24642-86-2

Basic information

• Product Name: Benzoic acid, 4-methoxy-, 2,4-dinitrophenyl ester
• CAS NO: 24642-86-2
• Molecular Formula: C14H10N2O7
• Molecular Weight: 318.243
• Mol File: 24642-86-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-methoxy-, 2,4-dinitrophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-methoxy-, 2,4-dinitrophenyl ester(24642-86-2)
• EPA Substance Registry System: Benzoic acid, 4-methoxy-, 2,4-dinitrophenyl ester(24642-86-2)

Safety Data

• Hazardous Substances Data: 24642-86-2(Hazardous Substances Data)

Upstream product

• 51-28-5 2,4-Dinitrophenol 
• 100-09-4 4-methoxybenzoic acid 

Downstream Products

• 50649-66-6 4-(methoxycarbonyl)phenyl 4-methoxybenzoate 
• 3532-17-0 4-methoxybenzoyl azide 
• 20350-26-9 2,4-dinitrophenolate 
• 100-09-4 4-methoxybenzoic acid 
• 1351142-86-3 C₁₃H₁₃N₂O₂⁽¹⁺⁾ 
• 14271-83-1 4-methoxybenzoyl cyanide 
• 7403-41-0 N-ethyl-4-methoxy-benzamide 
• 57463-79-3 [2-(4-Methoxy-benzoylamino)-acetylamino]-acetic acid 
• 26819-14-7 N-(2,2,2-trifluoroethyl)-p-methoxybenzamide 
• 94747-49-6 (4?methoxyphenyl)(piperazin?1?yl)methanone 
• 7504-58-7 N-(4-methoxybenzoyl)morpholine 
• 57700-94-4 N-(p-methoxybenzoyl)piperidine 
• 99-96-7 4-hydroxy-benzoic acid 

Relevant articles and documents

Activation volumes for ester hydrolysis via elimination-addition

Esters that have an acidic proton α to the carbonyl group (or vinylogous situation) and a good leaving group may undergo hydrolysis by elimination to an intermediate ketene, which rapidly hydrates.Examples are found in p-hydroxybenzoate, malonate, and acetoacetate esters of nitrophenols.The evidence for this mechanism (E1 cb type) includes the independence of rate with pH in the region of dissociation of the acidic proton and, in particular, positive volumes of activation that contrast sharply with negative values typical of the more usual BAc2 mechanism of hydrolysis.