Product Name

  • Name

    BARIUM AZIDE

  • EINECS 242-594-6
  • CAS No. 18810-58-7
  • Article Data29
  • CAS DataBase
  • Density g/cm3
  • Solubility g/100g H2O: 12.5 (0°C), 16.1 (10°C), 17.4 (20°C) [LAN05]; alcohol 0.17 (16°C), insoluble ether [CRC10]
  • Melting Point 120ºC
  • Formula BaN6
  • Boiling Point °Cat760mmHg
  • Molecular Weight 221.37
  • Flash Point °C
  • Transport Information
  • Appearance crystalline solid
  • Safety A poison. Moderate explosion hazard when shocked or heated to 275°. Spontaneously flammable in air. Very unstable. When heated to decomposition it emits toxic fumes of NOx. See also BARIUM COMPOUNDS (soluble) and AZIDES.
  • Risk Codes 20/22
  • Molecular Structure Molecular Structure of 18810-58-7 (BARIUM AZIDE)
  • Hazard Symbols Explodes when shocked or heated.
  • Synonyms Bariumazide (6CI,7CI,8CI)
  • PSA 99.50000
  • LogP 0.42752

Barium azide Chemical Properties

Molecular Formula: BaN6
Molar mass: 194.23 g/mol
EINECS: 242-594-6
Melting point: 120°C
Appearance: White needle crystal
Product categories of Barium azide (18810-58-7): Pharmaceutical Intermediates
Structure of Barium azide (18810-58-7):
        
H-Bond Donor: 0
H-Bond Acceptor: 4
IUPAC Name: Barium(2+) diazide
Canonical SMILES: [N-]=[N+]=[N-].[N-]=[N+]=[N-].[Ba+2]
InChI: InChI=1S/Ba.2N3/c;2*1-3-2/q+2;2*-1 
InChIKey: UUXFWHMUNNXFHD-UHFFFAOYSA-N

Barium azide Uses

 Barium azide (18810-58-7) can be used as getter for low luminescence, and can extend several times of the life of the filament.

Barium azide Consensus Reports

Reported in EPA TSCA Inventory. Barium and its compounds are on the Community Right-To-Know List.

Barium azide Safety Profile

A poison. Moderate explosion hazard when shocked or heated to 275°. Spontaneously flammable in air. Very unstable. When heated to decomposition it emits toxic fumes of NOx. See also BARIUM COMPOUNDS (soluble) and AZIDES.
 

Risk Statements:
20:  Harmful by inhalation
22:  Harmful if swallowed 
Safety Statements:
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)

Barium azide Standards and Recommendations

OSHA PEL: TWA 0.5 mg(Ba)/m3
ACGIH TLV: TWA 0.5 mg(Ba)/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 0.5 mg(Ba)/m3
DOT Classification:  EXPLOSIVE 1.1A; Label: EXPLOSIVE 1.1A, Poison (UN 0224); DOT Class: 4.1; Label: Flammable Solid, Poison (UN 1571)

Barium azide Specification

 Barium azide (18810-58-7) also can be called Barium azide, dry or wetted with <50% water, by mass [UN0224] [Explosive 1.1A] ; Barium azide, wetted with not <50% water, by mass [UN1571] [Flammable solid] .

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