• Name

  GLYCERYL TRIBENZOATE

• EINECS
• CAS No. 614-33-5
• Article Data23
• CAS DataBase
• Density 1.243g/cm³
• Solubility
• Melting Point 68-72 °C(lit.)
  
• Formula C24H20 O6
• Boiling Point 548.9°C at 760 mmHg
• Molecular Weight 404.419
• Flash Point 238.1°C
• Transport Information
• Appearance
• Safety Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms 1,2,3-Propanetriol,tribenzoate (9CI); Glycerol, tribenzoate (6CI,7CI,8CI); Benzoflex S 404;Glyceryl tribenzoate; NSC 2230; Tribenzoin; Uniplex 260
• PSA 78.90000
• LogP 3.92600

Synthetic route

56-81-5

glycerol

65-85-0

benzoic acid

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
With calcium hydroxide In 5,5-dimethyl-1,3-cyclohexadiene; decane at 220℃; for 1h; Solvent; Reagent/catalyst; Reflux; Large scale;	99.2%
With H2SO4/TiO2-La2O3-solid acid catalyst at 185 - 195℃; for 12h;	88.6%
at 200℃; anschl. auf 270grad;
at 200℃; dann auf 270grad im Druckrohr erhitzen;
With silicate-catalyst at 200 - 220℃; unter Entfernen des entstehenden Wassers;

98-88-4

benzoyl chloride

56-81-5

glycerol

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 20℃; for 16h; Cooling with ice;	70%

110-86-1

pyridine

98-88-4

benzoyl chloride

56-81-5

glycerol

614-33-5

glyceryl tribenzoate

...Expand

98-88-4

benzoyl chloride

furan-2,3,5(4H)-trione pyridine (1:1)

100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

614-33-5

glyceryl tribenzoate

...Expand

96-11-7

1,2,3-tribromopropane

582-25-2

Potassium benzoate

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃;

119-53-9

2-hydroxy-2-phenylacetophenone

65-85-0

benzoic acid

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
at 250℃;

3376-59-8

2,3-dihydroxypropyl benzoate

98-88-4

benzoyl chloride

furan-2,3,5(4H)-trione pyridine (1:1)

614-33-5

glyceryl tribenzoate

...Expand

98-88-4

benzoyl chloride

furan-2,3,5(4H)-trione pyridine (1:1)

56-81-5

glycerol

614-33-5

glyceryl tribenzoate

...Expand

93-97-0

benzoic acid anhydride

56-81-5

glycerol

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃;
at 200℃;

96-11-7

1,2,3-tribromopropane

65-85-0

benzoic acid

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
at 200℃; bei der Einwirkung auf Kaliumbenzoat;

93-97-0

benzoic acid anhydride

106-89-8

epichlorohydrin

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
im geschlossenen Rohr;

3376-49-6

2-benzoyloxypropane-1,3-diol

98-88-4

benzoyl chloride

A

614-33-5

glyceryl tribenzoate

B

76999-62-7

2,3-bis-benzoyloxy-propan-1-ol

C

40593-13-3

benzoic acid 3-hexanoyloxy-2-hydroxypropyl ester

Conditions

Conditions	Yield
With (S)-1-methyl-2-((morpholin-1-yl)methyl)pyrrolidine; (methylcyclopentadienyl)tin(II) chloride 1.) CH2Cl2, 0 deg C, 30 min, 2.) CH2Cl2, 5 min, 3.) CH2Cl2, 0 deg C, 1h,; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

532-32-1

sodium benzoate

benzoic acid-<β.β'-dichloro-isopropyl>-ester

benzoic acid-<β.β'-dichloro-isopropyl>-ester

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
at 180 - 200℃;
at 180 - 200℃;

98-88-4

benzoyl chloride

disodium salt of glycerol

disodium salt of glycerol

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
With diethyl ether

10364-94-0

1-benzoylimidazole

56-81-5

glycerol

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran for 48h;

65-85-0

benzoic acid

614-33-5

glyceryl tribenzoate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: tetrahydrofuran / 2 h 2: triethylamine / tetrahydrofuran / 48 h View Scheme

67-56-1

methanol

614-33-5

glyceryl tribenzoate

93-58-3

benzoic acid methyl ester

Conditions

Conditions	Yield
With Merrifield resin-supported N3=P(MeNCH2CH2)3N at 23 - 25℃; for 0.2h; Inert atmosphere;	95%

614-33-5

glyceryl tribenzoate

7550-45-0

titanium tetrachloride

[{(TiCl4)2(glycerol tribenzoate)}2]

Conditions

Conditions	Yield
In hexane for 2h; Inert atmosphere; Schlenk technique;	75%

614-33-5

glyceryl tribenzoate

81-07-2

saccharin

C24H19NO7S

Conditions

Conditions	Yield
With scandium tris(trifluoromethanesulfonate) at 150℃; for 24h; Sealed tube;	75%

64-17-5

ethanol

614-33-5

glyceryl tribenzoate

141-52-6

sodium ethanolate

93-89-0

benzoic acid ethyl ester

...Expand

110-86-1

pyridine

614-33-5

glyceryl tribenzoate

141-52-6

sodium ethanolate

56-81-5

glycerol

A

glycerol monobenzoate

glycerol monobenzoate

B

glycerol dibenzoate

glycerol dibenzoate

...Expand

64-17-5

ethanol

614-33-5

glyceryl tribenzoate

alkali

alkali

A

76999-62-7

2,3-bis-benzoyloxy-propan-1-ol

B

119-53-9

2-hydroxy-2-phenylacetophenone

...Expand

64-17-5

ethanol

614-33-5

glyceryl tribenzoate

alkali

alkali

A

532-32-1

sodium benzoate

B

93-89-0

benzoic acid ethyl ester

C

56-81-5

glycerol

...Expand

614-33-5

glyceryl tribenzoate

18838-10-3

N-(2-hydroxyethyl)-benzamide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Merrifield resin-supported N3=P(MeNCH2CH2)3N / 0.2 h / 23 - 25 °C / Inert atmosphere 2: Merrifield resin-supported N3=P(MeNCH2CH2)3N / tetrahydrofuran / 23 - 25 °C / Inert atmosphere View Scheme

614-33-5

glyceryl tribenzoate

62-53-3

aniline

758640-21-0

N-Benzylaniline

Conditions

Conditions	Yield
With tris(2,4-pentanedionato)ruthenium(III); hydrogen; bis(trifluoromethanesulfonyl)amide; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In tetrahydrofuran at 130℃; under 45004.5 Torr; for 18h; Autoclave;	87 %Chromat.

GLYCERYL TRIBENZOATE Chemical Properties

Glycerol tribenzoate(614-33-5)'s molecular formula is C₂₄H₂₀O₆ and its formula weight is 404.41.
Glycerol tribenzoate(614-33-5) has a  melting point of  68-72 °C(lit.).
The molecular structure of glycerol tribenzoate(614-33-5):

GLYCERYL TRIBENZOATE Toxicity Data With Reference

GLYCERYL TRIBENZOATE Consensus Reports

GLYCERYL TRIBENZOATE Safety Profile