5395-79-9

Basic information

• Product Name: 4-CHLORO-4'-METHYLBENZOPHENONE
• Synonyms: 4-CHLORO-4'-METHYLBENZOPHENONE;METHANONE,(4-CHLOROPHENYL);Methanone, (4-chlorophenyl)(4-Methylphenyl)-;(4-chlorophenyl)(p-tolyl)Methanone;4-Chlorophenyl 4-methylphenyl ketone;NSC 29
• CAS NO: 5395-79-9
• Molecular Formula: C₁₄H₁₁ClO
• Molecular Weight: 230.69
• Mol File: 5395-79-9.mol
• Article Data: 73

Chemical Properties

• Melting Point: 128.5-129 °C
• Boiling Point: 364.5 °C at 760 mmHg
• Flash Point: 197.3 °C
• Appearance: /
• Density: 1.178 g/cm³
• Vapor Pressure: 1.68E-05mmHg at 25°C
• Refractive Index: 1.586
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 4-CHLORO-4'-METHYLBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-CHLORO-4'-METHYLBENZOPHENONE(5395-79-9)
• EPA Substance Registry System: 4-CHLORO-4'-METHYLBENZOPHENONE(5395-79-9)

Safety Data

• Hazardous Substances Data: 5395-79-9(Hazardous Substances Data)

Usage

Uses

4-Chloro-4''-methylbenzophenone is a useful synthetic compound.

InChI:InChI=1/C14H11ClO/c1-10-2-4-11(5-3-10)14(16)12-6-8-13(15)9-7-12/h2-9H,1H3

Upstream product

• 99-94-5 p-Toluic acid 
• 108-90-7 chlorobenzene 
• 108-88-3 toluene 
• 74-11-3 para-chlorobenzoic acid 
• 874-60-2 4-methyl-benzoyl chloride 
• 122-01-0 4-chloro-benzoyl chloride 
• 77775-85-0 4-Chlorbenzoesaeure-difluorophosphorsaeure-anhydrid 
• 86814-00-8 cis-(p-ClC₆H₄/CO₂Me)-3-methoxycarbonyl-4-p-tolyl-4-(p-chloro-phenyl)-2-methylbut-3-enoic acid 
• 10557-71-8 4-chlorophenyltrimethylsilane 
• 201230-82-2 carbon monoxide 
• 7446-70-0 aluminium trichloride 
• 721427-06-1 (4-chloro-phenyl)-p-tolyl-acetaldehyde 
• 13389-74-7 4-chloro-4'methylbenzhydrol 
• 1679-18-1 4-Chlorophenylboronic acid 

Downstream Products

• 112325-97-0 2-(4-bromo-phenyl)-1-(4-chloro-phenyl)-1-p-tolyl-ethene 
• 13389-74-7 4-chloro-4'methylbenzhydrol 
• 6269-37-0 4-(4-chlorobenzoyl)benzoic acid 
• 6180-80-9 4-Amino-4'-methylbenzophenone 
• 76981-61-8 4'-chloro-4-methyl-3-nitro-benzophenone 
• 91457-11-3 4-bromomethyl-4'-chlorobenzophenone 
• 86813-97-0 α-cyano-β-(p-ClC6H4)-β-(p-tolyl)acrylonitrile 
• 86814-00-8 cis-(p-ClC₆H₄/CO₂Me)-3-methoxycarbonyl-4-p-tolyl-4-(p-chloro-phenyl)-2-methylbut-3-enoic acid 
• 30203-87-3 1-chloro-4-(4-methylbenzyl)benzene 
• 22494-67-3 4-chloro-4'-(chloromethyl)benzophenone 
• 742085-16-1 (4-chlorophenyl)[4-(pyrrolidin-1-ylmethyl)phenyl]methanone 
• 927690-05-9 (+/-)-(4-chlorophenyl)[4-(pyrrolidin-1-ylmethyl)phenyl]phenylmethanol 
• 927690-16-2 (+/-)-2-(4-chlorophenyl)-2-phenyl-2-{4-[(pyrrolidin-1-yl)methyl]phenyl}acetaldehyde 
• 927690-12-8 (+/-)-2-(4-chlorophenyl)-2-[4-(pyrrolidin-1-ylmethyl)phenyl]-2-phenylethanol 

Relevant articles and documents

Supported Palladium-Catalyzed Carbonylative Synthesis of Diaryl Ketones from Aryl Bromides and Arylboronic Acids

A palladium supported on graphitic carbon nitride (Pd/g-C3N4) catalyzed carbonylative reaction of aryl bromides and arylboronic acids by has been developed for the construction of diaryl ketones. Using benzene-1,3,5-triyl triformate (TFBen) as the CO source, the reaction proceeded well to give various diaryl ketones in moderate to good yields.

Photo-induced oxidative cleavage of C-C double bonds of olefins in water

The carbonyl compounds, synthesized by the oxidative cleavage of their corresponding olefins, are of great significance in organic synthesis, especially aryl ketones. We have developed a gentle and effective protocol, using acid red 94 as the organic metal-free photocatalyst, O2 as the oxidant, and water as the solvent. Under visible light irradiation, aryl ketone derivatives were obtained in moderate to excellent yields, showing good economic and environmental advantages.

Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water

Here a palladium-catalyzed oxidation method for converting alkylarenes into the aromatic ketones or benzaldehydes with water as the only oxygen donor is reported. This C-H bond oxidation functionalization does not require other oxidants and hydrogen accep