25070-80-8

Basic information

• Product Name: prop-2'-en-1'-yl cyclohexylcarbamate
• Synonyms: prop-2'-en-1'-yl cyclohexylcarbamate
• CAS NO: 25070-80-8
• Molecular Weight: 183.25
• Mol File: 25070-80-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: prop-2'-en-1'-yl cyclohexylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2'-en-1'-yl cyclohexylcarbamate(25070-80-8)
• EPA Substance Registry System: prop-2'-en-1'-yl cyclohexylcarbamate(25070-80-8)

Safety Data

• Hazardous Substances Data: 25070-80-8(Hazardous Substances Data)

Upstream product

• 108-91-8 cyclohexylamine 
• 2937-50-0 Allyl chloroformate 
• 107-18-6 allyl alcohol 
• 92954-34-2 O-allyl-N,N'-dicyclohexyl isourea 
• 110-82-7 cyclohexane 
• 172288-22-1 allyl N-(tosyloxy)carbamate 
• 108-94-1 cyclohexanone 
• 60718-45-8 1-cyclohexanecarbonyl-1H-imidazole 
• 98-89-5 Cyclohexanecarboxylic acid 
• 13810-02-1 N-hydroxycyclohexanecarboxamide 
• 3173-53-3 Cyclohexyl isocyanate 
• 18146-00-4 allyloxytrimethylsilane 
• 6257-10-9 N,N'-dicyclohexyl-O-methyl isourea 
• 538-75-0 dicyclohexyl-carbodiimide 

Downstream Products

• 3173-53-3 Cyclohexyl isocyanate 
• 57707-20-7 4-chloro-N-cyclohexylbenzamide 
• 53205-68-8 N-cyclohexyl-p-toluamide 
• 10264-23-0 N-cyclohexyl-3-phenylpropionamide 
• 1759-68-8 N-benzoylcyclohexylamine 
• 38313-19-8 N-cyclohexylpyrrolidine-1-carboxamide 
• 25855-24-7 N-benzyl-N'-cyclohexylurea 
• 2158-01-2 N-butyl-N'-cyclohexylurea 
• 104-51-8 1-butylbenzene 
• 7641-81-8 4,4'-di-(n-butyl)-1,1'-biphenyl 
• 842124-16-7 4-allyl-n-butylbenzene 
• 108-91-8 cyclohexylamine 

Relevant articles and documents

De novo synthesis of troc-protected amines: Intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates

The rhodium-catalyzed intermolecular C-H insertion of the nitrene derived from 2,2,2-trichloroethyl-N-tosyloxycarbamate proceeded in good to excellent yields to produce a variety of Troc-protected amines. With cyclic aliphatic alkanes, it is possible to use only 2 equiv of substrate, whereas the reaction with aromatic alkanes is run neat. Not only does the nitrene insertion proceed in benzylic, secondary, and tertiary C-H bonds but also primary C-H insertion products were obtained in good yields. Finally, the use of chiral rhodium catalysts to provide an enantioselective version of this process is discussed.

N-methylimidazole-catalyzed synthesis of carbamates from hydroxamic acids via the lossen rearrangement

An efficient, one-pot, N-methylimidazole (NMI) accelerated synthesis of aromatic and aliphatic carbamates via the Lossen rearrangement is reported. NMI is a catalyst for the conversion of isocyanate intermediates to the carbamates. Moreover, the utility of arylsulfonyl chloride in combination with NMI minimizes the formation of often-observed hydroxamate-isocyanate dimers during the sequence. Under the present conditions, lowering of temperatures is also possible, enabling a mild protocol.

Unmodified nano-powder magnetite catalyzes a four-component aza-Sakurai reaction

A new catalyst for an old material: magnetite is an excellent Lewis acid catalyst for the four-component aza-Sakurai reaction. The process could be repeated up to 15-times without losing effectiveness, with the catalyst recycling being as easy as the use of a simple magnet. The catalyst is selective and could discriminate between aldehyde and ketone functionalities, catalyzing first the reaction with the higher electrophilic aldehyde.