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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

manufactory of 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

BeiJing Greenchem Technology Co.,Ltd. was established by many people who are experienced in both management and professional technology in large and medium-sized pharmaceutical enterprises. It is located in Zhongguancun Technology Park, the synthesis

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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GIHI CHEMICALS CO.,LIMITED

GIHI CHEMICALS exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, GIHI CHEMICALS is your best choice. pls contact with us freely for getting detailed produc

2-Dicyclohexylphosphino-2,6-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl CAS number 657408-07-6 Assay ≥99% Appearance White powder Capacity 200mt/year Applicati

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

2-dicyclohexylPhosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

Dicyclohexyl(2',6'-dimethoxybiphenyl-2-yl)phosphine

Cas:657408-07-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Dicyclohexylphosphino-2',6'-Dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 657408-07-6 2-Dicyclohexylphosphino-2,6-dimethoxybiphenyl Manufacturer

Cas:657408-07-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

CHemwill -- 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU CHEM 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Enterprice standard Appearance:white Storage:dry Package:25kg net/paper drum Application:Diphenyl phosphine catalyst Transportation:by air , by sea Port:Shanghai

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 657408-07-6 with best quality

Cas:657408-07-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name 2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl/Sphos Structural Formula CAS No. 657408-07-6

2-Dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl

Cas:657408-07-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phosphine,dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)- 657408-07-6

Cas:657408-07-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl Synonyms: 98% SPhos;2-Dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl ,98%;2-Dicyclohexylphosphino-2', 6-diMethoxybihenyl;2-DicyclohexylphosphiNA-2',6

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl CAS:657408-07-6

Cas:657408-07-6

Min.Order:1 Kilogram

FOB Price: $69.0 / 76.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl CAS:657408-07-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, speci

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl CAS:657408-07-6

Cas:657408-07-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl CAS NO.657408-07-6

Cas:657408-07-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:657408-07-6

Cas:657408-07-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

High qualityHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global phar

high purity s-PHOS

Cas:657408-07-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 2-Dicyclohexylphosphino-2’,6’-dimethoxybiphenyl

Cas:657408-07-6

Min.Order:100 Gram

Negotiable

Type:Other

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Synthetic route

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

2'-bromo-2,6-dimethoxybiphenyl
755017-61-9

2'-bromo-2,6-dimethoxybiphenyl

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 2'-bromo-2,6-dimethoxybiphenyl With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Cooling with acetone-dry ice;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran at 20 - 45℃; Inert atmosphere;
88%
Stage #1: 2'-bromo-2,6-dimethoxybiphenyl With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: chlorodicyclohexylphosphane In tetrahydrofuran; hexane at -78 - 20℃;
3.32 g
2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 1,3-Dimethoxybenzene With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 3.5h;
Stage #2: 2-bromo-1-chlorobenzene In tetrahydrofuran at 0℃; for 0.5h;
Stage #3: chlorodicyclohexylphosphane
36%
(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
With 1,3-diphenyl-disiloxane In toluene at 110℃; Sealed tube; chemoselective reaction;87%
2'-chloro-2,6-dimethoxy-1,1'-biphenyl
1380028-15-8

2'-chloro-2,6-dimethoxy-1,1'-biphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Stage #1: 2'-chloro-2,6-dimethoxy-1,1'-biphenyl With sec.-butyllithium In diethyl ether; cyclohexane at -78 - -45℃; Inert atmosphere;
Stage #2: chlorodicyclohexylphosphane In diethyl ether; cyclohexane at -78℃; Inert atmosphere;
48%
2-bromo-1-chlorobenzene
694-80-4

2-bromo-1-chlorobenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 5 h / 0 - 20 °C
1.2: 81 percent / tetrahydrofuran; hexane / 0.25 h / 0 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
2.2: 3.32 g / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

4-methoxy-trans(?)-cinnamic acid

4-methoxy-trans(?)-cinnamic acid

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 5 h / 0 - 20 °C
1.2: 81 percent / tetrahydrofuran; hexane / 0.25 h / 0 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C
2.2: 3.32 g / tetrahydrofuran; hexane / -78 - 20 °C
View Scheme
potassium phosphate

potassium phosphate

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2,6-dimethoxyphenyl)boronic acid
23112-96-1

(2,6-dimethoxyphenyl)boronic acid

1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane / toluene / 70 °C / Inert atmosphere
2.1: sec.-butyllithium / diethyl ether; cyclohexane / -78 - -45 °C / Inert atmosphere
2.2: -78 °C / Inert atmosphere
View Scheme
1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2,2,6,6-tetramethylpiperidinyl-lithium / diethyl ether; tetrahydrofuran / 36 h / -45 °C / Inert atmosphere; Sealed tube
2: diethyl ether / -78 °C / Inert atmosphere; Sealed tube
View Scheme
chlorobenzene
108-90-7

chlorobenzene

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2,2,6,6-tetramethylpiperidinyl-lithium / diethyl ether; tetrahydrofuran / 36 h / -45 °C / Inert atmosphere; Sealed tube
2: diethyl ether / -78 °C / Inert atmosphere; Sealed tube
View Scheme
2,6-dimethoxybiphenyl
13732-86-0

2,6-dimethoxybiphenyl

chlorodicyclohexylphosphane
16523-54-9

chlorodicyclohexylphosphane

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Conditions
ConditionsYield
In diethyl ether at -78℃; Inert atmosphere; Sealed tube;1.3 g
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)
854045-95-7

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)

Conditions
ConditionsYield
In dichloromethane for 1.75h;100%
In dichloromethane at 20℃; for 1h; Darkness;
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate

sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 0 - 40℃; for 24h;
Stage #2: With sodium hydroxide In dichloromethane; water at 0℃; pH=~ 7.0; Cooling with ice;
99%
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 20℃; for 1h; Sealed tube;
Stage #2: With sodium hydroxide In dichloromethane; water at 20℃; for 0.25h; pH=14; Sealed tube; Cooling with ice; regioselective reaction;
85%
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane at 0 - 40℃; for 24.7h; Inert atmosphere;
Stage #2: With sodium hydroxide In dichloromethane; water at 0℃; pH=13;
62%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

Pd(π-cinnamyl)(SPhos)Cl

Pd(π-cinnamyl)(SPhos)Cl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h; Schlenk technique; Inert atmosphere;99%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

[Pd(μ-Cl)(Cl)(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)]2

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(PCy2-(2',6'-oMe2-2-byphenyl))]

[PdCl2(N,N′-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)(PCy2-(2',6'-oMe2-2-byphenyl))]

Conditions
ConditionsYield
In tetrahydrofuran for 3h; Schlenk technique; Inert atmosphere; Glovebox;98%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(η3-allyl-μ-chloropalladium(II))

bis(η3-allyl-μ-chloropalladium(II))

Pd(π-allyl)(SPhos)Cl

Pd(π-allyl)(SPhos)Cl

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h; Schlenk technique; Inert atmosphere;98%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(acetonitrile)(acetylacetonate)palladium(II) tetrafluoroborate

bis(acetonitrile)(acetylacetonate)palladium(II) tetrafluoroborate

(acetylacetonate-κ2O,O')(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl-κP)palladium(II) tetrafluoroborate

(acetylacetonate-κ2O,O')(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl-κP)palladium(II) tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 2h;97.3%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

hydrogen tetrachloroaurate(III) tetrahydrate

hydrogen tetrachloroaurate(III) tetrahydrate

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)
854045-95-7

chloro(dicyclohexyl(2',6'-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine)gold(I)

Conditions
ConditionsYield
Stage #1: hydrogen tetrachloroaurate(III) tetrahydrate With propyl sulfide In ethanol at 40℃; for 0.166667h;
Stage #2: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane In ethanol at 40℃; for 1h;
97%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C12H10ClNPd

C12H10ClNPd

2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl

2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl

Conditions
ConditionsYield
In acetone at 25℃;96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

4-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine
1429471-42-0

4-chloro-2-(dibenzo[b,d]furan-4-yl)pyridine

2-isopropenyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
126726-62-3

2-isopropenyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine
1421361-86-5

2-(dibenzo[b,d]furan-4-yl)-4-(prop-1-en-2-yl)pyridine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In water; ethyl acetate; toluene96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dihydrogen tetrachloropalladate(II)

dihydrogen tetrachloropalladate(II)

lithium bromide
7550-35-8

lithium bromide

[HSPhos]2[Pd2Br6]

[HSPhos]2[Pd2Br6]

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; dihydrogen tetrachloropalladate(II) In acetone at 18 - 27℃; for 0.5h;
Stage #2: lithium bromide In water; acetone
96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C26H35O8PS2

C26H35O8PS2

Conditions
ConditionsYield
Stage #1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane With sulfuric acid In dichloromethane for 1.5h; Sealed tube;
Stage #2: With fuming sulphuric acid In dichloromethane at 0 - 20℃; for 0.533333h; Sealed tube; regioselective reaction;
96%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Dihydroxy-isobutyl-boran
84110-40-7

Dihydroxy-isobutyl-boran

5,7-dichloro isoquinoline
73075-58-8

5,7-dichloro isoquinoline

5,7-diisobutylisoquinoline
1443013-08-8

5,7-diisobutylisoquinoline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In hexane; water; toluene95%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

2-bromo-3-methylaniline
54879-20-8

2-bromo-3-methylaniline

1-methylphenanthridin-6-amine
1859-17-2

1-methylphenanthridin-6-amine

Conditions
ConditionsYield
With nitrogen In tetrahydrofuran; methanol; dichloromethane95%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II)

2-(2-chlorophenyl)ethanamine
13078-80-3

2-(2-chlorophenyl)ethanamine

chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)
1028206-58-7

chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)

Conditions
ConditionsYield
In further solvent(s) treatment of palladium compd. with chlorobenzene deriv. and phosphine deriv. in methyl tert-butyl ether at 55°C; recrystn.;94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(1,5-cyclooctadiene)diiridium(I) dichloride
12112-67-3

bis(1,5-cyclooctadiene)diiridium(I) dichloride

[IrCl(COD)(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)]
1268489-06-0

[IrCl(COD)(2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl)]

Conditions
ConditionsYield
In toluene under Ar atm. using Schlenk techniques; mixt. of Ir complex and ligand in dry toluene was stirred at room temp. for 3 h; solvent evapd.; cold hexane added; suspn. filtered; washed (cold hexane); elem. anal.;94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

4-dibenzothiophene boronic acid
108847-20-7

4-dibenzothiophene boronic acid

3-(dibenzo[b,d]thiophen-4-yl)-9-phenyl-9H-carbazole

3-(dibenzo[b,d]thiophen-4-yl)-9-phenyl-9H-carbazole

Conditions
ConditionsYield
94%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer
1435520-65-2

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

C26H35O2P*C13H13NO3PdS
1445085-82-4

C26H35O2P*C13H13NO3PdS

Conditions
ConditionsYield
In tetrahydrofuran at 20℃;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II)
225931-80-6

bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II)

para-chlorotoluene
106-43-4

para-chlorotoluene

C33H42ClO2PPd

C33H42ClO2PPd

Conditions
ConditionsYield
In cyclohexane at 20℃; for 18h; Inert atmosphere; Glovebox;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C16H20I2N2Pd2

C16H20I2N2Pd2

C34H45INO2PPd

C34H45INO2PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dihydrogen tetrachloropalladate(II)

dihydrogen tetrachloropalladate(II)

[HSPhos]2[Pd2Cl6]

[HSPhos]2[Pd2Cl6]

Conditions
ConditionsYield
In acetone at 18 - 27℃; for 1.16667h;93%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

N-phenyl-2-aminobiphenylpalladium methanesulfonate
1599466-80-4

N-phenyl-2-aminobiphenylpalladium methanesulfonate

C45H52NO5PPdS
1599466-88-2

C45H52NO5PPdS

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

bis(pentafluorophenyl)(1,5-cyclo-octadiene)palladium(II)
105286-78-0

bis(pentafluorophenyl)(1,5-cyclo-octadiene)palladium(II)

C38H35F10O2PPd

C38H35F10O2PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 48h; Inert atmosphere;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C20H24I2N2O4Pd2

C20H24I2N2O4Pd2

C36H47INO4PPd

C36H47INO4PPd

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;92%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

[Pd2(CH3CN)6][BF4]2

[Pd2(CH3CN)6][BF4]2

C52H70O4P2Pd2(2+)*2BF4(1-)

C52H70O4P2Pd2(2+)*2BF4(1-)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.00166667h; Time;91%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

(2’,6’-dimethoxy-[1,1’-biphenyl]-2-yl)dicyclohexylphosphine oxide

Conditions
ConditionsYield
With dihydrogen peroxide In dichloromethane90%
With oxygen In toluene at 20℃; Product distribution; Further Variations:; Reagents; Temperatures;
With dihydrogen peroxide In diethyl ether at 30℃; for 16h;
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

Dihydroxy-isobutyl-boran
84110-40-7

Dihydroxy-isobutyl-boran

4,6-dichloro-1-(3,5-dimethylphenyl)isoquinoline
1443013-16-8

4,6-dichloro-1-(3,5-dimethylphenyl)isoquinoline

1-(3,5-dimethylphenyl)isoquinoline
1056451-68-3

1-(3,5-dimethylphenyl)isoquinoline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0) In dichloromethane; water; ethyl acetate; toluene90%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

C22H18Cl2N4O2Pd2

C22H18Cl2N4O2Pd2

C37H44ClN2O3PPd

C37H44ClN2O3PPd

Conditions
ConditionsYield
In acetone at 20℃; for 0.5h;90%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

ruthenium trichloride

ruthenium trichloride

C53H46CuN4OP2(1+)*BF4(1-)

C53H46CuN4OP2(1+)*BF4(1-)

C105H115Cl2CuN4O5P4Ru(1+)*BF4(1-)

C105H115Cl2CuN4O5P4Ru(1+)*BF4(1-)

Conditions
ConditionsYield
With sodium acetate In ethanol at 80℃; for 30h; Inert atmosphere;89%
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane
657408-07-6

dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane

dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2
848652-20-0

Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)2Cl2

Conditions
ConditionsYield
In dichloromethane mixt. ligand and (CH3CN)2PdCl2 in CH2Cl2 was stirred; flash chromy. on silica;88%

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