929554-00-7

Basic information

• Product Name: 4-Pentenoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (1R)-1-methyl-5-hexen-1-yl ester, (3S)-
• CAS NO: 929554-00-7
• Molecular Formula: C28H38O3Si
• Molecular Weight: 450.693
• Mol File: 929554-00-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (1R)-1-methyl-5-hexen-1-yl ester, (3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (1R)-1-methyl-5-hexen-1-yl ester, (3S)-(929554-00-7)
• EPA Substance Registry System: 4-Pentenoic acid, 3-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (1R)-1-methyl-5-hexen-1-yl ester, (3S)-(929554-00-7)

Safety Data

• Hazardous Substances Data: 929554-00-7(Hazardous Substances Data)

Upstream product

• 172516-17-5 (S)-3-((tert-butyldiphenylsilyl)oxy)pent-4-enal 
• 117661-29-7 (3S)-3-hydroxy-5-benzyloxy-1-pentene 
• 121671-81-6 (5R)-5-[1-(tert-butyl)-1,1-diphenylsilyl]oxyhexan-1-ol 
• 111466-55-8 ((2S,3S)-3-(2-(benzyloxy)ethyl)oxiran-2-yl)methanol 
• 929554-07-4 (R)-6-benzyloxy-hex-4-yn-2-yloxy-tert-butyldiphenylsilane 
• 929554-13-2 (3S)-3-tert-butyldiphenylsilyloxy-5-benzyloxy-1-pentene 
• 929554-08-5 (R)-tert-butyl(hept-6-en-2-yloxy)diphenylsilane 
• 929554-15-4 (3S)-3-tert-butyldiphenylsilyloxy-5-hydroxy-1-pentene 
• 174455-52-8 (R)-6-(benzyloxy)hex-4-yn-2-ol 
• 929554-11-0 (2S,3R)-2-[2-(benzyloxy)ethyl]-3-(chloromethyl)oxirane 
• 855256-87-0 (5R)-5-[1-(tert-butyl)-1,1-diphenylsilyl]oxyhexanal 
• 929554-04-1 (3S)-3-(tert-butyldiphenylsilyloxy)pent-4-enoic acid 
• 24395-10-6 (R)-hept-6-en-2-ol 

Downstream Products

• 56020-70-3 diplodialide C 
• 56020-71-4 diplodialide B 

Relevant articles and documents

Stereoselective synthesis of (+)-diplodialides-B, C and a formal synthesis of (+)-diplodialide-A by ring-closing metathesis approach

Stereoselective synthesis of diplodialides-B and C and the formal synthesis of diplodialide-A are reported. A combination of Jacobsen's hydrolytic kinetic resolution and Sharpless epoxidation is used for the creation of two stereogenic centers, while a ring-closing metathesis strategy was used for the construction of the lactone ring.