Product Name

  • Name

    HOMOPHTHALIC ANHYDRIDE

  • EINECS 211-873-4
  • CAS No. 703-59-3
  • Article Data40
  • CAS DataBase
  • Density 1.347 g/cm3
  • Solubility Decomposes in water.
  • Melting Point 140-142 °C(lit.)
  • Formula C9H6O3
  • Boiling Point 324.5 °C at 760 mmHg
  • Molecular Weight 162.145
  • Flash Point 159 °C
  • Transport Information
  • Appearance slightly yellow to beige or light green powder
  • Safety 26-36
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 703-59-3 (HOMOPHTHALIC ANHYDRIDE)
  • Hazard Symbols IrritantXi
  • Synonyms 1,3-Isochromandione(7CI);o-Toluic acid, a-carboxy-, cyclic anhydride (8CI);1H-Isochromene-1,3(4H)-dione;Benzeneacetic acid, 2-carboxy-, cyclic anhydride;Homophthalic acid anhydride;Homophthalic anhydride;NSC 2825;NSC 401693;
  • PSA 43.37000
  • LogP 0.92610

Homophthalic anhydride Chemical Properties

IUPAC Name: 4H-isochromene-1,3-dione 
Following is the structure of 1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3):
                            
Empirical Formula: C9H6O3
Molecular Weight: 162.1421 g/mol
Index of Refraction: 1.584
Molar Refractivity: 40.29 cm3
Molar Volume: 120.3 cm3
Density: 1.347 g/cm3
Flash Point: 159 °C
Sensitive: Moisture Sensitive
Surface Tension: 52 dyne/cm
Melting point: 140-142 °C(lit.)
Storage temp.: Refrigerator (+4°C)
Enthalpy of Vaporization: 56.66 kJ/mol
Boiling Point: 324.5 °C at 760 mmHg
Vapour Pressure of 1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3): 0.000244 mmHg at 25 °C
Appearance of 1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3): slightly yellow to beige or light green powder
Canonical SMILES: C1C2=CC=CC=C2C(=O)OC1=O
InChI: InChI=1S/C9H6O3/c10-8-5-6-3-1-2-4-7(6)9(11)12-8/h1-4H,5H2
InChIKey: AKHSBAVQPIRVAG-UHFFFAOYSA-N

Homophthalic anhydride Toxicity Data With Reference

1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. And the toxicological properties have not been fully investigated.

Homophthalic anhydride Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 3
F: 10-21

Homophthalic anhydride Specification

 1H-2-Benzopyran-1,3(4H)-dione , its cas register number is 703-59-3. It also can be called  Homophthalic anhydride ; and Benzoglutaric anhydride .
 1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3) is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water, and get medical aid immediately.
 1H-2-Benzopyran-1,3(4H)-dione (CAS NO.703-59-3) is moisture sensitive. It should avoid the condition like incompatible materials, exposure to moist air or water. It is not compatible with strong oxidizing agents, strong bases. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, carbon dioxide. However, its hazardous polymerization will not occur. In addition, it should keep refrigerated. (Store below 4°C/39°F.) And it should be stored in a tightly closed container, or stored in a dry area. And it should be kept under a nitrogen blanket.

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