Product Name

  • Name

    Diphenic anhydride

  • EINECS 227-950-0
  • CAS No. 6050-13-1
  • Article Data34
  • CAS DataBase
  • Density 1.335 g/cm3
  • Solubility decomposes
  • Melting Point 225-227 °C
  • Formula C14H8O3
  • Boiling Point 424 °C at 760 mmHg
  • Molecular Weight 224.216
  • Flash Point 212 °C
  • Transport Information
  • Appearance beige - white Crystalline Powder
  • Safety 26-37/39-7/8-24/25-37
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 6050-13-1 (Diphenic anhydride)
  • Hazard Symbols
  • Synonyms Diphenicanhydride (6CI,7CI,8CI);2,2'-Biphenyldicarboxylic acid anhydride;2,2'-Biphenyldicarboxylic anhydride;2,2'-Diphenic anhydride;2,2'-Diphenyldicarboxylic anhydride;Diphenic acid anhydride;NSC 116225;NSC67689;
  • PSA 47.28000
  • LogP 2.30640

Diphenic anhydride Chemical Properties

IUPAC Name: Benzo[d][2]benzoxepine-5,7-dione 
Following is the structure of Dibenz[c,e]oxepin-5,7-dione (CAS NO.6050-13-1):
                     
Empirical Formula: C14H8O3
Molecular Weight: 224.2115
EINECS: 227-950-0
Index of Refraction: 1.637
Molar Refractivity: 60.27 cm3
Molar Volume: 167.8 cm3
Density: 1.335 g/cm3
Flash Point: 212 °C
Surface Tension: 54 dyne/cm
Sensitive: Moisture Sensitive
Water Solubility: decomposes
Melting point: 225-227 °C(lit.)
Enthalpy of Vaporization: 67.84 kJ/mol
Boiling Point: 424 °C at 760 mmHg
Vapour Pressure: 2.14E-07 mmHg at 25 °C 
Appearance: beige - white Crystalline Powder
Product Categories: Biphenyl derivatives; Anhydride Monomers; Monomers; Polymer Science
Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3C(=O)OC2=O
InChI: InChI=1S/C14H8O3/c15-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14(16)17-13/h1-8H
InChIKey: RTSGJTANVBJFFJ-UHFFFAOYSA-N

Diphenic anhydride Toxicity Data With Reference

 Dibenz[c,e]oxepin-5,7-dione (CAS NO.6050-13-1) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.

Diphenic anhydride Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39-7-8-24/25-37 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37/39:Wear suitable gloves and eye/face protection. 
S7:Keep container tightly closed. 
S8:Keep container dry. 
S24/25:Avoid contact with skin and eyes. 
S37:Wear suitable gloves.
WGK Germany: 3

Diphenic anhydride Specification

 Dibenz[c,e]oxepin-5,7-dione , its cas register number 6050-13-1. It also can be called Diphenic anhydride ; 2,2'-Diphenyldicarboxylic anhydride ; and 2,2'-Biphenyldicarboxylic anhydride .
 Dibenz[c,e]oxepin-5,7-dione (CAS NO.6050-13-1) could be stable under normal temperatures and pressures. It should avoid the condition like incompatible materials, strong oxidants, exposure to moist air or water. It is not compatible with strong oxidizing agents, strong bases. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.  However, its hazardous polymerization has not been reported.

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