2,3-Dichloropropionaldehyde supplier

Name
2，3-Dichloropropionaldehyde
EINECS
CAS No. 10140-89-3
Article Data18
CAS DataBase
Density 1.288g/cm³
Solubility
Melting Point
Formula C3H4 Cl2 O
Boiling Point 153.9°Cat760mmHg
Molecular Weight 126.97
Flash Point 54.7°C
Transport Information
Appearance
Safety Poison by ingestion and skin contact. Mildly toxic by inhalation. A severe skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl⁻. See also ALDEHYDES and CHLORIDES.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Propionaldehyde,2,3-dichloro- (6CI,7CI,8CI); 2,3-Dichloropropanal; 2,3-Dichloropropionaldehyde;a,b-Dichloropropionaldehyde
PSA 17.07000
LogP 1.03150

Synthetic route

: 107-02-8
acrolein

: 10140-89-3
2,3-dichloropropanal

Conditions

Conditions	Yield
With hydrogenchloride; chlorine In tetrachloromethane at 15 - 20℃;	80%
With chlorine at -10 - 0℃; for 1h;	71%
With tetrachloromethane; chlorine

: 66826-73-1
trans-1,3-dichloropropene epoxide

A: 10140-89-3
2,3-dichloropropanal

B: 76429-86-2
2,5-Dihydroxy-3,6-bis(chloromethyl)-1,4-dioxane

Conditions

Conditions	Yield
In tetrahydrofuran; water at 20℃; for 168h; pH 7.4; Title compound not separated from byproducts;	A 52% B 20%
In tetrahydrofuran; water at 20℃; for 168h; pH 7.4;	A 52% B 20%

: 66826-72-0
cis-1,3-dichloropropene epoxide

A: 10140-89-3
2,3-dichloropropanal

B: 76429-86-2
2,5-Dihydroxy-3,6-bis(chloromethyl)-1,4-dioxane

Conditions

Conditions	Yield
In tetrahydrofuran; water at 20℃; for 168h; pH 7.4; Title compound not separated from byproducts;	A 52% B 20%
In tetrahydrofuran; water at 20℃; for 168h; pH 7.4;	A 52% B 20%

: 4,5-dichloro-pent-2-enoic acid

A: 10140-89-3
2,3-dichloropropanal

B: 144-62-7
oxalic acid

Conditions

Conditions	Yield
bei Ozonabbau;

: 66826-73-1
trans-1,3-dichloropropene epoxide

A: 10140-89-3
2,3-dichloropropanal

B: 84709-24-0
2-Hydroxy-3-chloropropanal

C: 76429-86-2
2,5-Dihydroxy-3,6-bis(chloromethyl)-1,4-dioxane

Conditions

Conditions	Yield
With water In tetrahydrofuran at 20℃; for 168h; pH 7.4; Yields of byproduct given. Title compound not separated from byproducts;
With water In tetrahydrofuran at 20℃; for 168h; pH 7.4;

...Expand

: 66826-72-0
cis-1,3-dichloropropene epoxide

A: 10140-89-3
2,3-dichloropropanal

B: 84709-24-0
2-Hydroxy-3-chloropropanal

C: 76429-86-2
2,5-Dihydroxy-3,6-bis(chloromethyl)-1,4-dioxane

Conditions

Conditions	Yield
With water In tetrahydrofuran at 20℃; for 168h; pH 7.4; Yields of byproduct given. Title compound not separated from byproducts;
With water In tetrahydrofuran at 20℃; for 168h; pH 7.4;

...Expand

: cis-1,3-Dichloropropene epoxide

A: 683-51-2
2-chloro-2-propenal

B: 10140-89-3
2,3-dichloropropanal

Conditions

Conditions	Yield
With dimethylsulfoxide-d6 at 22℃; Kinetics; Rearrangement;

: trans-1,3-Dichloropropene epoxide

A: 683-51-2
2-chloro-2-propenal

B: 10140-89-3
2,3-dichloropropanal

Conditions

Conditions	Yield
With dimethylsulfoxide-d6 at 22℃; Kinetics; Rearrangement;

: 56-23-5
tetrachloromethane

: 7782-50-5
chlorine

: 107-02-8
acrolein

: 10140-89-3
2,3-dichloropropanal

...Expand

: 310447-99-5, 310448-01-2
3,4-dichlorobut-1-ene

: 10028-15-6
ozone

A: 50-00-0
formaldehyd

B: 10140-89-3
2,3-dichloropropanal

Conditions

Conditions	Yield
at 0℃; Erwaermen des enthaltenen Ozonids mit Wasser;

...Expand

: 310447-99-5, 310448-01-2
3,4-dichlorobut-1-ene

: 10140-89-3
2,3-dichloropropanal

Conditions

Conditions	Yield
Stage #1: 3,4-dichlorobut-1-ene With ozone In dichloromethane at -78℃; for 10h; Stage #2: With dimethylsulfide In dichloromethane at -78℃; for 2h;

: 107-39-1
2,4,4-trimethyl-1-pentene

: 10140-89-3
2,3-dichloropropanal

: 51903-25-4
1-chloro-2,3-epoxy-5-neopentyl-5-hexene

Conditions

Conditions	Yield
Stage #1: 2,4,4-trimethyl-1-pentene; 2,3-dichloropropanal With tin(IV) chloride In benzene at 20℃; for 3h; Stage #2: With potassium hydroxide In ethanol; benzene at 30 - 35℃; for 6h;	85%

: 10140-89-3
2,3-dichloropropanal

: 115-11-7
isobutene

A: 140700-33-0, 140700-35-2
1,2-dichloro-5-methyl-3-tert-butoxy-5-hexene

: 42322-65-6, 140700-32-9, 140700-34-1, 141270-03-3, 141270-05-5
threo-1,2-dichloro-5-methyl-5-hexen-3-ol

: 42322-65-6, 140700-32-9, 140700-34-1, 141270-03-3, 141270-05-5
erythro-1,2-dichloro-5-methyl-5-hexen-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride In benzene at -40℃;	A 20% B 20% C 80%

...Expand

: 10140-89-3
2,3-dichloropropanal

: 122-52-1
triethyl phosphite

: 111480-26-3
trans-3-chloropropenyl diethyl phosphate

Conditions

Conditions	Yield
	61%

: 67-56-1
methanol

: 10140-89-3
2,3-dichloropropanal

: 67832-48-8
2,3-dichloro-1,1-dimethoxy-propane

: 4301-15-9
ethynyldimagnesium dibromide

: 10140-89-3
2,3-dichloropropanal

: 856340-49-3
4,5-dichloro-pent-1-yn-3-ol

: 4301-15-9
ethynyldimagnesium dibromide

: 10140-89-3
2,3-dichloropropanal

: 856336-34-0
1,2,7,8-tetrachloro-oct-4-yne-3,6-diol

Conditions

Conditions	Yield
higher-melting form;
With diethyl ether man trennt die beiden Formen durch fraktionierte Krystallisation aus Benzol und Chloroform; 1.2.7.8-tetrachloro-octyne-(4)-diol-(3.6); higher-melting form;
With diethyl ether man trennt die beiden Formen durch fraktionierte Krystallisation aus Benzol und Chloroform; 1.2.7.8-tetrachloro-octyne-(4)-diol-(3.6); lower-melting form;

: 60-29-7
diethyl ether

: 10140-89-3
2,3-dichloropropanal

: 3761-92-0
n-hexylmagnesium bromide

A: 616-23-9
2,3-Dichloro-1-propanol

B: 1,2-dichloro-nonan-3-ol

Conditions

Conditions	Yield
analoge Reaktionen mit Cyclohexylmagnesiumbromid und mit β-Phenaethylmagnesiumbromid;

...Expand

: 60-29-7
diethyl ether

: 10140-89-3
2,3-dichloropropanal

: phenylmagnesium bromide

: 2,3-dichloro-1-phenyl-propan-1-ol

...Expand

: 116-17-6
triisopropyl phosphite

: 10140-89-3
2,3-dichloropropanal

: phosphoric acid-(3-chloro-propenyl ester)-diisopropyl ester

: 1606-96-8
triisobutyl phosphite

: 10140-89-3
2,3-dichloropropanal

: phosphoric acid-(3-chloro-propenyl ester)-diisobutyl ester

: 10140-89-3
2,3-dichloropropanal

: 10541-83-0
N-methyl-p-aminobenzoic acid

: 6-carboxy-3-chloro-1-methyl-quinolinium; chloride

Conditions

Conditions	Yield
With 1,4-dioxane

: 10140-89-3
2,3-dichloropropanal

: 3761-92-0
n-hexylmagnesium bromide

: 1,2-dichloro-nonan-3-ol

Conditions

Conditions	Yield
With diethyl ether

: 10140-89-3
2,3-dichloropropanal

: 75-16-1
methylmagnesium bromide

: 133341-68-1, 133357-43-4
3,4-dichloro-butan-2-ol

: 10140-89-3
2,3-dichloropropanal

: 683-51-2
2-chloro-2-propenal

Conditions

Conditions	Yield
With water
With water; sodium acetate
With triethylamine In dichloromethane at -78℃; for 0.25h;	Ca. 1.5 g

: 10140-89-3
2,3-dichloropropanal

: 7789-90-4
2,2,3-trichloro-propionaldehyde

Conditions

Conditions	Yield
With water; chlorine
With chlorine; N,N-dimethyl-formamide In chloroform for 1h; Reflux;

: 10140-89-3
2,3-dichloropropanal

: 78-92-2, 15892-23-6
iso-butanol

: 616-23-9
2,3-Dichloro-1-propanol

Conditions

Conditions	Yield
With aluminum tri-sec-butoxide

: 10140-89-3
2,3-dichloropropanal

: 95-85-2
2-hydroxy-5-chloro-aniline

: 130-16-5
5-Chloro-8-hydroxyquinoline

Conditions

Conditions	Yield
With phosphoric acid; water at 135℃;

: 10140-89-3
2,3-dichloropropanal

: 122-52-1
triethyl phosphite

: 89094-95-1
phosphoric acid diethyl ester-(3-chloro-propenyl ester)

: 592-76-7
1-Heptene

: 10140-89-3
2,3-dichloropropanal

: 42322-67-8
1,2-dichloro-dec-5-en-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride

: 592-41-6
1-hexene

: 10140-89-3
2,3-dichloropropanal

: 42322-66-7
1,2-dichloro-non-5-en-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride

: 111-66-0
oct-1-ene

: 10140-89-3
2,3-dichloropropanal

: 42322-68-9
1,2-dichloro-undec-5-en-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride

: 10140-89-3
2,3-dichloropropanal

: 20614-26-0
2,3,2',3'-tetrachloro-1,1'-peroxy-bis-propan-1-ol

Conditions

Conditions	Yield
With dihydrogen peroxide In diethyl ether

: 10140-89-3
2,3-dichloropropanal

: 115-11-7
isobutene

: 42322-65-6
1,2-dichloro-5-methyl-hex-5-en-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride

: 10140-89-3
2,3-dichloropropanal

: 78-79-5
isoprene

: 65476-00-8
1,2-dichloro-5-methylene-hept-6-en-3-ol

Conditions

Conditions	Yield
With tin(IV) chloride

2,3-Dichloropropionaldehyde Chemical Properties

Empirical Formula of 2,3-Dichloropropionaldehyde (CAS NO.10140-89-3): C₃H₄Cl₂O
Molecular Weight: 126.9693 g/mol
EINECS: 233-399-7
Index of Refraction: 1.436
Density: 1.288 g/cm³
Flash Point: 54.7 °C
Enthalpy of Vaporization: 39.07 kJ/mol
Boiling Point: 153.9 °C at 760 mmHg
Vapour Pressure: 3.26 mmHg at 25 °C
Structure of 2,3-Dichloropropionaldehyde (CAS NO.10140-89-3):

IUPAC Name of 2,3-Dichloropropionaldehyde (CAS NO.10140-89-3): 2,3-Dichloropropanal

2,3-Dichloropropionaldehyde Toxicity Data With Reference

1.	skn-rbt 10 mg/24H open SEV	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
2.	skn-rbt 500 mg MOD	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
3.	eye-rbt 50 µg open SEV	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
4.	mmo-sat 1 nmol/plate	MUREAV Mutation Research. 78 (1980),113.
5.	orl-rat LD50:160 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.
6.	ihl-rat LCLo:2500 ppb/4H	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
7.	orl-mus LD50:250 mg/kg	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
8.	ihl-mus LCLo:9300 ppm/15M	SCCUR* Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
9.	skn-rbt LD50:78 mg/kg	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 4 (1951),119.

2,3-Dichloropropionaldehyde Safety Profile

Poison by ingestion and skin contact. Mildly toxic by inhalation. A severe skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl⁻. See also ALDEHYDES and CHLORIDES.

2,3-Dichloropropionaldehyde Specification

2,3-Dichloropropionaldehyde ,its cas register number is 10140-89-3. It also can be called 1,2-Dichloro-3-propional ;and Propionaldehyde, 2,3-dichloro- .

Product Name

2，3-Dichloropropionaldehyde

Synthetic route

2,3-Dichloropropionaldehyde Chemical Properties

2,3-Dichloropropionaldehyde Toxicity Data With Reference

2,3-Dichloropropionaldehyde Safety Profile

2,3-Dichloropropionaldehyde Specification

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