37471-41-3

Basic information

• Product Name: 2-Butanone, 3,3-dimethyl-1-(phenylthio)-
• CAS NO: 37471-41-3
• Molecular Formula: C12H16OS
• Molecular Weight: 208.324
• Mol File: 37471-41-3.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3,3-dimethyl-1-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3,3-dimethyl-1-(phenylthio)-(37471-41-3)
• EPA Substance Registry System: 2-Butanone, 3,3-dimethyl-1-(phenylthio)-(37471-41-3)

Safety Data

• Hazardous Substances Data: 37471-41-3(Hazardous Substances Data)

Upstream product

• 5469-26-1 1-Bromopinacolon 
• 930-69-8 sodium thiophenolate 
• 917-92-0 3,3-Dimethylbut-1-yne 
• 110228-59-6 N-methyl-4-nitro-N-(phenylthio)benzenamine 
• 75-97-8 3,3-dimethyl-butan-2-one 
• 108-98-5 thiophenol 
• 36452-23-0 N-(phenylthio)-ε-caprolactam 
• 16865-61-5 tert-butyl-2-chloro-acetylene 
• 630-18-2 tert-butyl isocyanide 
• 100-68-5 methyl-phenyl-thioether 
• 931-59-9 benzenesulfenyl chloride 
• 17510-46-2 3,3-dimethyl-2-(trimethylsilyl)oxy-1-butene 
• 13547-70-1 1-chloro-3,3-dimethyl-butan-2-one 
• 124251-77-0 (E)-N-methyl-N-(4-nitrophenyl)-N'-<1-(phenylthio)-3,3-dimethylbut-1-en-2-yl>acetamidine 

Downstream Products

• 79772-17-1 5,5-dimethyl-4-oxo-3-(phenylthio)hexanoic acid 
• 137351-39-4 1-Chloro-3,3-dimethyl-1-phenylsulfanyl-butan-2-one 
• 137524-60-8 1,1-Dichloro-3,3-dimethyl-1-phenylsulfanyl-butan-2-one 
• 558-37-2 tert-butylethylene 
• 108-98-5 thiophenol 
• 128867-24-3 3,3-dimethyl-1-(phenylsulfinyl)-2-butanone 
• 1194360-44-5 (Z)-methyl 2,4,4-trimethyl-3-phenylthiomethyl-2-pentenoate 
• 66164-74-7 2,4,4-Trimethyl-2-phenylthiopent-3-on 
• 121585-24-8 2,2-dimethyl-4-(phenylthio)pentan-3-one 
• 49565-21-1 methylphenylsulfonium α-pivaloylmethylide 
• 1114817-92-3 t-butyl (methylthio)(phenylthio)methyl ketone 
• 27767-55-1 3r-Chlor-4c-phenylsulfon-2,2-dimethyl-buten-⁽³⁾ 
• 137351-35-0 3,3-dimethyl β-keto α-thiophenyl butyl p-toluene sulfone 
• 137524-55-1 2,2-dimethyl β-keto S-phenyl thiobutanoate 

Relevant articles and documents

The Interrupted Pummerer Reaction in a Sulfoxide-Catalyzed Oxidative Coupling of 2-Naphthols

A benzothiophene S-oxide catalyst, generated in situ by sulfur oxidation with H2O2, mediates the oxidative coupling of 2-naphthols. Key to the catalytic process is the capture and inversion of reactivity of a 2-naphthol partner, using an interrupted Pummerer reaction of an unusual benzothiophene S-oxide, followed by subsequent coupling with a second partner. The new catalytic manifold has been showcased in the synthesis of the bioactive natural products, (±)-nigerone and (±)-isonigerone. Although Pummerer reactions are used widely, their application in catalysis is rare, and our approach represents a new catalytic manifold for metal-free C?C bond formation.

Gold-catalyzed carbene transfer to alkynes: Access to 2,4-disubstituted furans

Furans of gold: The first example of a gold-catalyzed intermolecular addition of carbon ylides to terminal alkynes is reported (see scheme; DCE=dichloroethane, Tf=trifluoromethanesulfonyl). Subsequent intramolecular trapping of the generated gold carbene completes a formal [3+2] cycloaddition, which represents a novel synthesis of 2,4-disubstituted furans. Copyright

A new route for generation of α-λ3-iodanyl ketones via ester exchange of (Z)-(β-acetoxyvinyl)-λ3-iodanes: Their nucleophilic substitutions with halides and sulfur and phosphorus nucleophiles

An efficient method for generation of α-λ3-iodanyl ketones from (Z)-(2-acetoxyvinyl)(phenyl)-λ3-iodanes was developed. The method involves ester exchange of (Z)-2-acetoxyvinyl-λ3-iodanes with methanol in the presence of triethylamine. α-λ3Iodanyl ketones react with a variety of nucleophiles such as halides, thiols, phosphines, phosphinic acids, and phosphates, under the conditions which produce α-functionalized carbonyl compounds probably via an SN2 pathway.