N-[3-(Trimethoxysilyl)propyl]ethylenediamine supplier

Name
N-[3-(Trimethoxysilyl)propyl]ethylenediamine
EINECS 217-164-6
CAS No. 1760-24-3
Article Data17
CAS DataBase
Density 0.975 g/cm³
Solubility reacts with water
Melting Point 0ºC
Formula C₈H₂₂N₂O₃Si
Boiling Point 272.2 ºC at 760 mmHg
Molecular Weight 222.36
Flash Point 108.1 ºC
Transport Information UN 3267 8/PG 2
Appearance colorless transparent liquid
Safety 26-39-61-37/39-24-36/37/39-23
Risk Codes 38-41-43-52/53-42/43-37/38
Molecular Structure
Hazard Symbols Xn,Xi
Synonyms 1,2-Ethanediamine,N-[3-(trimethoxysilyl)propyl]- (9CI);(2-Aminoethyl)(3-(trimethoxysilyl)propyl)amine;DynasylanDAMO-T;Geniosil GF 9;N-(Aminoethyl)aminopropyltrimethoxysilane;N-b-Aminoethyl-g-aminopropyyltrimethoxysilane;Prosil 3128;SilaneA 0700;en-APTAS;g-(Ethylenediamino)propyltrimethoxysilane;N-(β-aminoethyl)-γ-aminopropyl]trimethoxysilane;[3-(2-Aminoethyl)Aminopropyl]Trimethoxysilane;
PSA 65.74000
LogP 0.89410

Synthetic route

: 107-15-3
ethylenediamine

: 2530-87-2
3-Chloropropyltrimethoxysilan

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
Heating;	90%

: 2530-87-2
3-Chloropropyltrimethoxysilan

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
In ethylenediamine	70.1%

: 67-56-1
methanol

: C11H28N2O4Si

A: 110-80-5
2-ethoxy-ethanol

B: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

Conditions

Conditions	Yield
at 20℃; Kinetics; Equilibrium constant; Further Variations:; Temperatures;

...Expand

: 103-72-0
phenyl isothiocyanate

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C22H32N4O3S2Si

Conditions

Conditions	Yield
In ethanol for 0.25h; Heating;	100%

: 19494-73-6
1-[(2-oxazepan-1-yl)carbonyl]azepan-2-one

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

A: 105-60-2
caprolactam

B: C15H31N3O5Si

Conditions

Conditions	Yield
In toluene at 75℃; for 3h;	A n/a B 100%

...Expand

: 30674-80-7
2-Isocyanatoethyl methacrylate

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 4,9-dioxo-5-(3-(trimethoxysilyl)propyl)-3,5,8,10-tetraazadodecane-1,12-diyl bis(2-methylacrylate)

Conditions

Conditions	Yield
at 55℃;	100%

: 75-15-0
carbon disulfide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C10H20N2O3S4Si(2-)*2Li(1+)

Conditions

Conditions	Yield
With lithium hydride In tetrahydrofuran for 2h; Heating;	99%

: 2680-03-7
N,N-Dimethylacrylamide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C13H31N3O4Si

Conditions

Conditions	Yield
at 70 - 100℃; for 8.5h;	98%

: 4637-24-5
N,N-dimethyl-formamide dimethyl acetal

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1-[3-(trimethoxysilyl)propyl]-4,5-dihydro-1H-imidazole

Conditions

Conditions	Yield
In toluene at 80℃; for 24h;	98%

: 108-31-6
maleic anhydride

: 5333-84-6
3-methyl-Δ4-tetrahydrophthalic anhydride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C17H32N2O6Si

Conditions

Conditions	Yield
In ethyl acetate at 50 - 60℃;	97%

...Expand

: 108-31-6
maleic anhydride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: (E)3-{N-[3-(trimethoxysilyl)propylammonioethyl]carbamoyl}propenoate

Conditions

Conditions	Yield
In ethyl acetate at 50 - 60℃;	97%

: 85-44-9
phthalic anhydride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C16H26N2O6Si

Conditions

Conditions	Yield
In ethyl acetate at 50 - 60℃;	97%

: 75-15-0
carbon disulfide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C10H20N2O3S4Si(2-)*2Na(1+)

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran for 2h; Heating;	96%

: 1066-40-6
Trimethylsilanol

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 199327-09-8
1-[3-N-(2-aminoethyl)aminopropyl]-1,1-dimethoxy-3,3,3-trimethyldisiloxane

Conditions

Conditions	Yield
at 20℃;	95.5%

: 75-15-0
carbon disulfide

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C10H20N2O3S4Si(2-)*2K(1+)

Conditions

Conditions	Yield
With potassium hydride In tetrahydrofuran for 2h; Heating;	95%

: {Bu2Sn(diethylmalonato)}x

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: {Bu2Sn(diethylmalonato)(γ-((aminoethyl)amino)propyl)trimethoxysilane}x

Conditions

Conditions	Yield
In dichloromethane dissolved together in dry CH2Cl2; evapn. in vac., oil crystd. after standing at 25°C for several days, recrystn. from CH2Cl2 at -30°C; elem. anal.;	95%

: 98474-79-4
toluene diisocyanate trimer

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C35H40N8O9Si

Conditions

Conditions	Yield
With dibutyltin dilaurate In tetrahydrofuran at 20℃; for 5h; Dry environment;	95%

: 622-25-3
1-(2-chlorovinyl)benzene

: 64-19-7
acetic acid

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

N'-aminoethyl-N-vinylbenzyl-N-aminopropylpolysiloxane hydroacetate: N'-aminoethyl-N-vinylbenzyl-N-aminopropylpolysiloxane hydroacetate

Conditions

Conditions	Yield
Stage #1: [1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane With water In methanol for 1h; Stage #2: 1-(2-chlorovinyl)benzene at 50 - 64℃; for 3h; Stage #3: acetic acid With 2,6-di-tert-butyl-4-methyl-phenol; sodium methylate more than 3 stages;	94%
Stage #1: [1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane With water In methanol for 1h; Stage #2: 1-(2-chlorovinyl)benzene at 50 - 64℃; for 3h; Stage #3: acetic acid With 4-tert-Butylcatechol; sodium methylate more than 3 stages;	88%

...Expand

: 1066-40-6
Trimethylsilanol

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 3-[3-N-(2-aminoethyl)aminopropyl]-3-methoxy-1,1,1,5,5,5-hexamethyltrisiloxane

Conditions

Conditions	Yield
Heating;	92.5%

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 112-67-4
n-hexadecanoyl chloride

: [2-(N-hexadecanoylamino)ethyl]-[3-(trimethoxysilyl)propyl]ammonium chloride

Conditions

Conditions	Yield
In dichloromethane Cooling with ice;	92%

: 4435-57-8
bis(2-hydroxyethyl)(2-hydroxybutyl)amine

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1[N-(2-aminoethyl)aminopropyl]-3-ethylsilatrane

Conditions

Conditions	Yield
With potassium hydroxide In toluene for 3h; Heating;	91.8%

: 814-68-6
acryloyl chloride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: N-acryloyl-N-(2-(N-(3-(trimethoxysilyl)propyl)acrylamido)ethyl)acrylamide

Conditions

Conditions	Yield
Stage #1: [1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane With trimethylamine In dichloromethane for 0.166667h; Cooling with ice; Inert atmosphere; Stage #2: acryloyl chloride In dichloromethane at 20℃; for 8h; Cooling with ice; Inert atmosphere;	91.8%

: 141-43-5
ethanolamine

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1134640-03-1
C11H31N5O3Si

Conditions

Conditions	Yield
Heating;	91.3%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 255390-98-8, 237428-36-3
Rh(C8H12)(1+)*NH2(CH2)2NH(CH2)3Si(OCH3)3*Cl(1-)=Rh(C8H12)[NH2(CH2)2NH(CH2)3Si(OCH3)3]Cl

Conditions

Conditions	Yield
In dichloromethane (N2); stirring (room temp., 1 h); washing (hexane), dryig (vac.); elem. anal.;	91%

: 112-16-3
n-dodecanoyl chloride

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: [2-(N-dodecanoylamino)ethyl]-[3-(trimethoxysilyl)propyl]ammonium chloride

Conditions

Conditions	Yield
In dichloromethane Cooling with ice;	90%

: 672-13-9
2-hydroxy-5-methoxybenzaldehyde

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1293408-57-7
N-[N-(3-(trimethoxysilyl)propyl)ethylenediamine]-5-methoxysalicylaldimine

Conditions

Conditions	Yield
With formic acid In ethanol for 6h; Reflux;	88%

: 51980-54-2
4-(pyrrolidin-1-yl)benzaldehyde

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: ((4-pyrrolidin-1-yl)benzylidene)-3-(trimethoxysilyl)propylethane-1,2-diamine

Conditions

Conditions	Yield
In toluene for 4h; Inert atmosphere; Reflux;	87%

: 824-42-0
2-methoxy-3-methylbenzaldehyde

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1293408-54-4
N-[N-(3-(trimethoxysilyl)propyl)ethylenediamine]-3-methylsalicylaldimine

Conditions

Conditions	Yield
With formic acid In ethanol for 6h; Reflux;	85%

: ruthenium(II) bis(triphenylphosphine) dichloride

: 75-09-2
dichloromethane

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: C44H52Cl2N2O3P2RuSi*CH2Cl2

Conditions

Conditions	Yield
Stage #1: ruthenium(II) bis(triphenylphosphine) dichloride; [1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane In tetrahydrofuran for 4h; Reflux; Inert atmosphere; Schlenk technique; Stage #2: dichloromethane In hexane	85%

...Expand

: 1204-86-0
4-(4-morpholinyl)benzaldehyde

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: (4-morpholinobenzylidene)-3-(trimethoxysilyl)propylethane-1,2-diamine

Conditions

Conditions	Yield
In toluene for 4h; Inert atmosphere; Reflux;	85%

: 1430399-27-1
4′-[(4-formylphenoxy)methyl]biphenyl-2-carbonitrile

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 4'-((4-((1E)-9,9-dimethoxy-10-oxa-2,5-diaza-9-silaundec-1-en-1-yl)phenoxy)methyl)[1,1'-biphenyl]-2-carbonitrile

Conditions

Conditions	Yield
In toluene Inert atmosphere; Schlenk technique; Dean-Stark; Reflux;	85%

: 613-84-3
2-hydroxy-5-methylbenzaldehyde

: 1760-24-3
[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

: 1293408-56-6
N-[N-(3-(trimethoxysilyl)propyl)ethylenediamine]-5-methylsalicylaldimine

Conditions

Conditions	Yield
With formic acid In ethanol for 6h; Reflux;	84%

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Chemical Properties

IUPAC Name: N-(3-Trimethoxysilylpropyl)ethane-1,2-diamine
Molecular Formula: C₈H₂₂N₂O₃Si
Molecular Weight: 222.36 g/mol
SMILES: [Si](CCCNCCN)(OC)(OC)OC
InChI: InChI=1/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
EINECS: 217-164-6
Classification Code: Skin / Eye Irritant
Product Categories: Amino; Amino Silanes (Silane Coupling agents); Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Si-O Compounds; Trialkoxysilanes; Adhesion Promoters; Amino Silanes; Coupling Agents; Dispersing Agents; Surface Modifiers; Silane series
Water Solubility: REACTS
Sensitive: Air & Moisture Sensitive
Index of Refraction: 1.441
Molar Refractivity: 60.19 cm³
Molar Volume: 227.9 cm³
Polarizability: 23.86×10^-24 cm³
Surface Tension: 28.2 dyne/cm
Density: 0.975 g/cm³
Flash Point: 108.1 °C
Enthalpy of Vaporization: 51.05 kJ/mol
Boiling Point: 272.2 °C at 760 mmHg
Vapour Pressure of Z 6020 (CAS NO.1760-24-3): 0.00616 mmHg at 25 °C

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	intravenous	180mg/kg (180mg/kg)	U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03517,
rabbit	LDLo	skin	16mL/kg (16mL/kg)	Union Carbide Data Sheet. Vol. 4/2/1971,
rat	LD50	oral	7460uL/kg (7.46mL/kg)	Union Carbide Data Sheet. Vol. 4/2/1971,

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Consensus Reports

Reported in EPA TSCA Inventory.

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Safety Profile

Poison by intravenous route. Mildly toxic by ingestion and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Hazard Codes: Harmful Xn,Xi
Risk Statements: 38-41-43-52/53-42/43-37/38
R38:Irritating to skin.
R41:Risk of serious damage to the eyes.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R42/43:May cause sensitization by inhalation and skin contact.
R37/38:Irritating to respiratory system and skin.
Safety Statements: 26-39-61-37/39-24-36/37/39-23
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S37/39:Wear suitable gloves and eye/face protection.
S24:Avoid contact with skin.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S23:Do not breathe vapour.
RIDADR: UN 3267 8/PG 2
WGK Germany: 3
RTECS: KV7400000
F: 1-10
TSCA: Yes
HazardClass: 8
PackingGroup of Z 6020 (CAS NO.1760-24-3): III

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Specification

Z 6020 (CAS NO.1760-24-3), its Synonyms are AAS-M ; AP 132 ; Dow corning Z-6020 silane ; N-(3-Trimethoxysilylpropyl)-ethylenediamine ; 1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)- ; 1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)- ; Ethylenediamine, N-(3-(trimethoxysilyl)propyl)- ; N-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamine ; Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy- . It is colorless transparent liquid.

Product Name

N-[3-(Trimethoxysilyl)propyl]ethylenediamine

Synthetic route

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Chemical Properties

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Toxicity Data With Reference

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Consensus Reports

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Safety Profile

N-[3-(Trimethoxysilyl)propyl]ethylenediamine Specification

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