10-epi-γ-eudesmol

The 10-epi-g-Eudesmol is an organic compound with the formula C₁₅H₂₆O. The IUPAC name of this chemical is 2-[(2R,4aS)-4a,8-dimethyl-2,3,4,5,6,7-hexahydro-1H-naphthalen-2-yl]propan-2-ol. With the CAS registry number 15051-81-7, it is also named as 2-naphthalenemethanol, 1,2,3,4,4a,5,6,7-octahydro-α,α,4a,8-tetramethyl-, (2R,4aS)-.

Physical properties about 10-epi-g-Eudesmol are: (1)ACD/LogP: 4.86; (2)ACD/LogD (pH 5.5): 4.86; (3)ACD/LogD (pH 7.4): 4.86; (4)ACD/BCF (pH 5.5): 2890.92; (5)ACD/BCF (pH 7.4): 2890.92; (6)ACD/KOC (pH 5.5): 10447.33; (7)ACD/KOC (pH 7.4): 10447.33; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 9.23 Å²; (12)Index of Refraction: 1.505; (13)Molar Refractivity: 68.39 cm³; (14)Molar Volume: 230.4 cm³; (15)Polarizability: 27.11×10^-24cm³; (16)Surface Tension: 34.7 dyne/cm; (17)Density: 0.96 g/cm³; (18)Flash Point: 108.5 °C; (19)Enthalpy of Vaporization: 62.82 kJ/mol; (20)Boiling Point: 301.5 °C at 760 mmHg; (21)Vapour Pressure: 0.000103 mmHg at 25°C.

Preparation: this chemical can be prepared by (11E)-11,12-epoxy-eudesm-4-en-3-one. This reaction will need reagent LiAlH₄, AlCl₂H and solvent diethyl ether, diethyl ether. The reaction time is 13 hours with reaction temperature of 20 °C. The yield is about 82%.

Uses of 10-epi-g-Eudesmol: it can be used to produce 11-hydroxy-4,5-secoeudesmane-4,5-dione at temperature of -78 - 20 °C. It will need reagent ozone, Me₂S and solvent CH₂Cl₂. The yield is about 62%.

You can still convert the following datas into molecular structure:
(1)SMILES: OC([C@H]2C\C1=C(/C)CCC[C@]1(CC2)C)(C)C
(2)InChI: InChI=1/C15H26O/c1-11-6-5-8-15(4)9-7-12(10-13(11)15)14(2,3)16/h12,16H,5-10H2,1-4H3/t12-,15+/m1/s1
(3)InChIKey: WMOPMQRJLLIEJV-DOMZBBRYBS
(4)Std. InChI: InChI=1S/C15H26O/c1-11-6-5-8-15(4)9-7-12(10-13(11)15)14(2,3)16/h12,16H,5-10H2,1-4H3/t12-,15+/m1/s1
(5)Std. InChIKey: WMOPMQRJLLIEJV-DOMZBBRYSA-N