724-59-4

Basic information

• Product Name: 2-(4-fluorophenyl)-1-methylbenzimidazole
• Synonyms: 2-(4-fluorophenyl)-1-methylbenzimidazole;1-Methyl-2-(4-fluorophenyl)-1H-benzimidazole;2-(p-Fluorophenyl)-1-methyl-1H-benzimidazole
• CAS NO: 724-59-4
• Molecular Formula: C₁₄H₁₁FN₂
• Molecular Weight: 226.25
• Mol File: 724-59-4.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(4-fluorophenyl)-1-methylbenzimidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-fluorophenyl)-1-methylbenzimidazole(724-59-4)
• EPA Substance Registry System: 2-(4-fluorophenyl)-1-methylbenzimidazole(724-59-4)

Safety Data

• Hazardous Substances Data: 724-59-4(Hazardous Substances Data)

Usage

Uses

2-(4-Fluorophenyl)-1-methyl-1H-benzo[d]imidazole has been used as an electrolyte additive used to enhance the performance of dye-sensitized TiO2 solar cells.

Upstream product

• 140-75-0 para-fluorobenzylamine 
• 4760-34-3 N-methyl-1,2-phenylenediamine 
• 459-57-4 4-fluorobenzaldehyde 
• 1519051-16-1 4-fluoro-N'-(2-fluorophenyl)-N-methylbenzimidamide 
• 348-54-9 2-Fluoroaniline 
• 701-49-5 4-fluoro-N-methylbenzamide 
• 459-56-3 4-fluorobenzylic alcohol 
• 612-28-2 2-nitro-N-methylaniline 
• 1632-83-3 1-Methylbenzimidazole 
• 352-33-0 1-Chloro-4-fluorobenzene 
• 352-13-6 4-flourophenylmagnesium bromide 
• 25148-68-9 N-methylbenzene-1,2-diamine dihydrochloride 
• 352-34-1 4-fluoro-1-iodobenzene 

Downstream Products

• 2622-63-1 1-methyl-2-phenylbenzimidazole 

Relevant articles and documents

Photoinduced Heterogeneous C?H Arylation by a Reusable Hybrid Copper Catalyst

Heterogeneous copper catalysis enabled photoinduced C?H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step-economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid copper catalyst, among others, supported its outstanding stability and reusability.

Unified Protocol for Cobalt-Catalyzed Oxidative Assembly of Two Aryl Metal Reagents Using Oxygen as an Oxidant

The first cobalt-catalyzed oxidative cross-coupling reaction of two aryl metal reagents is described. An equivalent amount of two aryl Grignard or lithium reagents, after mediation by an equivalent amount of simple ClTi(OEt)3, was facilely assembled under the catalysis of 1 mol % of CoCl2/10 mol % of DMPU using oxygen. The cross-couplings between various aryl metal reagents, especially between two structurally similar aryl Grignard reagents, proceeded smoothly and selectively and, thus, provided a highly general and efficient method for the construction of biaryl compounds.

N -heterocyclic carbene-palladium(II)-1-methylimidazole complex-catalyzed direct C-H bond arylation of (Benz)imidazoles with aryl chlorides

(Benz)imidazoles can be efficiently functionalized by (hetero)aryl chlorides via direct C-H bond arylation in the presence of a well-defined NHC-Pd(II)-Im complex. Under the optimal conditions, various activated, unactivated, and deactivated (hetero)aryl chlorides were successfully applied as the arylating reagents to achieve the 2-(hetero)aryl (benz)imidazoles in acceptable to high yields, giving a facile and alternative methodology for the direct C-H bond arylation of (benz)imidazoles.