Product Name

  • Name

    Methacrylonitrile

  • EINECS 204-817-5
  • CAS No. 126-98-7
  • Article Data111
  • CAS DataBase
  • Density 0.8
  • Solubility 2.57 g/100 mL (20 ºC) in water
  • Melting Point -35.8 ºC
  • Formula C4H5 N
  • Boiling Point 90-92 ºC
  • Molecular Weight 67.0904
  • Flash Point 12 ºC
  • Transport Information UN 3079
  • Appearance straw yellow crystal
  • Safety Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. An eye irritant. A dangerous fire hazard when exposed to heat, flame, or sparks. When heated to decomposition it emits toxic fumes of NOx and CN. See also NITRILES.
  • Risk Codes R11;R23/24/25;R43   
  • Molecular Structure Molecular Structure of 126-98-7 (Methacrylonitrile)
  • Hazard Symbols
  • Synonyms Methacrylonitrile(8CI); 1-Methylethenyl cyanide; 2-Cyano-1-propene; 2-Cyanopropene;2-Methyl-2-propenenitrile; 2-Methylacrylonitrile; 2-Methylpropenenitrile;Isobutenenitrile; Isopropene cyanide; Isopropenylnitrile; Methacrylnitrile;Methylacrylonitrile; NSC 24145; a-Methacrylonitrile; a-Methylacrylonitrile
  • PSA 23.79000
  • LogP 1.08608

Methacrylonitrile Chemical Properties

Chemical Name: Methacrylonitrile
IUPAC NAME: 2-Methylprop-2-enenitrile
CAS No.: 126-98-7
EINECS: 204-817-5
RTECS: UD1400000
Molecular Formula: C4H5N
Molecular Weight: 67.09 g/mol
Melting Point: −35.8 °C(lit.)
Density: 0.809 g/cm3 
Flash Point: 12.2 °C
Boiling Point: 90.3 °C at 760 mmHg 
Following is the structure of Methylacrylonitrile (126-98-7):


Product Categories about are Alpha sort ;  MAlphabetic ; META - METH ; Volatiles/ semivolatiles ; Acrylic monomers ; Acrylonitrile ; Monomers
The chemical synonymous of Methylacrylonitrile (126-98-7) are 2-Methyl-2-propenenitrile ; 2-Methacrylonitrile ; Alpha-methylacrylic acid nitrile ; Alpha-methylacrylonitrile ; Methacrylic acid nitrile ; Methacrylonitrile ; Isopropenyl cyanide ; 1-Methyl-1-cyanoethylene

Methacrylonitrile Uses

 Methylacrylonitrile (126-98-7) is an important raw material of organic synthetic,it makes methyl methacrylate by hydrolysis, esterification availability, and itself can be aggregated into a polymer material.

Methacrylonitrile Toxicity Data With Reference

1.    

eye-rbt 500 mg/24H MLD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,901.
2.    

orl-rat LD50:120 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 29 (5)(1985),37.
3.    

orl-rbt LD50:16 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 29 (5)(1985),37.
4.    

ihl-rat LC50:328 ppm/4H

    AIHAAP    American Industrial Hygiene Association Journal. 29 (1968),202.
5.    

orl-mus LDLo:15 mg/kg

    SCCUR*    Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
6.    

ihl-mus LC50:36 ppm/4H

    AIHAAP    American Industrial Hygiene Association Journal. 29 (1968),202.
7.    

ipr-mus LDLo:15 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 31 (1949),113.
8.    

ihl-rbt LC50:37 ppm/4H

    AIHAAP    American Industrial Hygiene Association Journal. 29 (1968),202.
9.    

skn-rbt LD50:320 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 29 (1968),202.
     

 

Methacrylonitrile Consensus Reports

EPA Extremely Hazardous Substances List. Cyanide and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Methacrylonitrile Safety Profile

Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. An eye irritant. A dangerous fire hazard when exposed to heat, flame, or sparks. When heated to decomposition it emits toxic fumes of NOx and CN. See also NITRILES.
Hazard Codes:
F: Flammable
T: Toxic
Risk Statements about Methylacrylonitrile (126-98-7):
R11 Highly flammable.
R43 May cause sensitization by skin contact.
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. 
Safety Statements about Methylacrylonitrile (126-98-7):
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition.
S18 Handle and open container with care.
S29 Do not empty into drains.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

Methacrylonitrile Standards and Recommendations

OSHA PEL: TWA 1 ppm (skin)
ACGIH TLV: TWA 1 ppm (skin)
DOT Classification:  3; Label: Flammable Liquid, Poison

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