TRIPHENYLMETHANESULFENAMIDE

The CAS register number of Benzenemethanesulfenamide,a,a-diphenyl- is 38499-08-0. It also can be called as Triphenylmethanesulfenamide and the IUPAC name about this chemical is S-tritylthiohydroxylamine. The molecular formula about this chemical is C₁₉H₁₇NS and the molecular weight is 291.41. It belongs to the following product categories which include Organic Building Blocks; Others; Sulfur Compounds and so on.

Physical properties about Benzenemethanesulfenamide,a,a-diphenyl- are: (1)ACD/LogP: 5.73; (2)# of Rule of 5 Violations: 1  ; (3)#H bond acceptors: 1; (4)#H bond donors: 2; (5)#Freely Rotating Bonds: 5; (6)Polar Surface Area: 28.54 Å²; (7)Index of Refraction: 1.647; (8)Molar Refractivity: 91.06 cm³; (9)Molar Volume: 250.4 cm³; (10)Polarizability: 36.1x10^-24cm³; (11)Surface Tension: 49.4 dyne/cm; (12)Density: 1.163 g/cm³; (13)Flash Point: 218.6 °C; (14)Enthalpy of Vaporization: 69.46 kJ/mol; (15)Boiling Point: 437.9 °C at 760 mmHg; (16)Vapour Pressure: 7.19E-08 mmHg at 25 °C.

Preparation: this chemical can be prepared by triphenyl-methanesulfenyl chloride. This reaction will need reagents of diethyl ether, ammonia.

Uses of Benzenemethanesulfenamide,a,a-diphenyl-: it can be used to produce 3-Methylcyclohexenone tritylsulfenimine with 3-methyl-cyclohex-2-enone. This reaction will need reagents of 3-Angstroem molecular sieves, CaH₂; Pyridinium p-toluenesulfonate, (PPTS)/anhydr. MgSO₄ and solvent of CH₂Cl₂. This reaction needs heating and the reaction time is 3 days. The yield is about 44%.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin and it may cause inflammation to the skin or other mucous membranes. If you want to use it, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: S(N)C(c1ccccc1)(c2ccccc2)c3ccccc3
(2)InChI: InChI=1/C19H17NS/c20-21-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H,20H2
(3)InChIKey: PIDYQAYNSQSDQY-UHFFFAOYAH
(4)Std. InChI: InChI=1S/C19H17NS/c20-21-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H,20H2
(5)Std. InChIKey: PIDYQAYNSQSDQY-UHFFFAOYSA-N