92669-44-8

Basic information

• Product Name: dioxo(tetramesitylporphyrinato)ruthenium(VI)
• Synonyms: dioxo(tetramesitylporphyrinato)ruthenium(VI)
• CAS NO: 92669-44-8
• Molecular Weight: 914.124
• Mol File: 92669-44-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: dioxo(tetramesitylporphyrinato)ruthenium(VI)(CAS DataBase Reference)
• NIST Chemistry Reference: dioxo(tetramesitylporphyrinato)ruthenium(VI)(92669-44-8)
• EPA Substance Registry System: dioxo(tetramesitylporphyrinato)ruthenium(VI)(92669-44-8)

Safety Data

• Hazardous Substances Data: 92669-44-8(Hazardous Substances Data)

Upstream product

• 92669-46-0 Ru(C₂₀H₈N₄(C₆H₂(CH₃)3)4)O₂⁽¹⁺⁾*ClO₄^(1-)=(Ru(C₂₀H₈N₄(C₆H₂(CH₃)3)4)O₂)ClO₄ 
• 97877-73-1 (C₆H₂(CH₃)3)4(C₂₀H₁₀N₄)Ru(C₄H₈O)2 
• 10024-97-2 dinitrogen monoxide 
• 97877-74-2 bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-43-7 (5,10,15,20-tetrakis(2,4,6-trimethylphenyl)porphyrinato)(carbonyl)ruthenium(II) 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 
• 97877-73-1 bis(tetrahydrofuran)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-43-7 (carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 130461-48-2 tetramesitylporphinato ruthenium(II)(CO)(methanol) 
• 152600-35-6 dihydroxoruthenium(VI) tetramesitylporphyrin complex 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 145698-90-4 dichloro(5,10,15,20-tetramesitylporphyrinato)ruthenium(IV) 
• 7783-89-3 silver bromate 
• 79235-76-0 (5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 

Downstream Products

• 97877-74-2 bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 97877-73-1 bis(tetrahydrofuran)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92694-64-9 (5,10,15,20-tetramesitylporphyrinato)bis(trimethyl phosphite)ruthenium(II) 
• 92669-45-9 Ru(N₄C₂₀H₈(C₆H₂(CH₃)3)4)(O)2⁽¹⁺⁾ 
• 92669-43-7 (carbonyl)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) 
• 92669-46-0 Ru(C₂₀H₈N₄(C₆H₂(CH₃)3)4)O₂⁽¹⁺⁾*ClO₄^(1-)=(Ru(C₂₀H₈N₄(C₆H₂(CH₃)3)4)O₂)ClO₄ 
• 110613-27-9 oxoruthenium(IV) tetramesitylporphyrin 
• 110613-28-0 Ru(5,10,15,20-tetramesitylporphyrin)(PPh₃) 

Relevant articles and documents

Stereospecific Epoxidation by Air of Cholest-5-ene Derivatives catalysed by a Ruthenium Porphyrin

A ruthenium porphyrin catalyses the epoxidation of several cholest-5-ene derivatives by air in high yield and with nearly complete β-stereospecificity; C-3-unprotected cholesterol is unaffected, but cholesteryl acetate gives nearly pure (>99percent) 5β,6β-epoxide.

Generation of trans-dioxoruthenium(VI) porphyrins: A photochemical approach

trans-Dioxoruthenium(VI) porphyrin complexes have been developed as one of the best-characterized model systems for heme-containing enzymes. Traditionally, this type of compounds can be prepared by oxidation of ruthenium(II) precursors with peroxyacids an

Ruthenium porphyrin-catalyzed aerobic oxidation of terminal aryl alkenes to aldehydes by a tandem epoxidation-isomerization pathway

(Figure Presented) Catalytic oxidation of 1-alkenes to aldehydes by an epoxidation-isomerization pathway with air or dioxygen as terminal oxidant has been realized for bulky ruthenium(VI) porphyrin catalysts. For the new, recyclable catalyst [RuVI(tmttp)O2], product yields of up to 99% and total turnover numbers of up to 1144 were obtained.