34599-75-2

Basic information

• Product Name: Benzene, 2-(1,3-butadienyl)-2-methyl-, (E)-
• CAS NO: 34599-75-2
• Molecular Formula: C11H12
• Molecular Weight: 144.216
• Mol File: 34599-75-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzene, 2-(1,3-butadienyl)-2-methyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-(1,3-butadienyl)-2-methyl-, (E)-(34599-75-2)
• EPA Substance Registry System: Benzene, 2-(1,3-butadienyl)-2-methyl-, (E)-(34599-75-2)

Safety Data

• Hazardous Substances Data: 34599-75-2(Hazardous Substances Data)

Upstream product

• 1097191-50-8 1-allyl-2-(2-methylbenzyliene)hydrazine 
• 529-20-4 2-methylphenyl aldehyde 
• 1250596-10-1 1-(o-tolyl)but-3-yn-1-ol 
• 6502-18-7 1-(but-3-yn-1-yl)-2-methylbenzene 
• 24165-62-6 1-(2-methylphenyl)but-3-en-1-ol 
• 41301-43-3 trimethyl-2-propen-1-ylphosphonium bromide 
• 1560-54-9 allyltriphenylphosphonium bromide 
• 20850-01-5 3-(2-methylphenyl)-2-propen-1-ol 
• 75950-75-3 3-(2-methylphenyl)acrylic acid methyl ester 
• 93614-78-9 3-(2-methylphenyl)prop-2-en-1-al 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 2373-76-4 2-methylcinnamic acid 
• 95-46-5 2-methylphenyl bromide 
• 819066-30-3 1-((E)-3,3-Diethoxy-propenyl)-2-methyl-benzene 

Downstream Products

• 1352922-03-2 1-[(1E,3E)-6,7-dimethylocta-1,3,6-trien-1-yl]-2-methylbenzene 
• 1352922-19-0 1-methyl-2-((E)-5,6-dimethyl-3-methylenehepta-1,5-dienyl)benzene 
• 3695-02-1 N-benzyl-N-methyl-p-toluenesulfonamide 

Relevant articles and documents

Selective 1,2-Aminoisothiocyanation of 1,3-Dienes Under Visible-Light Photoredox Catalysis

Selective three-component 1,2-diamination of 1,3-dienes with concurrent introduction of two orthogonally protected amino groups remains unknown despite its significant synthetic potential. We report herein that reaction of conjugated dienes with N-aminopy

Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and beyond

A photoinduced palladium-catalyzed 1,2-carbofunctionalization of conjugated dienes has been developed. This mild modular approach, which does not require employment of exogeneous photosensitizers and external oxidants, allows for efficient and highly regio- and stereoselective synthesis of a broad range of allylic amines from readily available 1,3-dienes, alkyl iodides, and amines. Employment of O- and C-nucleophiles toward oxyalkylation and dialkylation products was also demonstrated. A putative π-allyl palladium radical-polar crossover path is proposed as a key event in this three-component coupling process. The utility of this protocol is highlighted by its application for derivatization of several amine-containing drugs.

Boron-Catalyzed C?C Functionalization of Allyl Alcohols

Tris(pentafluorophenyl)borane-catalyzed C?C bond functionalization of arylallyl alcohols using donor-acceptor carbenes is presented. The allylic hydroxyl group is found to assist the product formation by neighboring group participation providing a clue towards mechanistic understanding. This method can also be employed to effect homologation of allyl alcohols to homoallyl alcohols. Overall, this metal-free transformation presents a novel disconnection strategy towards carbon-carbon bond scission and formation. (Figure presented.).