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inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
NAPHTHACENE CAS:92-24-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates,
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inquiryNAPHTHACENE Basic information Product Name: NAPHTHACENE Synonyms: TETRACENE;NAPHTHACENE;NAPHTHYCENE;2,3-Benzanthrene;Chrysogen;Methacene;Rubene;Tetracen CAS: 92-24-0 MF: C18H12 MW: 228.29 EINECS: 202-138-9 Mol File: 92-24-0.mol
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Naphthacene cas 92-24-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai
2,3-diethynyl-anthracene
Tetracen
Conditions | Yield |
---|---|
With cyclohexa-1,4-diene In benzene at 160℃; under 12411.9 Torr; cycloaromatization; | 64% |
Tetracen
Conditions | Yield |
---|---|
With hydrogenchloride; tin(ll) chloride In tetrahydrofuran; water for 1h; Inert atmosphere; | 71.5% |
Conditions | Yield |
---|---|
palladium on activated charcoal In xylene for 48h; Heating; | 95% |
With chloranil; acetic acid | |
at 220℃; Erhitzen unter Durchleiten von Luft; | |
With copper at 400℃; |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran for 3h; Ambient temperature; | 83% |
Multi-step reaction with 2 steps 1: aq.-ethanolic NaOH; zinc-powder 2: mineral acid; ethanol View Scheme |
13-methyl-5,12-dihydronaphthacen-5,12-imine
Tetracen
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In acetonitrile for 2h; Heating; | 85% |
1,4:7,10-diepoxy-1,2,3,4,7,8,9,10-octahydronaphthacene
Tetracen
Conditions | Yield |
---|---|
With trifluoroacetic acid In chloroform for 1h; Heating; | 78% |
Tetracen
Conditions | Yield |
---|---|
With titanium tetrachloride In 1,2-dichloro-ethane at 40℃; for 3h; Reagent/catalyst; Temperature; Reflux; | 72% |
Tetracen
Conditions | Yield |
---|---|
With pyrographite In benzene at 80℃; under 760.051 Torr; for 72h; Sealed tube; Darkness; | 23.2 mg |
Conditions | Yield |
---|---|
With oxidizing agent; diborane 1.) diglyme; Multistep reaction; | |
Multi-step reaction with 2 steps 1: aq.-ethanolic NaOH; zinc-powder 2: mineral acid; ethanol View Scheme | |
Multi-step reaction with 2 steps 1: sodium tetrahydroborate / tetrahydrofuran; methanol / 1 h / 20 °C / Inert atmosphere 2: hydrogenchloride; tin(ll) chloride / tetrahydrofuran; water / 1 h / Inert atmosphere View Scheme |
Tetracen
Conditions | Yield |
---|---|
With zinc | |
With copper; zinc |
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: 81 percent / PdCl2dppf / diethyl ether / Heating 2: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 3: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 4: PdCl2dppf / diethyl ether / Heating 5: NaH; MeOH / tetrahydrofuran / 2 h 6: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 6 steps 1: 81 percent / PdCl2dppf / diethyl ether / Heating 2: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 3: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 4: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 5: NaH; MeOH / tetrahydrofuran / 2 h 6: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 6 steps 1: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 2: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 3: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 4: PdCl2dppf / diethyl ether / Heating 5: NaH; MeOH / tetrahydrofuran / 2 h 6: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 6 steps 1: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 2: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 3: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 4: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 5: NaH; MeOH / tetrahydrofuran / 2 h 6: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
1,2-bis(trimethylsilylethynyl)benzene
A
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 8 steps 1: 100 percent / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 3: 81 percent / PdCl2dppf / diethyl ether / Heating 4: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 5: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 6: PdCl2dppf / diethyl ether / Heating 7: NaH; MeOH / tetrahydrofuran / 2 h 8: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 8 steps 1: 100 percent / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 3: 81 percent / PdCl2dppf / diethyl ether / Heating 4: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 5: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 6: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 7: NaH; MeOH / tetrahydrofuran / 2 h 8: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 8 steps 1: 100 percent / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 3: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 4: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 5: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 6: PdCl2dppf / diethyl ether / Heating 7: NaH; MeOH / tetrahydrofuran / 2 h 8: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 8 steps 1: 100 percent / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 3: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 4: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 5: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 6: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 7: NaH; MeOH / tetrahydrofuran / 2 h 8: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 7 steps 1: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 2: 81 percent / PdCl2dppf / diethyl ether / Heating 3: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 4: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 5: PdCl2dppf / diethyl ether / Heating 6: NaH; MeOH / tetrahydrofuran / 2 h 7: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 7 steps 1: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 2: 81 percent / PdCl2dppf / diethyl ether / Heating 3: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 4: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 5: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 6: NaH; MeOH / tetrahydrofuran / 2 h 7: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 7 steps 1: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 2: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 3: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 4: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 5: PdCl2dppf / diethyl ether / Heating 6: NaH; MeOH / tetrahydrofuran / 2 h 7: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 7 steps 1: 70 percent / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 18100.7 Torr 2: 81 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 3: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 4: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 5: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 6: NaH; MeOH / tetrahydrofuran / 2 h 7: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
2,7-dibromo-3,6-dihydroxy naphthalene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 77 percent / 10percent aq. NaOH / acetone / 0 °C 2: 40 percent / phenyllithium / tetrahydrofuran; cyclohexane; diethyl ether / Ambient temperature 3: 80 percent / MeOH, Mg / 10percent Pd/C / Ambient temperature 4: 78 percent / trifluoroacetic acid (TFA) / CHCl3 / 1 h / Heating View Scheme |
1,4:7,10-diepoxy-1,4,7,10-tetrahydronaphthacene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 80 percent / MeOH, Mg / 10percent Pd/C / Ambient temperature 2: 78 percent / trifluoroacetic acid (TFA) / CHCl3 / 1 h / Heating View Scheme |
3,6-dibromo-2,7-bis<(p-tolylsulfonyl)oxy>naphthalene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 40 percent / phenyllithium / tetrahydrofuran; cyclohexane; diethyl ether / Ambient temperature 2: 80 percent / MeOH, Mg / 10percent Pd/C / Ambient temperature 3: 78 percent / trifluoroacetic acid (TFA) / CHCl3 / 1 h / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: PdCl2dppf / diethyl ether / Heating 2: NaH; MeOH / tetrahydrofuran / 2 h 3: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 3 steps 1: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 2: NaH; MeOH / tetrahydrofuran / 2 h 3: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 2: PdCl2dppf / diethyl ether / Heating 3: NaH; MeOH / tetrahydrofuran / 2 h 4: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 4 steps 1: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 2: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 3: NaH; MeOH / tetrahydrofuran / 2 h 4: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
2,3-bis[(trimethylsilyl)ethynyl]naphthalene
A
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 3: PdCl2dppf / diethyl ether / Heating 4: NaH; MeOH / tetrahydrofuran / 2 h 5: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme | |
Multi-step reaction with 5 steps 1: 0.36 g / NBS; AgNO3 / acetone / 10 h / 25 °C 2: 0.27 g / 1,4-cyclohexadiene; N2 / benzene / 2 h / 180 °C / 15514.9 Torr 3: 86 percent / PdCl2dppf; BuLi; ZnCl2 / tetrahydrofuran; diethyl ether / 12 h / Heating 4: NaH; MeOH / tetrahydrofuran / 2 h 5: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
2,3-bis(trimethylsilylethynyl)anthracene
A
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: NaH; MeOH / tetrahydrofuran / 2 h 2: 64 percent / 1,4-cyclohexadiene / benzene / 160 °C / 12411.9 Torr View Scheme |
5,12-dihydro-naphthacen-5-ol
Tetracen
Conditions | Yield |
---|---|
With ethanol; mineral acid |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: AlCl3; carbon disulfide 2: 415 °C View Scheme |
A
11H-benzo[a]carbazole
B
Benzo[k]fluoranthene
C
Tetracen
D
cyclopenta[c,d]pyrene
Conditions | Yield |
---|---|
With air at 900℃; Condensation; combustion; pyrolysis; PAH formation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts; | A 0.21 mg B 0.04 mg C 0.45 mg D 0.03 mg |
2,3-dibromonaphthalene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 52 percent / PhLi / tetrahydrofuran; cyclohexane / 1 h / 25 °C 2: 85 percent / m-CPBA / acetonitrile / 2 h / Heating View Scheme |
10-bromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 74 percent / Fe powder, Br2 / various solvent(s) / 2 h / Heating 2: 63 percent 3: 52 percent / PhLi / tetrahydrofuran; cyclohexane / 1 h / 25 °C 4: 85 percent / m-CPBA / acetonitrile / 2 h / Heating View Scheme |
10,11-dibromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-1,4;5,8-dimethanotriphenylene
Tetracen
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 63 percent 2: 52 percent / PhLi / tetrahydrofuran; cyclohexane / 1 h / 25 °C 3: 85 percent / m-CPBA / acetonitrile / 2 h / Heating View Scheme |
Conditions | Yield |
---|---|
Stage #1: 2,3-dibenzylfumaraldehyde With indium(III) triflate In 1,2-dichloro-ethane at 65℃; for 1.5h; Microwave irradiation; Stage #2: In 1,2-dichloro-ethane at 115℃; for 0.5h; Microwave irradiation; regiospecific reaction; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: NaI / dimethylformamide 2: 1.) diborane, 2.) oxidizing agent / 1.) diglyme View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: NaI / dimethylformamide 2: 1.) diborane, 2.) oxidizing agent / 1.) diglyme View Scheme |
Conditions | Yield |
---|---|
With potassium hydroxide at 150 - 160℃; |
Conditions | Yield |
---|---|
With hydrogen iodide; acetic acid for 120h; Heating; | 99% |
With tris(pentafluorophenyl)borate; hydrogen; (pentafluorophenyl)diphenylphosphine In 1,2-dichloro-ethane at 80℃; under 61506.2 Torr; for 10h; | 90% |
With Dicalcium Nitride Electride In tetrahydrofuran; isopropyl alcohol at 65℃; for 24h; Birch Reduction; Inert atmosphere; | 82% |
Conditions | Yield |
---|---|
In toluene under N2 or Ar; 2,3-benzanthracene was added to the samarocene in toluene, stirred for 5 min; solvent was removed by rotary evapn.; elem. anal.; | 98% |
vinylene carbonate
Tetracen
5,12-dihydro-5,12-ethanonaphthacene-cis-13,14-diyl carbonate
Conditions | Yield |
---|---|
In 5,5-dimethyl-1,3-cyclohexadiene at 180℃; for 72h; Diels-Alder Cycloaddition; Autoclave; | 95% |
for 8h; Heating; | 11% |
Tetracen
5,11-dibromonaphthacene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In chloroform; N,N-dimethyl-formamide at 60℃; for 5h; | 92% |
With N-Bromosuccinimide In chloroform; N,N-dimethyl-formamide at 60℃; for 5h; | 92% |
With N-Bromosuccinimide In chloroform at 60℃; | 48% |
Conditions | Yield |
---|---|
In benzene-d6 at 60℃; for 12h; Inert atmosphere; regioselective reaction; | 92% |
Tetracen
5-bromotetracene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In chloroform; N,N-dimethyl-formamide | 90% |
With N-Bromosuccinimide In chloroform at 60℃; for 3h; | 90% |
With N-Bromosuccinimide In dichloromethane; N,N-dimethyl-formamide at 50℃; Inert atmosphere; Darkness; | 88% |
Conditions | Yield |
---|---|
With sulfur In N,N-dimethyl-formamide at 155℃; for 5h; Inert atmosphere; | 86% |
With sulfur; 1,2,3-trichlorobenzene | |
With disulfur dichloride; 1,2,3-trichlorobenzene | |
Multi-step reaction with 2 steps 1: chlorobenzene; S2cl2 2: trichlorobenzene; sulfur View Scheme |
Tetracen
ethenetetracarbonitrile
13,13,14,14-tetracyano-5,12-dihydro-5,12-ethano-naphthacene
Conditions | Yield |
---|---|
In toluene at 120℃; for 20h; Diels-Alder Cycloaddition; Inert atmosphere; Darkness; Sealed tube; | 84% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 16h; Inert atmosphere; | 84% |
With boron trifluoride diethyl etherate at 80℃; for 16h; | 84% |
trans-1,2-dichloroethylene
Tetracen
trans-7,8-dichloro-2,3-(2',3'-naphtho)-5,6-benzobicyclo<2.2.2>octa-2,5-diene
Conditions | Yield |
---|---|
at 153℃; for 40h; | 79% |
Conditions | Yield |
---|---|
With iodosylbenzene sulfate; cobalt(II) 5,10,15,20-tetraphenylporphyrin In dichloromethane at 25℃; for 2h; Inert atmosphere; | 77% |
With oxygen In benzene for 17h; Irradiation; | 36% |
With air; xylene UV-Licht oder Gluehlampenlicht; |
Tetracen
Conditions | Yield |
---|---|
In nitromethane at 80℃; for 1h; Inert atmosphere; | 76% |
Conditions | Yield |
---|---|
In toluene at 105℃; for 0.5h; | 71% |
Tetracen
1,2,3,4,7,8,9,10-octahydrotetracene
Conditions | Yield |
---|---|
With tetrahydrofuran; chromium chloride; methylmagnesium bromide; hydrogen; 1,2-bis(2,6-diisopropylphenylimino)ethane at 0 - 20℃; under 37503.8 Torr; for 24h; Autoclave; regioselective reaction; | 69% |
Tetracen
5-[2,4,6-tris-(bis-trimethylsilanyl-methyl)-phenyl]-dibenzo[b,e]siline
Conditions | Yield |
---|---|
In benzene-d6 at 80℃; for 24h; Inert atmosphere; | 68% |
Tetracen
dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate
dimethyl 21-phenylpentacyclo[10.6.3.0(2,11).0(4,9).0(13,18)]henicosa-2,4,6,8,10,13,15,17-octaene-19,19-dicarboxylate
Conditions | Yield |
---|---|
With tin(IV) chloride In dichloromethane at -40 - 20℃; for 23.5h; Inert atmosphere; | 65% |
N-methylmaleimide
Tetracen
N-Methyl-5,12-ethano-5,12-dihydronaphthacen-13,14-dicarboximid
Conditions | Yield |
---|---|
In toluene at 120℃; for 24h; Diels-Alder Cycloaddition; Inert atmosphere; Darkness; Sealed tube; | 62% |
Tetracen
[(bis(η5-pentamethylcyclopentadienyl)cobalt):μ:(η4:1,4 η4:7,10-tetracene)]
Conditions | Yield |
---|---|
In benzene under inert gas; soln. of Co-complex and tetracene in benzene stirred for 3 h; evapd., residue dissolved in Et2O, cooled to 0°C; elem. anal.; | 61% |
Conditions | Yield |
---|---|
In toluene at 120℃; for 8h; Diels-Alder Cycloaddition; Inert atmosphere; Darkness; Sealed tube; | 60% |
With xylene | |
In various solvent(s) at 91.5℃; Rate constant; | |
In various solvent(s) at 91.5℃; Mechanism; Rate constant; analogous reaction of other polycyclic aromatic hydrocarbons; structure/reactivity correlations, application of theoretical models; |
Conditions | Yield |
---|---|
In toluene at 150℃; for 42h; Diels-Alder Cycloaddition; Inert atmosphere; Darkness; Sealed tube; | 55% |
Tetracen
C36H24
Conditions | Yield |
---|---|
In benzene for 20h; Irradiation; | 54% |
In benzene for 20h; Product distribution; Irradiation; |
Conditions | Yield |
---|---|
With aluminum (III) chloride In 1,2-dichloro-benzene at 20℃; for 12h; Friedel Crafts acylation; Inert atmosphere; | 54% |
With aluminum (III) chloride In 1,2-dichloro-benzene at 0 - 25℃; for 18h; Inert atmosphere; | 52% |
Conditions | Yield |
---|---|
In acetonitrile for 36h; Diels-Alder Cycloaddition; Schlenk technique; Inert atmosphere; | 53% |
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