79235-76-0

Basic information

• Product Name: (5,10,15,20-tetramesitylporphyrinato)ruthenium(II)
• Synonyms: (5,10,15,20-tetramesitylporphyrinato)ruthenium(II)
• CAS NO: 79235-76-0
• Molecular Weight: 882.126
• Mol File: 79235-76-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(79235-76-0)
• EPA Substance Registry System: (5,10,15,20-tetramesitylporphyrinato)ruthenium(II)(79235-76-0)

Safety Data

• Hazardous Substances Data: 79235-76-0(Hazardous Substances Data)

Upstream product

• 106210-09-7 Ru(TMP)(N₂)2 
• 97877-74-2 bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 

Downstream Products

• 115227-07-1 Ru(TMP)(Et₃N)(N₂) 
• 106210-11-1 Ru(TMP)(Et₂O)(N₂) 
• 106210-08-6 Ru(TMP)(Et₂O)2 
• 115227-06-0 Ru(TMP)(DMF)(N₂) 
• 131207-11-9 Ru(((CH₃)3C₆H₂)4C₂₀H₈N₄)(C₂H₄) 
• 97877-74-2 bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-43-7 (carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-44-8 dioxo(tetramesitylporphyrinato)ruthenium(VI) 
• 106210-09-7 Ru(TMP)(N₂)2 

Relevant articles and documents

Synthesis and Reactivity of a Monomeric 14-Electron 'Bare' Ruthenium(II) Porphyrin Complex; Reversible Binding of Dinitrogen to form Mono- and Bis-dinitrogen Complexes

The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex .

Alkyne and alkene complexes of (tetramesitylporphyrinato)ruthenium (II)

The reactions of benzene or toluene solutions of RuII(TMP), where TMP is the dianion of 5,10,15,20-tetramesitylporphyrin, with some acetylenes and alkenes are reported.Acetylene yields the isolable 2(μ-C2H2) species; while with phenylacetylene or diphenylacetylene, 1:1 ?-complexes are formed.The ?-complexes Ru(TMP)(C2H4) and Ru(TMP)(C2H4)(iPrOH)*iPrOH are isolated from reactions with ethylene, and a similar cyclohexene species is characterized in situ.The findings are relevant to O2-epoxidation of alkenes catalyzed by the trans-Ru(TMP)(O)2 complex.