92669-43-7

Basic information

• Product Name: Carbonyl[5,10,15,20-tetrakis(2,4,6-triMethylphenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%
• Synonyms: Carbonyl[5,10,15,20-tetrakis(2,4,6-triMethylphenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%
• CAS NO: 92669-43-7
• Molecular Weight: 910.136
• Mol File: 92669-43-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbonyl[5,10,15,20-tetrakis(2,4,6-triMethylphenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonyl[5,10,15,20-tetrakis(2,4,6-triMethylphenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%(92669-43-7)
• EPA Substance Registry System: Carbonyl[5,10,15,20-tetrakis(2,4,6-triMethylphenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%(92669-43-7)

Safety Data

• Hazardous Substances Data: 92669-43-7(Hazardous Substances Data)

Upstream product

• 15243-33-1 dodecacarbonyl-triangulo-triruthenium 
• 56396-12-4 5,10,15,20-tetramesitylporphyrin 
• 92669-44-8 dioxo(tetramesitylporphyrinato)ruthenium(VI) 
• 79235-76-0 (5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 201230-82-2 carbon monoxide 

Downstream Products

• 92669-44-8 dioxo(tetramesitylporphyrinato)ruthenium(VI) 
• 97877-74-2 bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 

Relevant articles and documents

Sandwich structure of a ruthenium porphyrin and an amino acid hydrazide for probing molecular chirality by circular dichroism

Owing to the strong Lewis acidity of ruthenium porphyrins, a commercial carbonyl ruthenium porphyrin and an amino acid hydrazide can assemble into a sandwich structure. The nature of such a structure is diagnostic of the absolute configuration of the amino acid by circular dichroism.

Synthesis and properties of metalloporphyrin monolayers and stacked multilayers bound to an electrode via site specific axial ligation to a self- assembled monolayers

A general method has been developed for the immobilization of metalloporphyrins at a gold electrode surface coated with a self-assembled monolayers (SAM). SAMs containing imidazole-terminated adsorbates are shown to bind a series of metalloporphyrins, including bis-acetonitrile octaethylporphyrinatoruthenium (II), Ru(OEP)(CH3CN)2; bis-acetonitrile octaethyltetraazaporphyrinato ruthenium(II), Ru(OETAP)(CH3CN)2, bis- acetonitrile tetra-(p-chlorophenyl)porphyrinatoruthrnium(II), Ru(Tp- CIPP)(CH3CN)2, bis-acetonitrile octaethylporphtrinatoosmium(II), Os(OEP)(CH3CN)2, and carbonyl meso-tetramesitylporphyrinatoruthenium(II), Ru(TMP)(CO). The SAM/metalloporphyrin films have been characterized by optical ellipsometry, contact angle goniometry, X-ray photoelectron spectroscopy, grazing angle FT-IR spectroscopy, transmission visible spectroscopy, and electrochemistry. The results indicated that the metalloporphyrins are chemisorbed via axial ligand substitution of the metal center with the porphyrin ring parallel to the surface and the second axial ligand position normal to the surface. Scanning tunneling microscopy images of Ru(TMP)(CO) bound to the SAM corroborate this model. Axial ligation of metalloporpyrins to SAMs serves as the basis for an iterative, defined approach to the preparation of stacked single component and mixed metalloporphyrin multilayers on SAms. In these materials, the bidentate ligand pyrazine serves as a bridge between successive metalloporphyrins in the stacks.