Product Name

  • Name

    AZINPHOS-METHYL

  • EINECS 201-676-1
  • CAS No. 86-50-0
  • Density 1.51 g/cm3
  • Solubility insoluble in water
  • Melting Point 73-74
  • Formula C10H12 N3 O3 P S2
  • Boiling Point 421.3 °C at 760 mmHg
  • Molecular Weight 317.329
  • Flash Point 208.6 °C
  • Transport Information 2783
  • Appearance COLOURLESS CRYSTALS
  • Safety Poison by inhalation, ingestion, skin contact, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. See also PARATHION and ESTERS. When heated to decomposition it emits very toxic fumes of POx, SOx, and NOx.
  • Risk Codes 24-26/28-43-50/53
  • Molecular Structure Molecular Structure of 86-50-0 (AZINPHOS-METHYL)
  • Hazard Symbols A poison, cholinesterase inhibitor. Absorbed by skin. TLV: 0.2 mg/m3.
  • Synonyms Phosphorodithioicacid, O,O-dimethyl ester, S-ester with 3-(mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one(8CI); 1,2,3-Benzotriazine, phosphorodithioic acid deriv.;3-(Mercaptomethyl)-1,2,3-benzotriazin-4(3H)-one O,O-dimethyl phosphorodithioateS-ester; Azimil; Azinfos-methyl; Azinphos; Azinphos M; Azinphos-methyl; Azinugec;BAY 17147; Bayer 17147; Carfene; Cotneon; Cotnion; Cotnion-methyl; ENT 23,233;Gusathion; Gusathion 20; Gusathion 25; Gusathion M; Gusathion-methyl; Guthion;Metazintox; Methyl guthion; Methyl-azinphos; Methylgusathion; O,O-DimethylS-(3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl-methyl) dithiophosphate;O,O-Dimethyl S-(4-oxo-3H-1,2,3-benzotriazine-3-methyl)phosphorodithioate;O,O-Dimethyl S-(4-oxobenzotriazino-3-methyl)phosphorodithioate; O,O-DimethylS-4-oxo-1,2,3-benzotriazin-3(4H)-ylmethyl phosphorodithioate; O,O-DimethylS-[4-oxo-1,2,3-benzotriazine-3(4H)-ylmethyl] phosphorodithioate;O,O-Dimethylphosphorodithioate S-ester with3-(mercaptomethyl)-1,2,3-benzotriazin-4-(3H)-one; Pancide;S-(3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl) O,O-dimethyl phosphorodithioate;S-(3,4-Dihydro-4-oxo-benzo[d][1,2,3]triazin-3-ylmethyl) O,O-dimethylphosphorodithioate; S-(3,4-Dihydro-4-oxobenzo[d]-1,2,3-triazin-3-ylmethyl)dimethyl phosphorothiolothionate; Sepizin M; Toxation
  • PSA 133.44000
  • LogP 2.65010

AZINPHOS METHYL Chemical Properties

Detail of AZINPHOS METHYL (86-50-0).
Molecular Structure:

Name:AZINPHOS METHYL
CAS Number:86-50-0
Molecular Formula:C10H12N3O3PS2
Molecular Weight: 317.34
EINECS:201-676-1
Density:1.51 g/cm3
Melting Point:73-74
Boiling Point:421.3 °C at 760 mmHg
Flash Point:208.6 °C
Solubility:insoluble in water
liansport Information:2783
Properties:Crystals or brown, waxy solid.
storage temp.:0-6°C
Merck:13,915
Synonyms of AZINPHOS METHYL (86-50-0):S-(3,4-DIHYDRO-4-OXOBENZO[D]-[1,2,3]-TRIAZINE-3-YL-METHYL)O,O-DIMETHYL PHOSPHORODITHIOATE;O,O-DIMETHYL-S-[4-OXO-1,2,3-BENZOTRIAZIN-3(4H)-YLMETHYL]PHOPHORODITHIOATE;O,O-DIMETHYL-S-[4-OXO-1,2,3-BENZOTRIAZIN-3(4H)-YLMETHYL]PHOSPHORODITHIOATE;R1582;1,2,3-Benzotriazin-4(3H)-one, 3-(mercaptomethyl)-, O,O-dimethyl phosphorodithioate;1,2,3-benzotriazin-4(3h)-one,3-(mercaptomethyl)-,o,o-dimethylphosphorodith;1,2,3-benzotriazin-4(3h)-one,3-(mercaptomethyl)-,o,o-dimethylphosphorodithio;2,3-benzotriazin-4(3h)-one

AZINPHOS METHYL Toxicity Data With Reference

1.   

mmo-ssp 25 mmol/L

   MUREAV    Mutation Research. 117 (1983),139.
2.   

mma-ssp 25 mmol/L

   MUREAV    Mutation Research. 117 (1983),139.
3.   

cyt-hmn:lng 120 mg/L

   CNJGA8    Canadian Journal of Genetics and Cytology. 17 (1975),455.
4.   

cyt-hmn:oth 120 mg/L

   CNJGA8    Canadian Journal of Genetics and Cytology. 17 (1975),455.
5.   

orl-rat LD50:7 mg/kg

   JPPMAB    Journal of Pharmacy and Pharmacology. 13 (1961),435.
6.   

ihl-rat LC50:69 mg/m3/1 H

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB277-077 .
7.   

skn-rat LD50:88 mg/kg

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1182.
8.   

ipr-rat LD50:4900 µg/kg

   PSEBAA    Proceedings of the Society for Experimental Biology and Medicine. 114 (1963),509.
9.   

ivn-rat LD50:7500 µg/kg

   NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB277-077 .
10.   <p class="carditem

AZINPHOS METHYL Consensus Reports

NCI Carcinogenesis Bioassay (feed); Inadequate Studies: rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-69 ,1978. ; No Evidence: mouse NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-69 ,1978. . EPA Genetic Toxicology Program. EPA Extremely Hazardous Substances List.

AZINPHOS METHYL Safety Profile

Poison by inhalation, ingestion, skin contact, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Human mutation data reported. Questionable carcinogen with experimental tumorigenic data. See also PARATHION and ESTERS. When heated to decomposition it emits very toxic fumes of POx, SOx, and NOx.
Safety Information of AZINPHOS METHYL (86-50-0).
Hazard Codes:T+,N
Risk Statements:24-26/28-43-50/53
Safety Statements:28-36/37-45-60-61
RIDADR:2783
RTECS:TE1925000
HazardClass:6.1(a)
PackingGroup:II

AZINPHOS METHYL Standards and Recommendations

OSHA PEL: TWA 0.2 mg/m3 (skin)
ACGIH TLV: TWA 0.2 mg/m3 (skin, sensitizer); Not Classifiable as a Human Carcinogen
DFG MAK: 0.2 mg/m3

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