CAS No.80054-40-6,(E,E)-2,6-DiMethyl-2,6-octadienedial Suppliers

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2,6-dimethylocta-2,6-dienedial CAS NO.80054-40-6Appearance:powder Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courier

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Synthetic route

: 38290-51-6
(2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienal

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With manganese(IV) oxide In chloroform for 48h;	88%

: 26488-97-1
8-hydroxygeraniol

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With pyridinium chlorochromate In dichloromethane for 3h; Ambient temperature;	70%

: 141-27-5
3,7-dimethyl-2,6-octadienal

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With selenium(IV) oxide In dichloromethane at 20℃; for 72h; Inert atmosphere;	19%

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 80054-37-1
(2E,8E)-8-hydroxy-3,7-dimethyl-2,6-octadienal

B: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

C: 80054-36-0
(2Z,6E)-8-hydroxyneral

D: 80054-41-7
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With selenium(IV) oxide In ethanol for 0.75h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 108526-78-9
<1-(3)H>-10-hydroxygeraniol

A: 38290-51-6
(2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienal

B: 80054-37-1
(2E,8E)-8-hydroxy-3,7-dimethyl-2,6-octadienal

C: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With NAD Rauwolfia serpentina cell suspension cultures, pH 6.5, incubation;

...Expand

: 156155-53-2
2,6-dimethylocta-2E/Z,6E-dienediol

A: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

B: 80054-41-7
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With manganese(IV) oxide In chloroform for 60h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: [(2)H2]-8-Hydroxygeraniol

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With Plagiodera versicolora defensive secretion In phosphate buffer pH=7.5; Oxidation;

: 5392-40-5
(E/Z)-3,7-dimethyl-2,6-octadienal

A: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

B: 80054-41-7
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
With selenium(IV) oxide In dichloromethane at 25℃; Title compound not separated from byproducts.;

: 105-87-3
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 40 percent / SeO2, t-BuOOH / toluene / 120 h / Ambient temperature 2: 87 percent / aq. K2CO3 / methanol / 1 h 3: 88 percent / MnO2 / CHCl3 / 48 h View Scheme

: 37905-02-5
(2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 87 percent / aq. K2CO3 / methanol / 1 h 2: 88 percent / MnO2 / CHCl3 / 48 h View Scheme

: 156155-54-3
(2E/Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 41 percent / KBH4, LiCl, Amberlit IR C-50 / propan-2-ol; dioxane / 10 h / 20 °C 2: MnO2 / CHCl3 / 60 h View Scheme

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: [(2)H2]-8-Hydroxygeraniol

Conditions

Conditions	Yield
With potassium dihydrogenphosphate; ethanol-d6 for 132h; alcohol-dehydrogenase from horse liver, formiate dehydrogenase from Candida boidinii;	68%

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 4,7-dimethyl-5,6,7,7a-tetrahydrocyclopenta[c]pyran-1(4aH)-one

Conditions

Conditions	Yield
With 3-phenyl-1,4-bis(2,4,6-trimethylphenyl)-1H-1,2,4-triazol-4-ium chloride; N-ethyl-N,N-diisopropylamine In toluene at 60℃; for 6h; Reagent/catalyst;	60%

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 69252-84-2
(1R,4aS,7S,7aR)-nepetalactone

Conditions

Conditions	Yield
With NADPH at 37℃; purified monoterpene cyclase, pH 7;
With mercaptoethyl alcohol; 25 deg C; Rauwolfia serpentina cell suspension; NADPH Dependence of the cyclase activity on pH, temperature and time, and coenzyme specificity;

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 63808-11-7, 66537-23-3, 66884-89-7, 73052-07-0, 75332-42-2, 76375-87-6, 76497-42-2, 83945-84-0
dl-dehydroiridodial

: 63808-11-7, 66537-23-3, 66884-89-7, 73052-07-0, 75332-42-2, 76375-87-6, 76497-42-2, 83945-84-0
dl-chrysomelidial

Conditions

Conditions	Yield
With sodium hydroxide In methanol; water for 0.166667h; Ambient temperature; Yield given. Yields of byproduct given;

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

A: (8R)-[8-2H]-8-hydroxygeranial

B: (1R)-[1-2H]-8-oxogeraniol

Conditions

Conditions	Yield
With potassium dihydrogenphosphate; ethanol-d6 for 96h; alcohol-dehydrogenase from horse liver, formiate dehydrogenase from Candida boidinii; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: C19H23(2)HO4

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: KH2PO4, ethanol-d6, NADD / 96 h / alcohol-dehydrogenase from horse liver, formiate dehydrogenase from Candida boidinii 2: 62 percent / 4-dimethylaminopyridine, N,N'-dicyclohexylcarbodiimide / CH2Cl2 / 3 h / -10 °C View Scheme

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: C19H23(2)HO4

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: KH2PO4, ethanol-d6, NADD / 96 h / alcohol-dehydrogenase from horse liver, formiate dehydrogenase from Candida boidinii 2: 62 percent / 4-dimethylaminopyridine, N,N'-dicyclohexylcarbodiimide / CH2Cl2 / 3 h / -10 °C View Scheme

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 21700-67-4, 24189-97-7, 73088-69-4, 76792-78-4, 76792-79-5, 85506-58-7, 85506-59-8, 85506-60-1, 107795-98-2
dehydroiridodiol(3R*,8S*)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 0.01 N NaOH / methanol; H2O / 0.17 h / Ambient temperature 2: LiAlH4 View Scheme

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 21700-67-4, 24189-97-7, 73088-69-4, 76792-78-4, 76792-79-5, 85506-58-7, 85506-59-8, 85506-60-1, 107795-98-2
isodehydroiridodiol (3R*,8R*)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 0.01 N NaOH / methanol; H2O / 0.17 h / Ambient temperature 2: LiAlH4 View Scheme

: 80054-40-6
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial

: 109215-55-6
(4αS,7S,7αR)nepetalactol

Conditions

Conditions	Yield
With iridoid synthase; NADPH Kinetics; Reagent/catalyst; Enzymatic reaction;

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