D-(+)-Arabitol supplier | CasNO.488-81-3

Name
ADONITOL
EINECS 207-685-7
CAS No. 488-81-3
Article Data56
CAS DataBase
Density 1.526 g/cm³
Solubility Soluble in water (100 mg/ml).
Melting Point 102-105 °C
Formula C₅H₁₂O₅
Boiling Point 494.527 °C at 760 mmHg
Molecular Weight 152.147
Flash Point 261.85 °C
Transport Information
Appearance White powder
Safety 24/25-36-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Adonitol(7CI);Adonit;Adonite;NSC 16868;ribo-Pentitol;Ribitol;
PSA 101.15000
LogP -2.94630

Synthetic route

: C17H42O5Si4

: 488-81-3
Adonitol

Conditions

Conditions	Yield
Stage #1: C17H42O5Si4 With bis(pentafluorophenyl)borinic acid; 1,1,3,3-tetramethyldisilazane In 1,4-dioxane at 25℃; for 24h; Inert atmosphere; Glovebox; Stage #2: In methanol Inert atmosphere; Glovebox; chemoselective reaction;	92%

: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-Ribose

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With methanol; lithium borohydride at 10 - 20℃; for 3h; Large scale;	78%

: 54-17-1, 492-61-5, 492-62-6, 492-66-0, 530-25-6, 530-26-7, 530-27-8, 530-28-9, 552-76-1, 579-36-2, 643-69-6, 655-45-8, 2280-44-6, 3646-73-9, 7282-78-2, 7282-79-3, 7282-80-6, 7282-81-7, 7282-82-8, 7283-02-5, 7283-08-1, 7283-09-2, 7283-10-5, 7283-11-6, 7296-15-3, 7296-64-2, 7322-31-8, 10257-28-0, 12772-65-5, 12773-29-4, 12773-31-8, 12773-32-9, 12773-33-0, 12773-34-1, 19982-85-5, 28538-24-1, 32445-46-8, 32445-47-9, 32445-51-5, 32445-52-6, 34685-56-8, 34685-57-9, 35810-56-1, 39281-65-7, 39281-66-8, 39281-67-9, 39281-68-0, 39281-69-1, 39392-61-5, 39392-62-6, 39392-63-7, 39392-65-9, 39392-66-0, 39392-69-3, 40825-84-1, 40825-86-3, 40825-87-4, 40825-89-6, 42752-07-8, 42789-83-3, 46032-76-2, 54808-89-8, 66069-07-6, 120442-57-1, 120442-58-2, 120442-59-3, 120442-67-3, 131064-91-0, 131064-92-1, 131065-00-4, 131065-01-5, 131348-38-4
D-allose

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With 1-methyl-pyrrolidin-2-one; Wilkinson's catalyst at 130℃;	50%

: 18524-23-7, 876594-33-1
DL-erythro-pentene-(1)-triol-(3.4.5)-triacetate

A: 488-81-3
Adonitol

: 5346-78-1, 5401-55-8, 6330-69-4, 7208-42-6, 26674-23-7, 74033-71-9, 85761-13-3
1,2,3,4,5-penta-O-acetyl-DL-arabinitol

Conditions

Conditions	Yield
With osmium(VIII) oxide; silver(I) chlorate und Acetylierung des erhaltenen Gemisches von Ribit-1.2.3-triacetat und D-Arabit-3.4.5-triacetat Verseifen des Pentaacetats mit methylalkoh.HCl;

: 50-69-1
D-ribose

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With sodium metaborate; water
With nickel; magnesium at 100℃; under 22065.2 Torr; Hydrogenation;
Yield given. Multistep reaction;

: 24259-59-4
L-ribose

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With sodium amalgam

: 1-bromo-DL-1-deoxy-ribitol-3.4.5-triacetate

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With potassium acetate; acetic anhydride; acetic acid und Verseifen des entstandenen Pentaacetats mit siedender methylalkoh.HCl;

: 57-48-7
D-Fructose

A: 488-81-3
Adonitol

B: 81893-52-9
(S)-3,4-dihydroxy-butyraldehyde

C: 81539-41-5
2,3-dideoxy-3-C-hydroxymethyltetrose

D: 81539-40-4, 132215-58-8
2-deoxy-2-C-hydroxymethyltetrose

E: 107-21-1
ethylene glycol

F: 583-50-6
D-erythrose

Conditions

Conditions	Yield
In water Quantum yield; Irradiation; 254-nm photolysis in deoxigenated and oxygenated solutions;

...Expand

: 58-86-6
D-xylose

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With sodium tetrahydroborate

: 3445-24-7
D-erythro-pentos-2-ulose

A: 488-82-4
D-Arabitol

B: 488-81-3
Adonitol

C: 488-84-6
D-ribulose

D: 50-69-1
D-ribose

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In water at 80℃; for 0.5h;	A n/a B n/a C 70 % Chromat. D n/a

...Expand

: 922-65-6
divinylcarbinol

: 6018-27-5
1,2,3,4,5-pentapentanol

B: 87-99-0
XYLITOL

C: 488-81-3
Adonitol

Conditions

Conditions	Yield
With 4-nitroperbenzoic acid In dichloromethane at 90℃;

...Expand

: 81076-13-3
4,5-O-isopropylidene-D-ribitol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With Dowex 50X8-200 resin In water at 25℃; for 3h;
With hydrogenchloride

: 85716-54-7
(Z)-(4RS)-1,4,5-triacetoxypent-2-ene

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With pyridine; hydrogenchloride; tert.-butylhydroperoxide; osmium(VIII) oxide; tetraethylammonium acetate; acetic anhydride Yield given. Multistep reaction;

: 81028-11-7, 81076-13-3, 81076-14-4, 81076-15-5, 92935-75-6, 92935-76-7, 92935-77-8, 92935-78-9
(1R,2R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propane-1,2,3-triol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With hydrogenchloride In methanol Heating;
With hydrogenchloride In methanol Heating;

: 88367-64-0, 88391-55-3, 88391-65-5, 88391-66-6
(1R,2R)-(S)-1-(1,4-Dioxa-spiro[4.5]dec-2-yl)-propane-1,2,3-triol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With hydrogenchloride In methanol Heating;
With hydrogenchloride In methanol Heating;

: 88367-62-8, 88391-53-1, 88391-61-1, 88391-62-2
2,2-Dimethyl-propionic acid (2R,3R)-3-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,3-dihydroxy-propyl ester

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0℃;
Multi-step reaction with 2 steps 1: 5 percent conc HCl / methanol / Heating 2: LiAlH4 / diethyl ether / 0 °C View Scheme

: 88367-65-1, 88391-56-4, 88391-67-7, 88391-68-8
(2R,3R,4S)-4,5-Bis-benzyloxy-pentane-1,2,3-triol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol; acetic acid
With hydrogen; palladium on activated charcoal In methanol; acetic acid Ambient temperature;

: 88367-63-9, 88391-54-2, 88391-63-3, 88391-64-4
(1S,2S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propane-1,2-diol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0℃;
Multi-step reaction with 2 steps 1: 5 percent conc HCl / methanol / Heating 2: (n-Bu)4N(+)F(-) / tetrahydrofuran / Ambient temperature View Scheme

: 2,2-Dimethyl-propionic acid (2S,3R,4R)-2,3,4,5-tetrahydroxy-pentyl ester

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0℃;

: (2R,3R,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-pentane-1,2,3,4-tetraol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran Ambient temperature;

: C41H66O14

A: 488-81-3
Adonitol

B: (2R,4aS,5R,6aS,6bR,9R,10S,12aS)-5-Hydroxy-4a,9-bis-hydroxymethyl-2,6a,6b,9,12a-pentamethyl-10-((2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b-octadecahydro-picene-2-carboxylic acid

Conditions

Conditions	Yield
With sodium hydroxide In water

: scorzoneroside B

A: 2280-44-6
D-Glucose

B: 488-81-3
Adonitol

C: (2R,4aS,5R,6aS,6bR,9R,10S,12aS)-5-Hydroxy-4a,9-bis-hydroxymethyl-2,6a,6b,9,12a-pentamethyl-10-((2R,3R,4S,5R,6R)-3,4,5-trihydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,12b-octadecahydro-picene-2-carboxylic acid

Conditions

Conditions	Yield
With sodium hydroxide In water

...Expand

: 226089-02-7
(2S,3S,4R)-5-((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-pentane-1,2,3,4-tetraol

A: 2280-44-6
D-Glucose

B: 488-81-3
Adonitol

Conditions

Conditions	Yield
With sulfuric acid In 1,4-dioxane; water

: 35320-17-3
D-ribitol 5-phosphate

aqueous ammonium acetate: aqueous ammonium acetate

: 488-81-3
Adonitol

Conditions

Conditions	Yield
Hydrolysis;

: 488-30-2
arabinoic acid

A: 909878-64-4
meso-erythritol

B: 488-82-4
D-Arabitol

C: 87-99-0
XYLITOL

D: 488-81-3
Adonitol

Conditions

Conditions	Yield
With hydrogen; Ru-carbon In water at 80℃; under 45003.6 Torr; Product distribution; Further Variations:; Catalysts; pH-values; Temperatures; Reagents;

...Expand

: 141-46-8
Glycolaldehyde

: 56-82-6
Glyceraldehyde

A: 2418-52-2
D-threitol

B: 488-82-4
D-Arabitol

C: 87-99-0
XYLITOL

D: 488-81-3
Adonitol

Conditions

Conditions	Yield
Stage #1: Glycolaldehyde; Glyceraldehyde With zinc(II) bis(L-proline) In water at 20℃; for 168h; Stage #2: With sodium tetrahydroborate for 3h; Further byproducts given. Title compound not separated from byproducts;

...Expand

O-polysaccharide of the lipopolysaccharide from Proteus vulgaris strain TG 276-1: O-polysaccharide of the lipopolysaccharide from Proteus vulgaris strain TG 276-1

A: C6H12N2O2

B: 488-81-3
Adonitol

Conditions

Conditions	Yield
With trifluoroacetic acid at 120℃; for 2h;

: Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4S)-2,3,4,5-tetrahydroxy-pentyloxy)-tetrahydro-pyran-4-yl ester

: 488-81-3
Adonitol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: NaOMe / methanol 2: 5percent H2SO4 / H2O; dioxane View Scheme

: 102419-56-7
(1R,4'R)-1-(2,2-dimethyl-1,3-dioxolane-4-yl)-2-trimethylsilylprop-2-en-1-ol

: 488-81-3
Adonitol

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 85 percent / TBHP-VO(acac)2 2: 80 percent / t-BuOK, n-Bu4NF 3: 70 percent / NaOH / 70 °C 4: HCl View Scheme

: 488-81-3
Adonitol

: 77-76-9
2,2-dimethoxy-propane

: 3969-85-5, 73543-86-9, 88390-55-0
bis(2,2-dimethyl-1,3-dioxolan-4-yl)methanol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide Ambient temperature;	99%
With hydrogen cation In acetone for 2h; Ambient temperature;	95%
With toluene-4-sulfonic acid In N,N-dimethyl-formamide; acetone at 20℃; for 16h; Cyclization;	85%

: 4437-80-3
4,4-dimethyl-5-methylene-1,3-dioxolan-2-one

: 488-81-3
Adonitol

: C13H16O10

Conditions

Conditions	Yield
With 1-methyl-2,3,4,6,7,8-hexahydro-1H-pyrimido[1,2-a]pyrimidine In N,N-dimethyl-formamide at 25℃; for 24h;	99%

: 488-81-3
Adonitol

: 108-24-7
acetic anhydride

: 7208-42-6
penta-O-acetylribitol

Conditions

Conditions	Yield
With Sulfuric acid immobilized on silica gel at 20℃; for 0.333333h; neat (no solvent);	98%
With zinc(II) chloride anfangs unter Eiskuehlung;
With pyridine Ambient temperature;

: 488-81-3
Adonitol

: (S)-((R)-2-Oxo-2λ4-[1,3,2]dioxathiolan-4-yl)-((S)-2-oxo-2λ4-[1,3,2]dioxathiolan-4-yl)-methanol

Conditions

Conditions	Yield
With 1H-imidazole; thionyl chloride In tetrahydrofuran at -10℃; for 0.5h;	98%

: 488-81-3
Adonitol

: 849585-22-4
LACTIC ACID

Conditions

Conditions	Yield
With barium hydroxide octahydrate In methanol at 140℃; for 12h; Inert atmosphere; Sealed tube;	93%
With H2O*Ba8H16O16 In methanol at 140℃; for 12h; Sealed tube;	88 %Chromat.

: 488-81-3
Adonitol

: 461-64-3
ethyl fluoroformate

: 124781-65-3
Penta-O-(ethoxycarbonyl)adonitol

Conditions

Conditions	Yield
With potassium fluoride In dimethyl sulfoxide 1) 60 deg C, 10 h; 2) 90 deg C, 10 h;	91%

: 488-81-3
Adonitol

: 491-19-0, 3169-91-3, 3169-92-4, 3999-31-3, 39798-06-6, 39999-42-3, 41935-96-0, 41936-38-3, 51607-76-2, 51607-78-4, 53448-53-6, 58716-62-4, 106248-68-4, 106707-70-4, 120442-63-9
1,4-anhydro-D,L-ribitol

Conditions

Conditions	Yield
With hydrogenchloride at 100℃; for 48h;	90%
With pyridine hydrochloride at 150℃;	70%
at 290℃; for 2h;	45%
With hydrogenchloride at 110℃;

: 488-81-3
Adonitol

: 491-19-0, 3169-91-3, 3169-92-4, 3999-31-3, 39798-06-6, 39999-42-3, 41935-96-0, 41936-38-3, 51607-76-2, 51607-78-4, 53448-53-6, 58716-62-4, 106248-68-4, 106707-70-4, 120442-63-9
1,4-anhydro-D-ribitol

Conditions

Conditions	Yield
With carbon tetrabromide; triphenylphosphine In N,N-dimethyl-formamide Ambient temperature;	90%
In water at 249.84℃; Kinetics; Temperature; Inert atmosphere;

: 1189-71-5
isocyanate de chlorosulfonyle

: 488-81-3
Adonitol

: d-ribitol pentacarbamate

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1.5h; Cooling with ice;	88%

: 488-81-3
Adonitol

: 76-83-5
trityl chloride

: 96871-07-7
1,5-Di-O-trityladonitol

Conditions

Conditions	Yield
With pyridine at 100℃; for 22h; Inert atmosphere;	85%
With pyridine at 100℃;
With pyridine at 20℃;
With pyridine; dmap at 25℃; for 33h;
With pyridine; dmap at 20℃; for 30h; Inert atmosphere;

: 488-81-3
Adonitol

: 67-64-1
acetone

: 3969-86-6, 19139-74-3, 30737-85-0, 84709-27-3, 84709-35-3, 84709-41-1, 100484-23-9, 127305-49-1
1,2:3,4-Di-O-isopropylidene-DL-ribitol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In various solvent(s) Ambient temperature;	85%

: 488-81-3
Adonitol

: 33842-02-3, 529510-96-1
dichloromethylenedimethyliminium chloride

: 143094-04-6, 143167-34-4, 143167-35-5
1,5-dichloro-1,5-dideoxy-2,4-di-O--ribitol

Conditions

Conditions	Yield
In 1,4-dioxane at 25℃; for 2.5h;	79%
In 1,4-dioxane at 23℃; for 2.5h;	79%

: 488-81-3
Adonitol

: 3457-45-2
p-formylacetophenone

: 2,4-(4-methylcarbonylbenzylidene)-D-xylitol

Conditions

Conditions	Yield
With hydrogenchloride In methanol; water for 8h;	70%

: 488-81-3
Adonitol

: 1005-56-7
phenylcarbonochloridothioate

: ribitol-1,2:4,5-bis-thionocarbonate

Conditions

Conditions	Yield
Stage #1: Adonitol With di(n-butyl)tin oxide In toluene Stage #2: phenylcarbonochloridothioate In chloroform at 20℃; for 4h;	63%
Stage #1: Adonitol With di(n-butyl)tin oxide In toluene Heating; Stage #2: phenylcarbonochloridothioate In chloroform at 20℃; for 4h;	63%

: 488-81-3
Adonitol

: C22H22ClF3N2O4S

: 77-76-9
2,2-dimethoxy-propane

: C30H32ClF3N2O8S

Conditions

Conditions	Yield
Stage #1: Adonitol With pyridine hydrochloride at 150℃; for 4h; Stage #2: 2,2-dimethoxy-propane With toluene-4-sulfonic acid In acetone at 20℃; for 0.5h; Stage #3: C22H22ClF3N2O4S Further stages;	58%

...Expand

: 488-81-3
Adonitol

: 100664-93-5
ribitol 3-O-(dichlorophosphite) 1,2;4,5-bis-O-(chlorophosphite)

Conditions

Conditions	Yield
With phosphorus trichloride In 1,4-dioxane at 60 - 65℃; for 30h;	57%

: 488-81-3
Adonitol

: 108-24-7
acetic anhydride

: 100-39-0
benzyl bromide

A: 7208-42-6
penta-O-acetylribitol

: 2,3,4,5-tetra-O-acetyl-1-O-benzyl-D,L-ribitol

C: 2,3,4-tri-O-acetyl-1,5-di-O-benzylribitol

Conditions

Conditions	Yield
Stage #1: Adonitol With bis(tri-n-butyltin)oxide In toluene for 5h; Heating; Stage #2: benzyl bromide at 80℃; for 20h; Stage #3: acetic anhydride With pyridine at 20℃;	A 23% B 52% C 16%

...Expand

: 488-81-3
Adonitol

: 33842-02-3, 529510-96-1
dichloromethylenedimethyliminium chloride

A: 143094-04-6, 143167-34-4, 143167-35-5
1,5-dichloro-1,5-dideoxy-2,4-di-O--ribitol

: 1,4,5-trichloro-1,4,5-trideoxy-2,3-di-O--DL-arabinitol

Conditions

Conditions	Yield
In 1,4-dioxane at 23℃; for 26h;	A 47% B 20%

...Expand

: 488-81-3
Adonitol

: 33842-02-3, 529510-96-1
dichloromethylenedimethyliminium chloride

A: 143094-04-6, 143167-34-4, 143167-35-5
1,5-dichloro-1,5-dideoxy-2,4-di-O--ribitol

B: 1,3,5-trichloro-1,3,5-trideoxy-2,4-di-O--ribitol or -xylitol

Conditions

Conditions	Yield
In 1,4-dioxane at 23℃; for 26h;	A 47% B 21%

...Expand

: 488-81-3
Adonitol

: 108-24-7
acetic anhydride

: 100-39-0
benzyl bromide

A: 7208-42-6
penta-O-acetylribitol

: 2,3,4,5-tetra-O-acetyl-1-O-benzyl-D,L-ribitol

C: 2,3,4-tri-O-acetyl-1,5-di-O-benzylribitol

: 2,3,5-tri-O-acetyl-1,4-di-O-benzyl-D,L-ribitol

Conditions

Conditions	Yield
Stage #1: Adonitol With di(n-butyl)tin oxide In toluene for 16h; Heating; Stage #2: benzyl bromide In chloroform at 65℃; for 65h; Stage #3: acetic anhydride With pyridine at 20℃;	A 47% B 10% C n/a D n/a
Stage #1: Adonitol With di(n-butyl)tin oxide In toluene for 16h; Heating; Stage #2: benzyl bromide In chloroform at 50℃; for 40h; Stage #3: acetic anhydride With pyridine at 20℃;	A 32% B 31% C 8% D 17%
Stage #1: Adonitol With di(n-butyl)tin oxide In toluene for 16h; Heating; Stage #2: benzyl bromide In chloroform at 65℃; for 65h; Stage #3: acetic anhydride With pyridine at 20℃;	A 16% B 26% C 11% D 20%

...Expand

: 488-81-3
Adonitol

: 334-48-5
1-decanoic acid

: (±) ribitol monocaprate

Conditions

Conditions	Yield
With (1S)-10-camphorsulfonic acid; phenylboronic acid In toluene at 120 - 130℃; for 24h; Inert atmosphere; Dean-Stark;	47%

: 488-81-3
Adonitol

: 57-11-4
stearic acid

: (±) ribitol monostearate

Conditions

Conditions	Yield
With (1S)-10-camphorsulfonic acid; phenylboronic acid In toluene at 120 - 130℃; for 24h; Inert atmosphere; Dean-Stark;	44%

: 589-98-0
rac-3-octanol

: 488-81-3
Adonitol

: 1402224-63-8
(E)-3-(penta-2,4-dienyloxy)octane

Conditions

Conditions	Yield
With C13H21O3Re at 135℃; for 15h; Reagent/catalyst; Inert atmosphere;	42%

: 488-81-3
Adonitol

: 122-52-1
triethyl phosphite

: 117562-69-3
3-O-(diethyl phosphite)-1,2:4,5-bis-O-(ethyl phosphite)ribitol

Conditions

Conditions	Yield
at 115 - 130℃;	38%

: 488-81-3
Adonitol

: 116-11-0
2-Methoxypropene

A: 3969-85-5, 73543-86-9, 88390-55-0
bis(2,2-dimethyl-1,3-dioxolan-4-yl)methanol

: 100423-71-0, 100484-25-1
1,4:2,3-di-O-isopropylidene-DL-ribitol

: 131247-52-4
1,3:4,5-di-O-isopropylidene-DL-ribitol

: 131247-54-6
1,3:2,5-di-O-isopropylidene-DL-ribitol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 0℃; for 0.0166667h;	A 36% B 3% C 12% D 5%
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 0℃; for 0.0166667h; Product distribution;	A 36% B 3% C 12% D 5%

...Expand

: 488-81-3
Adonitol

: 584-02-1
2-pentanol

: 1402224-62-7
(E)-5-(pentan-3-yloxy)penta-1,3-diene

Conditions

Conditions	Yield
With methyltrioxorhenium(VII) at 170℃; for 3h;	33%

: 488-81-3
Adonitol

: 120878-42-4
3,4-bis(decyloxy)benzoic acid

: Pentakis-O-(3,4-didecyloxybenzoyl)adonitol

Conditions

Conditions	Yield
With dmap In dichloromethane at 20℃; for 72h; Esterification;	8%

D-(+)-Arabitol Chemical Properties

Molecular Formula: C₅H₁₂O₅
Molar mass: 152.15 g/mol
EINECS: 207-685-7
Density: 1.525 g/cm³
Flash Point: 261.9 °C
Index of Refraction: 1.57
Boiling Point: 494.5 °C at 760 mmHg
Vapour Pressure: 7.47E-12 mmHg at 25°C
Melting point: 102-105 °C
Storage temp: Store at RT.
Sensitive: Hygroscopic
Appearance: White powder
Product categories: Sugars, Carbohydrates & Glucosides;Biochemistry;Sugar Alcohols
Structure of Ribitol (488-81-3):

XLogP3-AA: -2.5
H-Bond Donor: 5
H-Bond Acceptor: 5
Systematic Name: Pentane-1,2,3,4,5-pentol
SMILES: OC(CO)C(O)C(O)CO
InChI: InChI=1/C5H12O5/c6-1-3(8)5(10)4(9)2-7/h3-10H,1-2H2
InChIKey: HEBKCHPVOIAQTA-UHFFFAOYAB
Std. InChI: InChI=1S/C5H12O5/c6-1-3(8)5(10)4(9)2-7/h3-10H,1-2H2
Std. InChIKey: HEBKCHPVOIAQTA-UHFFFAOYSA-N

D-(+)-Arabitol Production

Ribitol (488-81-3) is formed by the reduction of Ribose . It occurs naturally in the plant Adonis vernalis, as well as in the cell walls of Gram positive bacteria.

D-(+)-Arabitol Toxicity Data With Reference

ipr-mus LDLo:10 g/kg

PSEBAA Proceedings of the Society for Experimental Biology and Medicine. 35 (1936),98.

Carcinogenicity of Ribitol (488-81-3) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65.You can see actual entry in RTECS for complete information.

D-(+)-Arabitol Consensus Reports

Reported in EPA TSCA Inventory.

D-(+)-Arabitol Safety Profile

Mildly toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes.

Hazard Codes: Xi
Risk Statements:
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
24: Avoid contact with skin
25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing

D-(+)-Arabitol Specification

Ribitol (488-81-3) is a crystalline pentose alcohol, and also can be called adonitol ; pentitol ; Pentane-1,2,3,4,5-pentaol ; 1,2,3,4,5-Pentanepentol ; 1,2,3,4,5-Pentahydroxypentane .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing.Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Then you have the ingesting of the product : Do not induce vomiting.If victim is conscious and alert, give 2-4 cupfuls of milk or water.
In addition, Ribitol (488-81-3) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, and you must not take it with strong oxidants and incompatible materials.And also prevent it to broken down into hazardous decomposition products: irritating and toxic fumes and gases, carbon dioxide, carbon monoxide.

Product Name

ADONITOL

Synthetic route

D-(+)-Arabitol Chemical Properties

D-(+)-Arabitol Production

D-(+)-Arabitol Toxicity Data With Reference

D-(+)-Arabitol Consensus Reports

D-(+)-Arabitol Safety Profile

D-(+)-Arabitol Specification

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