Dibromofluoromethane supplier

Name
Dibromofluoromethane
EINECS
CAS No. 1868-53-7
Article Data12
CAS DataBase
Density 2.484 g/cm³
Solubility
Melting Point -78°C
Formula CHBr₂F
Boiling Point 67.781 °C at 760 mmHg
Molecular Weight 191.825
Flash Point -5.206 °C
Transport Information
Appearance liquild
Safety 24/25-41-59-45-36/37-16
Risk Codes 23/24/25-59-22-39/23/24/25-11
Molecular Structure
Hazard Symbols Xi,N,Xn,T,F
Synonyms Dibromofluoromethane;Fluorodibromomethane;
PSA 0.00000
LogP 2.02930

Synthetic route

: 353-54-8
tribromofluoromethane

: 1868-53-7
dibromofluoromethane

Conditions

Conditions	Yield
Stage #1: tribromofluoromethane With triphenylphosphine In N,N-dimethyl-formamide for 0.5h; Stage #2: With zinc In N,N-dimethyl-formamide at 20℃; for 0.25h;	56%

: 75-25-2
Bromoform

: 1868-53-7
dibromofluoromethane

Conditions

Conditions	Yield
With mercury(II) fluoride
With bromine; antimony(III) fluoride
With potassium fluoride; antimony(III) chloride
With calcium fluoride; antimony(III) chloride
With bromine; antimony(III) fluoride at 110 - 120℃;

: 353-99-1
dibromofluoroacetic acid

: 1868-53-7
dibromofluoromethane

Conditions

Conditions	Yield
beim Kochen der Loesung;

: 81962-38-1
dibromofluoromethyltriphenylphosphonium bromide

A: 1868-53-7
dibromofluoromethane

B: 353-54-8
tribromofluoromethane

C: 1478-04-2
fluorodibromoiodomethane

D: 753-67-3
fluorobromodiiodomethane

Conditions

Conditions	Yield
With potassium fluoride; iodine In various solvent(s)	A 10 % Spectr. B 31 % Spectr. C 57 % Spectr. D 15 % Spectr.
With potassium fluoride; iodine In various solvent(s) Title compound not separated from byproducts;	A 10 % Spectr. B 31 % Spectr. C 57 % Spectr. D 15 % Spectr.

...Expand

: 81962-38-1
dibromofluoromethyltriphenylphosphonium bromide

A: 1868-53-7
dibromofluoromethane

B: 791-28-6
Triphenylphosphine oxide

Conditions

Conditions	Yield
With water In chloroform for 1h; Mechanism;

silver-salt of/the/ (+-)-bromo-fluoro-acetic acid: silver-salt of/the/ (+-)-bromo-fluoro-acetic acid

: 1868-53-7
dibromofluoromethane

Conditions

Conditions	Yield
With bromine at 100℃;

: 75-25-2
Bromoform

: 7726-95-6
bromine

: 7783-56-4
antimony(III) fluoride

A: 1511-62-2
bromodifluoromethane

B: 1868-53-7
dibromofluoromethane

...Expand

: 7726-95-6
bromine

: 359-16-0
bromo-fluoro-acetic acid ; silver-salt

: 1868-53-7
dibromofluoromethane

: 563-79-1
2,3-Dimethyl-2-butene

: 65094-25-9
diethyl dibromofluoromethylphosphonate

A: 1868-53-7
dibromofluoromethane

B: 358-74-7
diethyl fluorophosphate

C: 34636-25-4
1-bromo-1-fluoro-2,2,3,3-tetramethylcyclopropane

Conditions

Conditions	Yield
With potassium fluoride In Triethylene glycol dimethyl ether at 20℃;	A 8 %Spectr. B 93 %Spectr. C 45 %Spectr.

...Expand

: 65094-25-9
diethyl dibromofluoromethylphosphonate

A: 1868-53-7
dibromofluoromethane

B: 358-74-7
diethyl fluorophosphate

Conditions

Conditions	Yield
With potassium fluoride; ethanol In Triethylene glycol dimethyl ether at 20℃;	A 67 %Spectr. B 72 %Spectr.

: 1868-53-7
dibromofluoromethane

: 15,15'-Bis(hexaspiro[2.0.2.0.0.0.2.0.2.0.1.0]pentadecylidene)

: 24-Bromo-24-fluorotetradecaspiro[2.0.2.0.0.0.0.0.2.0.2.0.0.0.2.0.2.0.0.1.0.0.2.0.2.0.0.0]untriacontane

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride at 20℃; for 72h; Addition;	94%

: 1868-53-7
dibromofluoromethane

: 15,15'-Bis(hexaspiro[2.0.2.0.0.0.2.0.2.0.1.0]pentadecylidene)

: 24-Bromo-24-fluorotetradecaspiro[2.0.2.0.0.0.0.0.2.0.2.0.0.0.2.0.2.0.0.1.0.0.2.0.2.0.0.0]untriacontane

Conditions

Conditions	Yield
With sodium hydroxide; ethanol; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane at 20℃; for 72h;	94%

: 1868-53-7
dibromofluoromethane

: 704908-60-1
2-vinyl-3-(methoxy)isoindol-1-one

: 2-(2-bromo-2-fluoro-cyclopropyl)-3-methoxy-2,3-dihydro-isoindol-1-one

Conditions

Conditions	Yield
With potassium hydroxide; Bn(n-Bu)3Cl In dichloromethane	92%

: 4233-18-5
bicyclohexylidene

: 1868-53-7
dibromofluoromethane

: 78775-49-2
13-Brom-13-fluordispiro<5.0.5.1>tridecan

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 4h; Ambient temperature;	90%

: 1868-53-7
dibromofluoromethane

: 3-methoxy-3-(2-methoxy-phenyl)-2-vinyl-2,3-dihydro-isoindol-1-one

: 2-(2-bromo-2-fluoro-cyclopropyl)-3-methoxy-3-(2-methoxy-phenyl)-2,3-dihydro-isoindol-1-one

Conditions

Conditions	Yield
With potassium hydroxide; 18-crown-6 ether In dichloromethane at 0℃;	88%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-(trifluoromethoxy)benzoate

: 7-bromo-7-fluoroheptyl 4-(trifluoromethoxy)benzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	87%

: 1868-53-7
dibromofluoromethane

: 3-isopropyl-3-methoxy-2-vinyl-2,3-dihydro-isoindol-1-one

: 2-(2-bromo-2-fluoro-cyclopropyl)-3-isopropyl-3-methoxy-2,3-dihydro-isoindol-1-one

Conditions

Conditions	Yield
With potassium hydroxide; 18-crown-6 ether In dichloromethane at 20℃;	86%

: 1868-53-7
dibromofluoromethane

: 14114-06-8
cyclopropylidenecyclohexane

: 1175147-15-5
10-bromo-10-fluorodispiro[2.0.5.1]decane

Conditions

Conditions	Yield
With ethanol; N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane; water at 0 - 20℃;	86%

: 530-48-3
1,1-Diphenylethylene

: 1868-53-7
dibromofluoromethane

: 64859-37-6
(2-bromo-2-fluorocyclopropane-1,1-diyl)dibenzene

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane at 20℃;	84%
With potassium tert-butylate In hexane

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-iodobenzoate

: 7-bromo-7-fluoroheptyl 4-iodobenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	83%

: 1868-53-7
dibromofluoromethane

: 111-81-9
Methyl 10-undecenoate

: methyl-10,12-dibromo-12-fluoro dodecanoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	82%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-iodobenzoate

: 5,7-dibromo-7-fluoroheptyl-4-iodo benzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	82%

: 1868-53-7
dibromofluoromethane

: 1453-24-3
1-ethylcyclohexene

: 78775-52-7
7-Brom-1-ethyl-7-fluorbicyclo<4.1.0>heptan

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 4h; Ambient temperature; also: 6h, reflux;	80%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-methylbenzoate

: 7-bromo-7-fluoroheptyl 4-methylbenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	80%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-fluorobenzoate

: 5,7-dibromo-7-fluoroheptyl 4-fluorobenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	80%

: 1868-53-7
dibromofluoromethane

: 1352390-87-4
hex-5-en-1-yl 4-bromobenzoate

: 7-bromo-7-fluoroheptyl 4-bromobenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	79%

: 1868-53-7
dibromofluoromethane

: 3-methoxy-3-m-tolyl-2-vinyl-2,3-dihydro-isoindol-1-one

: 2-(2-bromo-2-fluoro-cyclopropyl)-3-methoxy-3-m-tolyl-2,3-dihydro-isoindol-1-one

Conditions

Conditions	Yield
With potassium hydroxide; 18-crown-6 ether In dichloromethane at 20℃;	78%

: 1868-53-7
dibromofluoromethane

: 1528-30-9
methylenecyclopentane

: 1-bromo-1-fluorospiro[2.4]heptane

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In dichloromethane; benzene at 20℃;	78%

: 1868-53-7
dibromofluoromethane

: 2-methylene-1-tosylpyrrolidine

: C13H15BrFNO2S

Conditions

Conditions	Yield
With sodium hydroxide	78%
With benzyltrimethylammonium chloride; sodium hydroxide In dichloromethane at 20℃; for 25.5h;	1.0 g

: 1868-53-7
dibromofluoromethane

: 112-41-4
1-dodecene

: 1,3-dibromo-1-fluorotridecane

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	78%

: 1868-53-7
dibromofluoromethane

: 1352390-87-4
hex-5-en-1-yl 4-bromobenzoate

: 5,7-dibromo-7-fluoroheptyl 4-bromobenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	78%

: 1868-53-7
dibromofluoromethane

: 41795-26-0
benzoic acid hex-5-enyl ester

: 7-bromo-7-fluoroheptyl benzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	77%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl benzenesulfonate

: 5,7-dibromo-7-fluoroheptyl benzenesulfonate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	77%

: 821-41-0
5-Hexen-1-ol

: 1868-53-7
dibromofluoromethane

: 5,7-dibromo-7-fluoroheptan-1-ol

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	77%

: 1868-53-7
dibromofluoromethane

: 111-81-9
Methyl 10-undecenoate

: methyl 12-bromo-12-fluorododecanoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	76%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 4-methoxybenzoate

: 5,7-dibromo-7-fluoroheptyl 4-methoxybenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	76%

: 1868-53-7
dibromofluoromethane

: C15H18O4

: 5,7-dibromo-7-fluoroheptyl methyl terephthalate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	76%

: 1868-53-7
dibromofluoromethane

: 74972-56-8
(hex-5-en-1-yloxy)benzene

: ((5,7-dibromo-7-fluoroheptyl)oxy)benzene

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	76%

: 1868-53-7
dibromofluoromethane

: hex-5-en-1-yl 3,6-dichloro-2-methoxybenzoate

: 5,7-dibromo-7-fluoroheptyl 3,6-dichloro-2-methoxybenzoate

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In water; N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere; Irradiation;	76%

: 7736-25-6
2-(pent-4-enyl)-isoindoline-1,3-dione

: 1868-53-7
dibromofluoromethane

: 1616366-00-7
2-(6-bromo-6-fluorohexyl)isoindoline-1,3-dione

Conditions

Conditions	Yield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; potassium hydrogencarbonate In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Irradiation;	75%

Dibromofluoromethane Chemical Properties

Molecular Structure of Methane, dibromofluoro-(6CI,7CI,8CI,9CI) (CAS NO.1868-53-7):

Molecular Formula: CHBr₂F
Molecular Weight: 191.825
IUPAC Name: Dibromo(fluoro)methane
Synonyms of Methane, dibromofluoro-(6CI,7CI,8CI,9CI) (CAS NO.1868-53-7): Dibromofluoromethane ; Methane, dibromofluoro-
CAS NO: 1868-53-7
Classification Code: Alpha Sort ; BromoVolatiles/ Semivolatiles ; Chemical Class ; D ; DAlphabetic ; DIA - DIC ; Halogenated
Index of Refraction: 1.488
Molar Refractivity: 22.26 cm³
Molar Volume: 77.2 cm³
Surface Tension: 31.5 dyne/cm
Density: 2.483 g/cm³
Enthalpy of Vaporization: 29.67 kJ/mol
Boiling Point: 67.8 °C at 760 mmHg
Vapour Pressure: 155 mmHg at 25°C

Dibromofluoromethane Safety Profile

Hazard Codes of Methane, dibromofluoro-(6CI,7CI,8CI,9CI) (CAS NO.1868-53-7): Irritant Xi,N, Harmful Xn, Toxic T, Flammable F
Risk Statements: 23/24/25-59-22-39-11
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R59: Dangerous to the ozone layer.
R22: Harmful if swallowed.
R39: Danger of very serious irreversible effects.
R11: Highly flammable.
Safety Statements: 24/25-41-59-45-36/37
S24/25: Avoid contact with skin and eyes.
S41: In case of fire and / or explosion do not breathe fumes.
S59: Refer to manufacturer / supplier for information on recovery / recycling.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37: Wear suitable protective clothing and gloves.
RIDADR: 2810
Hazard Note: Irritant

Product Name

Dibromofluoromethane

Synthetic route

Dibromofluoromethane Chemical Properties

Dibromofluoromethane Safety Profile

Related Products

Hot Products