Molecular Structure of Maneb-methylthiophanate mixture (CAS NO.13770-16-6):
IUPAC Name: manganese(2+); methyl N-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate; N-
[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
Empirical Formula: C16H20MnN6O4S6
Molecular Weight: 607.6958
Classification Code : Agricultural Chemical; Fungicide, bactericide, wood preservative
Synonyms of Maneb-methylthiophanate mixture (CAS NO.13770-16-6): Manganese, ((1,2-ethanediylbis(carbamodithioato))(2-))-, mixt. with dimethyl(1,2-phenylenebis(iminocarbonothioyl))bis(carbamate) ; BAS 36801F ; Caligran M ; Duosan ; Duosan (pesticide) ; Labilite ; Maneb-methylthiophanate mixt. ; Methylthiophanate-maneb mixt. ; Organil 644
1. | orl-rat LD50:10,200 mg/kg | FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1989,C114. | ||
2. | skn-rbt LD50:8 g/kg | FMCHA2 Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1989,C114. |
OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Mn)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JAN 1993 OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JAN 1993 OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JAN 1993 OEL-POLAND:TWA 0.3 mg(Mn)/m3 JAN 1993 OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust) JAN 1993 OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust) JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
Mildly toxic by ingestion and skin contact. When heated to decomposition it emits toxic fumes of NOx, SOx, and Mn.
OSHA PEL: CL 5 mg(Mn)/m3
ACGIH TLV: TWA 5 mg(Mn)/m3
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