97877-74-2Relevant articles and documents
Molecular dinitrogen complexes of ruthenium(II) porphyrins
Camenzind, Mark J.,James, Brian R.,Dolphin, David,Sparapany, John W.,Ibers, James A.
, p. 3054 - 3057 (2008/10/08)
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Synthesis and Reactivity of a Monomeric 14-Electron 'Bare' Ruthenium(II) Porphyrin Complex; Reversible Binding of Dinitrogen to form Mono- and Bis-dinitrogen Complexes
Camenzind, Mark J.,James, Brian R.,Dolphin, David
, p. 1137 - 1139 (2007/10/02)
The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex .