2,2',4,4',6,6'-Hexanitrodifenylamin supplier

Name
DIPICRYLAMINE
EINECS 205-037-8
CAS No. 131-73-7
Article Data29
CAS DataBase
Density 1.938g/cm³
Solubility 2.4 mg l-1 (e)
Melting Point about 238° with dec
Formula C₁₂H₅N₇O₁₂
Boiling Point 532.5°Cat760mmHg
Molecular Weight 439.211
Flash Point 275.9°C
Transport Information
Appearance light yellow to beige or light brown crystalline
Safety 35-36-45-61
Risk Codes 2-26/27/28-33-51/53
Molecular Structure
Hazard Symbols ET+N
Synonyms Diphenylamine,2,2',4,4',6,6'-hexanitro- (8CI);2,2',4,4',6,6'-Hexanitrodiphenylamine;2,4,6,2',4',6'-Hexanitrodiphenylamine;2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)benzenamine;Bis(2,4,6-trinitrophenyl)amine;Dipicrylamine;Hexamine;Hexamine (potassiumreagent);Hexanitrodiphenylamine;Hexyl;Hexyl (reagent);N,N-Bis(2,4,6-Trinitrophenyl)amine;NSC 1786;
PSA 286.95000
LogP 6.09160

Synthetic route

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
technische Gewinnung;
With nitric acid
Nitrierung;

: 489-98-5
picramide

A: 3698-53-1
1,2,3,5-tetranitrobenzene

B: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With nitric acid at -5 - 7℃; Einleiten von nitrosen Gasen;

: 603-54-3
N,N-diphenylurea

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With sulfuric acid; nitric acid

: 21565-22-0
(2,4-dinitro-phenyl)-picryl-amine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With nitric acid at 70℃;

: 552-82-9
benzhydrylidene(methyl)amine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With nitric acid

: 2919-12-2
trinitro-2,4,6 diphenylamine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With nitric acid mit rauchender Salpetersaeure;
With nitric acid at 25℃; mit absol. Salpetersaeure;
With sulfuric acid; nitric acid at 70℃;
Multi-step reaction with 2 steps 1: nitric acid / 25 °C / mit Salpetersaeure (D:1.49) 2: nitric acid / 70 °C View Scheme

: 2908-76-1
bis(2,4-dinitrophenyl)amine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With nitric acid at 70 - 90℃; mit 93prozentiger Salpetersaeure;
With sulfuric acid; nitric acid at 20 - 32℃;
Nitrierung;

: 38417-97-9
N-(p-nitrophenyl)picrylamine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With sulfuric acid; nitric acid

: 871882-90-5
bis-(2,4-dinitro-phenyl)-carbamic acid ethyl ester

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With sulfuric acid; nitric acid

: 2919-12-2
trinitro-2,4,6 diphenylamine

: 64-19-7
acetic acid

: 110-46-3
isopentyl nitrite

A: 21565-22-0
(2,4-dinitro-phenyl)-picryl-amine

B: 131-73-7
Dipikrylamin

...Expand

: 122-39-4
diphenylamine

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
Nitrierung;
With nitric acid
With sulfuric acid; nitric acid

: 16969-45-2
pyridin-1-ium

: 32817-38-2
Dipicrylamin-Anion

A: 110-86-1
pyridine

B: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
for 11h; Rate constant;

...Expand

: 88-88-0
2,4,6-trinitrochlorobenzene

: 489-98-5
picramide

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
With sodium hydride; iodophenylbis(triphenylphosphine)palladium acetonitrile, 6 h; Yield given. Multistep reaction;

: 7664-93-9
sulfuric acid

: 603-54-3
N,N-diphenylurea

10 part nitric acid: 10 part nitric acid

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
in der Waerme;

...Expand

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 7697-37-2
nitric acid

: 131-73-7
Dipikrylamin

: 2919-12-2
trinitro-2,4,6 diphenylamine

: 7697-37-2
nitric acid

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
at 25℃; bei 24-stuendiger Einw.;
auf dem Wasserbad;

: 2908-76-1
bis(2,4-dinitrophenyl)amine

HNO3+H2SO4: HNO3+H2SO4

: 131-73-7
Dipikrylamin

: 2908-76-1
bis(2,4-dinitrophenyl)amine

nitric acid (93 percent ): nitric acid (93 percent )

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
at 40 - 90℃;

: 7664-93-9
sulfuric acid

: 2919-12-2
trinitro-2,4,6 diphenylamine

nitric acid (D:1.49): nitric acid (D:1.49)

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
at 70℃;

...Expand

: 489-98-5
picramide

: 7697-37-2
nitric acid

nitrogen oxide: nitrogen oxide

A: 3698-53-1
1,2,3,5-tetranitrobenzene

B: 131-73-7
Dipikrylamin

...Expand

: 7664-93-9
sulfuric acid

: 603-54-3
N,N-diphenylurea

10 part nitric acid: 10 part nitric acid

A: 131-73-7
Dipikrylamin

B N.N-bis-<2.4-dinitro-phenyl>-urea: N.N-bis-<2.4-dinitro-phenyl>-urea

Conditions

Conditions	Yield
in der Kaelte;

...Expand

: 606-35-9
1-methoxy-2,4,6-trinitrobenzene

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: aniline; alcohol 2: nitric acid / mit rauchender Salpetersaeure View Scheme

: 88-88-0
2,4,6-trinitrochlorobenzene

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: alcohol 2: HNO3+H2SO4 View Scheme

: 100-01-6
4-nitro-aniline

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: alcohol 2: HNO3+H2SO4 View Scheme
Multi-step reaction with 2 steps 1: sulfuric acid; potassium nitrate 2: aqueous HNO3 / -5 - 7 °C / Einleiten von nitrosen Gasen View Scheme

: 36062-19-8
1,3-diaminoguanidine hydrochloride

: 131-73-7
Dipikrylamin

: 1352994-43-4
CH7N5*C12H5N7O12

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: 1,3-diaminoguanidine hydrochloride In water at 20℃; for 1h;	97%

: 12125-02-9
ammonium chloride

: 131-73-7
Dipikrylamin

: 2844-92-0
dipicryl-amin; ammonium salt

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: ammonium chloride In water at 20℃; for 1h;	96%

: 2644-70-4
hydrazine hydrochloride

: 131-73-7
Dipikrylamin

: 1352994-40-1
C12H5N7O12*H4N2

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: hydrazine hydrochloride In water at 20℃; for 1h;	93%

: 131-73-7
Dipikrylamin

: 1-amino-3-methyl-1,2,3-triazol-3-ium iodide

: C3H7N4(1+)*C12H4N7O12(1-)

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: 1-amino-3-methyl-1,2,3-triazol-3-ium iodide In water at 20℃; for 1h;	89%

: 1052012-46-0, 1173151-14-8
1-methyl-3,4,5-triamino-1,2,4-triazolium iodide

: 131-73-7
Dipikrylamin

: C3H9N6(1+)*C12H4N7O12(1-)*H2O

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: 1-methyl-3,4,5-triamino-1,2,4-triazolium iodide In water at 20℃; for 1h;	88%

: 1467-16-9
Imidazole hydrochloride

: 131-73-7
Dipikrylamin

: 1352994-39-8
C3H4N2*C12H5N7O12

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: Imidazole hydrochloride In water at 20℃; for 1h;	87%

: 18299-54-2
ethylenediamine hydrochloride

: 131-73-7
Dipikrylamin

: C2H8N2*2C12H5N7O12

Conditions

Conditions	Yield
Stage #1: Dipikrylamin With sodium hydroxide In water at 80℃; for 0.5h; Stage #2: ethylenediamine hydrochloride In water at 20℃; for 1h;	86%

: 58476-20-3
4,7-dimethyl-3-chloromethyl-2H-1-benzopyran-2-one

: 131-73-7
Dipikrylamin

: 138719-90-1
3-{[Bis-(2,4,6-trinitro-phenyl)-amino]-methyl}-4,7-dimethyl-chromen-2-one

Conditions

Conditions	Yield
In benzene for 4h; Heating;	50%

: 467-63-0
crystal violet carbinol base

: 98-95-3
nitrobenzene

: 131-73-7
Dipikrylamin

: dipicryl-(4,4',4''-tris-dimethylamino-trityl)-amine

...Expand

: 467-62-9
pararosaniline

: 67-64-1
acetone

: 131-73-7
Dipikrylamin

: dipicryl-(4,4',4''-triamino-trityl)-amine

...Expand

: 467-63-0
crystal violet carbinol base

: 67-64-1
acetone

: 131-73-7
Dipikrylamin

: dipicryl-(4,4',4''-tris-dimethylamino-trityl)-amine

...Expand

: 467-62-9
pararosaniline

: 131-73-7
Dipikrylamin

: dipicryl-(4,4',4''-triamino-trityl)-amine

Conditions

Conditions	Yield
With acetone

: 467-63-0
crystal violet carbinol base

: 131-73-7
Dipikrylamin

: dipicryl-(4,4',4''-tris-dimethylamino-trityl)-amine

Conditions

Conditions	Yield
With acetone
With nitrobenzene

: 110-86-1
pyridine

: 131-73-7
Dipikrylamin

A: 16969-45-2
pyridin-1-ium

B: 32817-38-2
Dipicrylamin-Anion

Conditions

Conditions	Yield
for 11h; Rate constant;

...Expand

: 131-73-7
Dipikrylamin

: 13474-21-0
dipicryl-amine; sodium-salt

Conditions

Conditions	Yield
With sodium hydride In acetonitrile for 3h;

2,2',4,4',6,6'-Hexanitrodifenylamin Chemical Properties

Molecular Structure of 2,2',4,4',6,6'-Hexanitrodifenylamin (CAS No.131-73-7):

Molecular Formula: C₁₂H₅N₇O₁₂
Molecular Weight: 439.21
IUPAC Name: 2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)aniline
CAS No: 131-73-7
EINECS: 205-037-8
H bond acceptors: 19
H bond donors: 1
Freely Rotating Bonds: 8
Polar Surface Area: 286.95 Å²
Index of Refraction: 1.778
Molar Refractivity: 94.9 cm³
Molar Volume: 226.5 cm³
Surface Tension: 109.9 dyne/cm
Density: 1.938 g/cm³
Flash Point: 275.9 °C
Enthalpy of Vaporization: 80.83 kJ/mol
Boiling Point: 532.5 °C at 760 mmHg
Vapour Pressure: 2.02E-11 mmHg at 25°C
Classification Code: Mutation data;Tumor data
Canonical SMILES: C1=C(C=C(C(=C1[N+](=O)[O-])NC2=C(C=C(C=C2[N+](=O)[O-])[N+](=O)[O-])[N+]
(=O)[O-])[N+](=O)[O-])[N+](=O)[O-]
InChI: InChI=1S/C12H5N7O12/c20-14(21)5-1-7(16(24)25)11(8(2-5)17(26)27)13-12-9
(18(28)29)3-6(15(22)23)4-10(12)19(30)31/h1-4,13H
InChIKey: CBCIHIVRDWLAME-UHFFFAOYSA-N

2,2',4,4',6,6'-Hexanitrodifenylamin Uses

2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)aniline (CAS NO.131-73-7) is used for the manufacture of ammunition and an analysis of potassium.

2,2',4,4',6,6'-Hexanitrodifenylamin Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD	oral	> 500mg/kg (500mg/kg)		National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 11, 1953.

2,2',4,4',6,6'-Hexanitrodifenylamin Consensus Reports

Reported in EPA TSCA Inventory.

2,2',4,4',6,6'-Hexanitrodifenylamin Safety Profile

Safety Information of 2,2',4,4',6,6'-Hexanitrodifenylamin (CAS No.131-73-7):
Hazard Codes: Explosive E, Very T+, Dangerous N
Risk Statements: 2-26/27/28-33-51/53
R2:Risk of explosion by shock, friction, fire or other source of ignition.
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed.
R33:Danger of cumulative effects.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 35-36-45-61
S35:This material and its container must be disposed of in a safe way.
S36:Wear suitable protective clothing.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: 0079
HazardClass: 1.1D

2,2',4,4',6,6'-Hexanitrodifenylamin Standards and Recommendations

DOT Classification: EXPLOSIVE 1.1D; Label: EXPLOSIVE 1.1D

2,2',4,4',6,6'-Hexanitrodifenylamin Specification

2,2',4,4',6,6'-Hexanitrodifenylamin (CAS No.131-73-7), it also can be called 2,4,6-trinitro-N-(2,4,6-trinitrophenyl)aniline ; Benzenamine, 2,4,6-trinitro-N- (2,4,6-trinitrophenyl)- ; Bis(2,4,6-trinitro-phenyl)-amin .

Product Name

DIPICRYLAMINE

Synthetic route

2,2',4,4',6,6'-Hexanitrodifenylamin Chemical Properties

2,2',4,4',6,6'-Hexanitrodifenylamin Uses

2,2',4,4',6,6'-Hexanitrodifenylamin Toxicity Data With Reference

2,2',4,4',6,6'-Hexanitrodifenylamin Consensus Reports

2,2',4,4',6,6'-Hexanitrodifenylamin Safety Profile

2,2',4,4',6,6'-Hexanitrodifenylamin Standards and Recommendations

2,2',4,4',6,6'-Hexanitrodifenylamin Specification

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