetanilid
103-84-4

Acetanilid

Conditions
ConditionsYield
With 6H(1+)*Mo9O40PV3(6-); oxygen In acetonitrile at 60℃; under 760.051 Torr; for 0.5h; Inert atmosphere; Glovebox;99%
With eosin; oxygen In N,N-dimethyl-formamide at 20℃; for 6h; Reagent/catalyst; Solvent; Irradiation; Green chemistry;93%
With P,P-dichlorophenylphosphine oxide In acetonitrile at -4℃; for 3h;90%
phenylsulfonyl azide
938-10-3

phenylsulfonyl azide

thioacetanilide
637-53-6

thioacetanilide

N-phenyl-N'-benzenesulfonylacetamidine

N-phenyl-N'-benzenesulfonylacetamidine

Conditions
ConditionsYield
In ethanol for 1h; Temperature; Solvent; Reflux; chemoselective reaction;99%
In ethanol at 20℃; for 20h;63%
thioacetanilide
637-53-6

thioacetanilide

phenylacetylene
536-74-3

phenylacetylene

N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide
1068465-05-3

N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide

Conditions
ConditionsYield
With TOP; bis(2-methallyl)(cycloocta-1,5-diene)ruthenium(II) In toluene at 100℃; for 15h; Molecular sieve; Inert atmosphere;98%
thioacetanilide
637-53-6

thioacetanilide

Methanesulfonyl azide
624-90-8, 1516-70-7

Methanesulfonyl azide

N-phenyl-N'-methanesulfonylacetamidine

N-phenyl-N'-methanesulfonylacetamidine

Conditions
ConditionsYield
In ethanol for 1h; Temperature; Solvent; Reflux; chemoselective reaction;97%
pentacarbonyl[3-(cyclohex-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

pentacarbonyl[3-(cyclohex-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

thioacetanilide
637-53-6

thioacetanilide

syn-pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

syn-pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

Conditions
ConditionsYield
In diethyl ether under Ar atm. pentacarbonyl(3-(cyclohex-1-yl)-1-ethoxy-2-propyn-1-ylidene)tungsten was reacted with (N-phenyl)thioacetamide in diethyl ether at20°C for 25 min; ppt. was collected, washed with n-pentane and dried in vacuo; elem. anal.;96%
thioacetanilide
637-53-6

thioacetanilide

3-(trifluoromethyl)benzenesulfonyl azide

3-(trifluoromethyl)benzenesulfonyl azide

N'-((3-trifluoromethylphenyl)sulfonyl)-N-phenylacetimidamide

N'-((3-trifluoromethylphenyl)sulfonyl)-N-phenylacetimidamide

Conditions
ConditionsYield
In ethanol at 20℃; for 17h;95%
pentacarbonyl[3-(cyclohept-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

pentacarbonyl[3-(cyclohept-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

thioacetanilide
637-53-6

thioacetanilide

syn-pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

syn-pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

Conditions
ConditionsYield
In diethyl ether under Ar atm. pentacarbonyl(3-(cyclohex-1-yl)-1-ethoxy-2-propyn-1-ylidene)tungsten was reacted with (N-phenyl)thioacetamide in diethyl ether at20°C for 25 min; ppt. was collected, washed with n-pentane and dried in vacuo; elem. anal.;94%
thioacetanilide
637-53-6

thioacetanilide

3,5-bis(trifluoromethyl)phenylsulfonyl azide
1431968-93-2

3,5-bis(trifluoromethyl)phenylsulfonyl azide

N'-((3,5-bis(trifluoromethyl)phenyl)sulfonyl)-N-phenylacetimidamide

N'-((3,5-bis(trifluoromethyl)phenyl)sulfonyl)-N-phenylacetimidamide

Conditions
ConditionsYield
In ethanol at 20℃; for 7h;93%
1,3-diethyl 2-diazopropanedioate
5256-74-6

1,3-diethyl 2-diazopropanedioate

thioacetanilide
637-53-6

thioacetanilide

diethyl 2-(1-(phenylamino)ethylidene)malonate
81022-80-2

diethyl 2-(1-(phenylamino)ethylidene)malonate

Conditions
ConditionsYield
With tris(triphenylphosphine)ruthenium(II) chloride In benzene at 90℃; for 4h; Reagent/catalyst; Time; Inert atmosphere; Sealed tube;92%
With copper(I)-complexed magnetic nanoparticle catalyst In 1,2-dichloro-ethane at 70℃; for 5h;90%
With (CuOTf)2*Tol In 1,2-dichloro-ethane at 90℃; for 9h; Inert atmosphere; Sealed tube;74%
ethyl 2-diazo-3-oxobutanoate
2009-97-4

ethyl 2-diazo-3-oxobutanoate

thioacetanilide
637-53-6

thioacetanilide

2-acetyl-3-phenylaminobut-2-enoic acid ethyl ester

2-acetyl-3-phenylaminobut-2-enoic acid ethyl ester

Conditions
ConditionsYield
With copper(I)-complexed magnetic nanoparticle catalyst In 1,2-dichloro-ethane at 70℃; for 3h; diastereoselective reaction;91%
2-bromo-2-propenoic acid
10443-65-9

2-bromo-2-propenoic acid

thioacetanilide
637-53-6

thioacetanilide

4-carboxy-2-methyl-3-phenyl-Δ2-thiazolinium bromide

4-carboxy-2-methyl-3-phenyl-Δ2-thiazolinium bromide

Conditions
ConditionsYield
In toluene at 90℃; for 1h;90%
In toluene at 90℃;
tetra[μ-acetato-bis(methanol)]dirhodium

tetra[μ-acetato-bis(methanol)]dirhodium

thioacetanilide
637-53-6

thioacetanilide

Rh2(OC2Me)4(N-phenylthioacetamide)2

Rh2(OC2Me)4(N-phenylthioacetamide)2

Conditions
ConditionsYield
In ethanol soln. of ligand added to soln. of Rh-complex with stirring (1 h);; filtered, washed with absolute EtOH, dried in vacuo, washed with abundant pentane, elem. anal.;;90%
[(Fe(CO)3)2(μ-S(Me)C(CF3)CFC(NMe2))]

[(Fe(CO)3)2(μ-S(Me)C(CF3)CFC(NMe2))]

thioacetanilide
637-53-6

thioacetanilide

[(Fe(CO)3)2( μ-S(CH3)C(CF3)C β (SC(NPh)Me) C α (N(CH3)2))]
436162-62-8

[(Fe(CO)3)2( μ-S(CH3)C(CF3)C β (SC(NPh)Me) C α (N(CH3)2))]

Conditions
ConditionsYield
In tetrahydrofuran room temp., 3 hs, (Ar); filtration (celite), vac. evapn., washing (-50 °C, pentane), elem. anal.;90%
pentacarbonyl[3-(cyclopent-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

pentacarbonyl[3-(cyclopent-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

thioacetanilide
637-53-6

thioacetanilide

pentacarbonyl[N-phenyl-thioacetimidic acid (3-ethoxy-2,4,5,6-tetrahydropentalen-1-yl) ester-N]tungsten

pentacarbonyl[N-phenyl-thioacetimidic acid (3-ethoxy-2,4,5,6-tetrahydropentalen-1-yl) ester-N]tungsten

Conditions
ConditionsYield
With triethylamine In dichloromethane under Ar atm. pentacarbonyl(3-(cyclopent-1-yl)-1-ethoxy-2-propyn-1-ylidene)tungsten was reacted with (N-phenyl)thioacetamide in dichloromethanein the presence of 1 equiv. triethylamine with stirring for 20 min at 20°C; fast chromy. on silica; elem. anal.;89%
thioacetanilide
637-53-6

thioacetanilide

1-chloro-1-phenyl-2,2,2-trifluoroethyl isocyanate
57959-52-1

1-chloro-1-phenyl-2,2,2-trifluoroethyl isocyanate

6-Methylene-2,5-diphenyl-2-trifluoromethyl-[1,3,5]thiadiazinan-4-one

6-Methylene-2,5-diphenyl-2-trifluoromethyl-[1,3,5]thiadiazinan-4-one

Conditions
ConditionsYield
With triethylamine In benzene for 3h;88%
thioacetanilide
637-53-6

thioacetanilide

5-methyl-1-phenyl-1H-tetrazole
14213-16-2

5-methyl-1-phenyl-1H-tetrazole

Conditions
ConditionsYield
With sodium azide; tetrachlorosilane In acetonitrile at 20 - 82℃; for 6h;87%
N-nitrosoacetanilide
938-81-8

N-nitrosoacetanilide

thioacetanilide
637-53-6

thioacetanilide

A

2,2'-dipyridyldisulphide
2127-03-9

2,2'-dipyridyldisulphide

B

N-Phenyl-thioacetimidic acid phenyl ester
87107-49-1

N-Phenyl-thioacetimidic acid phenyl ester

C

Acetanilid
103-84-4

Acetanilid

Conditions
ConditionsYield
Product distribution;A 86%
B 71%
C 75%
pentacarbonyl[3-(cyclohept-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

pentacarbonyl[3-(cyclohept-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

thioacetanilide
637-53-6

thioacetanilide

pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7,8-pentahydro-3aH-azulen-1-yl) ester-N]tungsten

Conditions
ConditionsYield
With triethylamine In dichloromethane under Ar atm. pentacarbonyl(3-(cyclohept-1-yl)-1-ethoxy-2-propyn-1-ylidene)tungsten was reacted with (N-phenyl)thioacetamide in dichloromethanein the presence of 1 equiv. triethylamine with stirring for 20 min at 20°C; elem. anal.;86%
di(rhodium)tetracarbonyl dichloride

di(rhodium)tetracarbonyl dichloride

thioacetanilide
637-53-6

thioacetanilide

{Rh2(CO)4(μ-CH3CSN(C6H5))2}

{Rh2(CO)4(μ-CH3CSN(C6H5))2}

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran byproducts: H2; addn. of N-phenylacetamide to a stirred suspn. of NaH (THF), filtn. of soln. into a stirred soln. of starting Rh-complex (THF, -78°C), all steps under N2; evapg. to dryness, extg. of residue (hexane), concg., cooling to 0°C, elem. anal.;84%
With triethylamine In not given
thioacetanilide
637-53-6

thioacetanilide

3-nitrobenzenesulfonyl azide
6647-85-4

3-nitrobenzenesulfonyl azide

N'-((3-nitrophenyl)sulfonyl)-N-phenylacetimidamide

N'-((3-nitrophenyl)sulfonyl)-N-phenylacetimidamide

Conditions
ConditionsYield
In ethanol at 20℃; for 20h;84%
pentacarbonyl[3-(cyclohex-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

pentacarbonyl[3-(cyclohex-1-enyl)-1-ethoxy-2-propyn-1-ylidene]tungsten

thioacetanilide
637-53-6

thioacetanilide

pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

pentacarbonyl[N-phenylthioacetimidic acid (3-ethoxy-4,5,6,7-tetrahydro-3aH-inden-1-yl) ester-N]tungsten

Conditions
ConditionsYield
With triethylamine In dichloromethane under Ar atm. pentacarbonyl(3-(cyclohex-1-yl)-1-ethoxy-2-propyn-1-ylidene)tungsten was reacted with (N-phenyl)thioacetamide in dichloromethane in the presence of 1 equiv. triethylamine with stirring for 20 min at 20°C; elem. anal.;83%
thioacetanilide
637-53-6

thioacetanilide

acetic acid hydrazide
1068-57-1

acetic acid hydrazide

3,5-dimethyl-4-phenyl-4H-[1,2,4]triazole
13576-46-0

3,5-dimethyl-4-phenyl-4H-[1,2,4]triazole

Conditions
ConditionsYield
With mercury(II) diacetate In tetrahydrofuran microwave irradiation;82%
In butan-1-ol for 16h; Heating; Yield given;
(–)-menthone

(–)-menthone

thioacetanilide
637-53-6

thioacetanilide

2-[(1R,2S,5R)-1-hydroxy-5-methyl-2-(propan-2-yl)cyclohexyl]-N-phenylethanethioamide

2-[(1R,2S,5R)-1-hydroxy-5-methyl-2-(propan-2-yl)cyclohexyl]-N-phenylethanethioamide

Conditions
ConditionsYield
Stage #1: thioacetanilide With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran at -5 - 5℃; for 1.5h; Inert atmosphere;
Stage #2: (–)-menthone In tetrahydrofuran at -15 - -5℃; Inert atmosphere; stereoselective reaction;
81%
4-toluenesulfonyl azide
941-55-9

4-toluenesulfonyl azide

thioacetanilide
637-53-6

thioacetanilide

N-phenyl-N'-tosylacetimidamide
27049-62-3

N-phenyl-N'-tosylacetimidamide

Conditions
ConditionsYield
In pyridine at 90 - 100℃; for 5h;79%
In ethanol at 20℃; for 20h;46%

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