L-xylo-2-Hexulosonicacid supplier

Name
L-xylo-hex-2-ulosonic acid
EINECS 208-403-5
CAS No. 526-98-7
Article Data44
CAS DataBase
Density 1.757g/cm³
Solubility 335.3g/L at 20℃
Melting Point 171 °C
Formula C₆H₁₀O₇
Boiling Point 550.6 °C at 760 mmHg
Molecular Weight 194.141
Flash Point 300.9 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Gulonicacid, 2-keto-, L- (6CI);L-xylo-Hexulosonic acid (7CI,8CI);Idonic acid,2-keto-, L- (6CI);2-Keto-L-gulonic acid;2-Keto-L-idonic acid;
PSA 135.29000
LogP -3.28490

Synthetic route

: 67-56-1
methanol

: 87-79-6
L-sorbose

: 142-71-2
copper diacetate

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Behandeln einer wss.Loesung des von Kupfer-Ionen befreiten Reaktionsprodukts mit Brom;

...Expand

: 87-79-6
L-sorbose

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With oxygen; Pt/Al2O3 at 50℃; under 750.06 Torr; for 2.86667h; other catalysts; var. reaction time;	39 % Chromat.
With hexamethylenetetramine; oxygen; platinum on activated charcoal In water at 50℃; under 750.06 Torr; Product distribution; Kinetics; var. of pH, base, catalyst;
With pyridine; oxygen; Pt/Al2O3 In water at 50℃; under 750.06 Torr; Rate constant; var. tertiary amines or tetraalkylammonium hydroxide, var. supports of Pt catalyst;

: 49865-02-3
L-sorbosone

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With water; bromine im diffusen Licht;

: 52507-87-6
O2,O3;O4,O6-dicyclohexylidene-α-L-xylo-[2]hexulofuranosonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With water
With water

: 6027-87-8
sodium gluconate

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With sodium chlorate; vanadia

: 50-70-4
D-sorbitol

A: 1114-17-6
L-idonic acid

B: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Gluconobacter melanogenus IFO 3293 mutant; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 50-70-4
D-sorbitol

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Gluconobacter melanogenus IFO 3293 mutant; Yield given;
Multi-step reaction with 3 steps 1: 31 percent 2: 46 percent / NaI, Ca(OH)2 / H2O / 1 h / 20 °C / anode - platinum, cathode - stainless steel 3: 0.1N aq. HCl / 1 h / 90 °C View Scheme

: 87-79-6
L-sorbose

A: 1114-17-6
L-idonic acid

B: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Gluconobacter melanogenus IFO 3293 mutant; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 136090-58-9
3,5,4,6-diethylidene-L-xylo-2-hexulosonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With hydrogenchloride at 90℃; for 1h;

: 2595-33-7
2,5-diketo-D-gluconic acid

A: 669-90-9
fructonic acid

B: 526-98-7
2-keto-L-gulonic acid

C: 13425-76-8
D-lyxo-hex-5-ulosonic acid

D: 5287-64-9
5-keto-D-gluconic acid

Conditions

Conditions	Yield
With Ru-TPPTS; sulfuric acid; hydrogen; sodium iodide In water at 27℃; under 7500.6 Torr; for 8h; Product distribution; other pH, temperature, reaction time, hydrogen pressure, catalyst amount;

...Expand

: 87-79-6
L-sorbose

: 7697-37-2
nitric acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield

: 87-79-6
L-sorbose

: 7664-93-9
sulfuric acid

: 7722-84-1
dihydrogen peroxide

: iron(II) sulfate

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield

...Expand

calcium salt of/the/ L-gulonic acid: calcium salt of/the/ L-gulonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With chromium(VI) oxide; iron(III) sulfate; water

calcium salt of/the/ L-idonic acid: calcium salt of/the/ L-idonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With chromium(VI) oxide; iron(III) sulfate; water
durch aerobe Oxidation mit Hilfe von Enzym-Praeparaten aus Pseudomonas fluorescens;

calcium salt of/the/ D-gluconic acid: calcium salt of/the/ D-gluconic acid

calcium salt of/the/ L-idonic acid: calcium salt of/the/ L-idonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
durch aerobe Oxidation mit Hilfe eines Enzym-Praeparats aus Pseudomonas fluorescens;
durch aerobe Oxidation mit Hilfe von Enzym-Praeparaten aus Pseudomonas chromo-spirans;

: 56-23-5
tetrachloromethane

: 87-79-6
L-sorbose

: 10544-72-6
dinitrogen tetraoxide

calcium sulfate: calcium sulfate

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Behandeln der Calcium-Salze der erhaltenen Saeuren mit Oxalsaeure in Wasser;

...Expand

O2,O3;O4,O6-diisopropylidene-α-L-xylo-<2>hexulofuranosonic acid-hydrate: O2,O3;O4,O6-diisopropylidene-α-L-xylo-<2>hexulofuranosonic acid-hydrate

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With water

: 87-79-6
L-sorbose

aqueous sodium hydrogencarbonate: aqueous sodium hydrogencarbonate

air: air

platinum/charcoal: platinum/charcoal

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
at 25℃; Schuetteln (16-72 h);

...Expand

: 87-79-6
L-sorbose

: 7732-18-5
water

oxygen: oxygen

platinum/charcoal: platinum/charcoal

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
at 4 - 80℃; pH (3.6-8.4);

...Expand

: 87-79-6
L-sorbose

: 7697-37-2
nitric acid

sodium nitrite: sodium nitrite

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield

...Expand

sodium-salt of/the/ L-gulonic acid: sodium-salt of/the/ L-gulonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With water; sodium acetate; acetic acid und Vanadium(V)-oxid und Natriumchlorat;

sodium-salt of/the/ L-idonic acid: sodium-salt of/the/ L-idonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With water; acetic acid; sodium bromide und Chrom(VI)-oxid bei der anodischen Oxidation;
With sodium chlorate; phosphoric acid; water anschl. mit Methanol und Vandium(V)-oxid;

: 87-79-6
L-sorbose

aqueous NaOH-solution: aqueous NaOH-solution

oxygen: oxygen

platinum/charcoal: platinum/charcoal

A: 7306-96-9
L-threonic acid

B: 526-98-7
2-keto-L-gulonic acid

C: 144-62-7
oxalic acid

Conditions

Conditions	Yield

...Expand

: 7270-77-1
L-sorbopyranose

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
With oxygen; sodium carbonate; hyper-cross-linked polystyrene-Pt-THF at 70℃; for 3.66667h; pH=5.9; Product distribution; Further Variations:; Temperatures; pH-values;

calcium-salt of/the/ L-idonic acid: calcium-salt of/the/ L-idonic acid

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
durch aerobe Oxidation mit Hilfe von Enzym-Praeparaten aus Pseudomonas-Arten sowie aus Acetobacter aerogenes;

: 50895-31-3
1,3:2,4-di-O-ethylidene-D-sorbitol

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 46 percent / NaI, Ca(OH)2 / H2O / 1 h / 20 °C / anode - platinum, cathode - stainless steel 2: 0.1N aq. HCl / 1 h / 90 °C View Scheme

: 5934-57-6
L-xylo-[2]hexosulose bis-phenylhydrazone

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: benzaldehyde; water; ethanol / Reagens: Essigsaeure 2: water; bromine / im diffusen Licht View Scheme

: 20880-90-4
O2,O3;O4,O6-dicyclohexylidene-α-L-sorbofuranose

: 526-98-7
2-keto-L-gulonic acid

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: pyridine; potassium hydroxide; potassium permanganate 2: water View Scheme

Reaxys ID: 11364755: Reaxys ID: 11364755

A: 526-98-7
2-keto-L-gulonic acid

B: 50-81-7
ascorbic acid

Conditions

Conditions	Yield
In Tri-n-octylamine; 8-methyl-1-nonanol; tri(n-decyl)amine; water at 30℃; Purification / work up;

: 186581-53-3, 908094-01-9
diazomethane

: 526-98-7
2-keto-L-gulonic acid

: 3031-98-9
L-xylo-[2]hexulosonic acid methyl ester

Conditions

Conditions	Yield
With methanol; diethyl ether at -10℃;

: 1117-96-0
Diazoethan

: 526-98-7
2-keto-L-gulonic acid

: 5965-56-0
L-xylo-[2]hexulosonic acid ethyl ester

Conditions

Conditions	Yield
With ethanol

: 67-56-1
methanol

: 526-98-7
2-keto-L-gulonic acid

: 3031-98-9
L-xylo-[2]hexulosonic acid methyl ester

Conditions

Conditions	Yield
With hydrogenchloride; trimethyl orthoformate
With hydrogenchloride; dimethylsulfite
With acidic cationen-exchanger
sulfuric acid at 65 - 66℃; under 760.051 Torr; for 2 - 2.5h;	90 - 97 %Chromat.

: 71-23-8
propan-1-ol

: 526-98-7
2-keto-L-gulonic acid

: 109848-63-7
L-xylo-[2]hexulosonic acid propyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

: 64-17-5
ethanol

: 526-98-7
2-keto-L-gulonic acid

: 5965-56-0
L-xylo-[2]hexulosonic acid ethyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

: 123-51-3
i-Amyl alcohol

: 526-98-7
2-keto-L-gulonic acid

: 110462-68-5
L-xylo-[2]hexulosonic acid isopentyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

: 526-98-7
2-keto-L-gulonic acid

: 78-83-1
2-methyl-propan-1-ol

: 113535-34-5
L-xylo-[2]hexulosonic acid isobutyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

: 526-98-7
2-keto-L-gulonic acid

: 50-81-7
ascorbic acid

Conditions

Conditions	Yield
With hydrogenchloride; water; butan-1-ol
With water at 100℃;
With hydrogenchloride; water

: 526-98-7
2-keto-L-gulonic acid

: 67-63-0
isopropyl alcohol

: 88669-03-8
L-xylo-[2]hexulosonic acid isopropyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

: 526-98-7
2-keto-L-gulonic acid

: 100-51-6
benzyl alcohol

: 98056-03-2
L-xylo-[2]hexulosonic acid benzyl ester

Conditions

Conditions	Yield
With cationen-exchanger at 130℃;

: 526-98-7
2-keto-L-gulonic acid

: 71-36-3
butan-1-ol

: 98055-99-3
L-xylo-[2]hexulosonic acid butyl ester

Conditions

Conditions	Yield
With acidic cationen-exchanger

L-xylo-2-Hexulosonicacid Specification

The L-xylo-2-Hexulosonicacid, with CAS registry number 526-98-7, has the systematic name of L-sorbosonic acid. Besides this, it is also called L-xylo-hex-2-ulosonic acid. And the chemical formula of this chemical is C₆H₁₀O₇. What's more, its EINECS is 208-403-5.

Physical properties of L-xylo-2-Hexulosonicacid: (1)ACD/LogP: -2.82; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -6.13; (4)ACD/LogD (pH 7.4): -6.56; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 7; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 9; (12)Polar Surface Area: 80.29 Å²; (13)Index of Refraction: 1.593; (14)Molar Refractivity: 37.45 cm³; (15)Molar Volume: 110.4 cm³; (16)Polarizability: 14.84×10^-24cm³; (17)Surface Tension: 108.7 dyne/cm; (18)Density: 1.757 g/cm³; (19)Flash Point: 300.9 °C; (20)Enthalpy of Vaporization: 95.49 kJ/mol; (21)Boiling Point: 550.6 °C at 760 mmHg; (22)Vapour Pressure: 2.04E-14 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O)C(=O)[C@@H](O)[C@H](O)[C@@H](O)CO
(2)InChI: InChI=1/C6H10O7/c7-1-2(8)3(9)4(10)5(11)6(12)13/h2-4,7-10H,1H2,(H,12,13)/t2-,3+,4-/m0/s1
(3)InChIKey: VBUYCZFBVCCYFD-NUNKFHFFBO
(4)Std. InChI: InChI=1S/C6H10O7/c7-1-2(8)3(9)4(10)5(11)6(12)13/h2-4,7-10H,1H2,(H,12,13)/t2-,3+,4-/m0/s1
(5)Std. InChIKey: VBUYCZFBVCCYFD-NUNKFHFFSA-N

Product Name

L-xylo-hex-2-ulosonic acid

Synthetic route

L-xylo-2-Hexulosonicacid Specification

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