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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1

Negotiable

Type:Other

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

img _fcksavedurl="/UserAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:It is an important raw material and intermediate used in Organic Synthesis, Phar

Hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Trimethylsilanol

Cas:1066-40-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 1066-40-6 with competitive price

Cas:1066-40-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

hydroxytrimethylsilane CAS:1066-40-6

Cas:1066-40-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Silanol,1,1,1-trimethyl- 1066-40-6

Cas:1066-40-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Syntheses Material Intermediate, hydroxytrimethylsilane CAS: 1066-40-6

Cas:1066-40-6

Min.Order:1 Kilogram

FOB Price: $81.0 / 89.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

hydroxytrimethylsilane CAS:1066-40-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

hydroxytrimethylsilane CAS:1066-40-6

Cas:1066-40-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Silanol,1,1,1-trimethyl-

Cas:1066-40-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Silanol,1,1,1-trimethyl-

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Trimethyl-Silanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Trimethyl-Silanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

hydroxytrimethylsilane Basic information Product Name: hydroxytrimethylsilane Synonyms: Silanol,1,1,1-triMethyl-;TriMethylsilanol >=98.0% (GC);Trimethylsilanol >=97.5% (GC);Medetomidine Impurity 17;hydroxytrimethylsilane;Trimethylsilanol

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in

SAGECHEM/ Hydroxytrimethylsilane /Manufacturer in China

Cas:1066-40-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Trimethylsilanol cas no. 1066-40-6 98%

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

TriMethylsilanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Trimethylsilanol 100g

Cas:1066-40-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Trimethyl-Silanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as: Frac

Trimethylsilanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

hydroxytrimethylsilane

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Nanjing HuaNuo Bio-Pharmacuetical Co.,Ltd

Independent research and development of impurities, familiar with the market and impurity characteristics; We can ship out on the same day if the products are in stock; Focus on impurity development of new products in the market; Expert in customizi

Trimethylsilanol

Cas:1066-40-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-n-butyl-1-trimethylsilylbenzene
81631-74-5

4-n-butyl-1-trimethylsilylbenzene

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

1-butylbenzene
104-51-8

1-butylbenzene

Conditions
ConditionsYield
With Montmorillonite KSF In water at 20℃;A n/a
B 99%
trimethylsilyl-2-hydroxypropane
121386-65-0, 145428-84-8, 145428-85-9

trimethylsilyl-2-hydroxypropane

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

propene
187737-37-7

propene

C

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With hydrogenchloride In methanol at 40℃; Rate constant; var. +>;A n/a
B 98%
C n/a
N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

Conditions
ConditionsYield
With nitrosonium tetrafluoroborate In dichloromethane Ambient temperature;A n/a
B 98%
benzyloxy-trimethylsilane
14642-79-6

benzyloxy-trimethylsilane

Trimethylsilanol
1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline In N,N-dimethyl acetamide at 20℃; for 2h;97%
N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

benzene diazonium chloride
100-34-5

benzene diazonium chloride

Conditions
ConditionsYield
With nitrosylchloride In dichloromethane for 0.166667h; Ambient temperature;A n/a
B 96%
N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

benzenediazonium bromide
71290-63-6

benzenediazonium bromide

Conditions
ConditionsYield
With nitrosyl bromide In dichloromethane for 0.166667h; Ambient temperature;A n/a
B 94%
N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

nitrosonium trifluoromethanesulfonate
14848-27-2

nitrosonium trifluoromethanesulfonate

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

benzenediazonium trifluoromethanesulfonate
90756-34-6

benzenediazonium trifluoromethanesulfonate

Conditions
ConditionsYield
In dichloromethane Ambient temperature;A n/a
B 93%
0.5C4H10O2*C6H18NSi2(1-)*2Cl(1-)*Pr(3+)

0.5C4H10O2*C6H18NSi2(1-)*2Cl(1-)*Pr(3+)

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

praseodymium(III) hydroxide

praseodymium(III) hydroxide

C

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With water In hexane deaerated water addn. to Pr-compd. soln., soln. decanting from ppt.; GLC, IR spectroscopy;A <1
B 92.3%
C 73.8%
1,1,1,2,2,2-hexamethyldisilane
1450-14-2

1,1,1,2,2,2-hexamethyldisilane

10-methylacridinium perchlorate
26456-05-3

10-methylacridinium perchlorate

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

9,10-dihydro-10-methylacridine
4217-54-3

9,10-dihydro-10-methylacridine

Conditions
ConditionsYield
With water In [D3]acetonitrile; acetonitrile for 4h; Irradiation;A n/a
B 88%
carbon monoxide
201230-82-2

carbon monoxide

1-Phenyl-2-(trimethylsilyl)acetylene
2170-06-1

1-Phenyl-2-(trimethylsilyl)acetylene

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

inden-1-one
83-33-0

inden-1-one

Conditions
ConditionsYield
With water; triethylamine; triphenylphosphine; chloro(1,5-cyclooctadiene)rhodium(I) dimer In tetrahydrofuran at 160℃; under 51485.6 Torr; for 4h; Product distribution; other phosphine ligand, other rhodium complex, other temp., other additives, other solv.;A n/a
B 86%
bis-1,3-trimethylsilyl-2-hydroxypropane
17887-33-1

bis-1,3-trimethylsilyl-2-hydroxypropane

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

propene
187737-37-7

propene

C

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

D

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

Conditions
ConditionsYield
With hydrogenchloride In methanol at 40℃; Rate constant; var. +>;A n/a
B 85%
C n/a
D n/a
4-Nitro-N-(trimethylsilyl)anilin
63911-89-7

4-Nitro-N-(trimethylsilyl)anilin

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

trimethyl(isopentyloxy)silane
18246-56-5

trimethyl(isopentyloxy)silane

C

4-nitrobenzenediazonium chloride
100-05-0

4-nitrobenzenediazonium chloride

Conditions
ConditionsYield
With chloro-trimethyl-silane; isopentyl nitrite In dichloromethane for 10h; Ambient temperature;A n/a
B n/a
C 82%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Trimethylsilanol
1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
With water; ammonium carbonate; sodium chloride In diethyl ether78%
With NaOH In diethyl ether; water fast addn. of (CH3)3SiCl to a 0.25N aq. NaOH-soln. in presence of a large amt. of ether at 0°C;;35%
With 1,4-dioxane; acridine at 25℃; Rate constant;
With ammonia In water; acetone Product distribution; various chloroorganosilanes under different reaction conditions;
With water In diethyl ether
trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

Trimethylsilanol
1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
With NaOH In diethyl ether; water addn. of aq. NaOH to a cooled soln. of (CH3)3SiF in ether under vigorous stirring (neutral soln.);; drying of the ether phase; evapn. of ether; distn. of the residue;;70%
With NaOH In diethyl ether; water addn. of aq. NaOH to a cooled soln. of (CH3)3SiF in ether under vigorous stirring (neutral soln.);; drying of the ether phase; evapn. of ether; distn. of the residue;;70%
With sodium hydroxide; diethyl ether
With sodium hydroxide In diethyl ether Yield given;
methyltrimethicone
17928-28-8

methyltrimethicone

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

C

methyltrifluorosilane
373-74-0

methyltrifluorosilane

D

1,1-difluorotetramethyldisiloxane
56998-71-1

1,1-difluorotetramethyldisiloxane

E

3-fluoroheptamethyltrisiloxane
24291-15-4

3-fluoroheptamethyltrisiloxane

Conditions
ConditionsYield
With NaHF2 at 190℃; for 0.0333333h; Product distribution;A 0.3%
B 62.9%
C 18.1%
D 1.5%
E 2.5%
diphenyl hydrogen phosphate
838-85-7

diphenyl hydrogen phosphate

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

diphenyl (1H-imidazol-1-yl)phosphonate
66778-06-1

diphenyl (1H-imidazol-1-yl)phosphonate

Conditions
ConditionsYield
In tetrahydrofuran for 8h; Reflux;A n/a
B 50%
(N-phenyliminovinylidene)triphenylphosphorane
64448-06-2, 21385-80-8

(N-phenyliminovinylidene)triphenylphosphorane

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

N-[1-(1H-imidazol-1-yl)-2-(triphenylphosphoranylidene)ethylidene]aniline

N-[1-(1H-imidazol-1-yl)-2-(triphenylphosphoranylidene)ethylidene]aniline

Conditions
ConditionsYield
In tetrahydrofuran for 5h; Reflux;A n/a
B 35%
Bestmann ylide
73818-55-0, 15596-07-3

Bestmann ylide

1-(Trimethylsilyl)imidazole
18156-74-6

1-(Trimethylsilyl)imidazole

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

2-triphenyl(α-carboxymethylene)phosphorane imidazolide
73818-41-4

2-triphenyl(α-carboxymethylene)phosphorane imidazolide

Conditions
ConditionsYield
In tetrahydrofuran for 6h; Reflux;A n/a
B 30%
diethyl ether
60-29-7

diethyl ether

bis(trimethylsilyl)sulphate
18306-29-1

bis(trimethylsilyl)sulphate

1-methyl-4-nitrosobenzene
623-11-0

1-methyl-4-nitrosobenzene

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Trimethylsilanol
1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
With hydrogenchloride
With hydrogenchloride; dibutyl ether
With hydrogenchloride
tetrakis-O-trimethylsilanyl-ξ-D-glucopyranuronic acid

tetrakis-O-trimethylsilanyl-ξ-D-glucopyranuronic acid

Trimethylsilanol
1066-40-6

Trimethylsilanol

Conditions
ConditionsYield
Zersetzung;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

N-(4-chlorobenzylidene)aniline
780-21-2

N-(4-chlorobenzylidene)aniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

4-chloro-aniline
106-47-8

4-chloro-aniline

C

2-[(E)-2-phenylethenyl]pyridine
538-49-8

2-[(E)-2-phenylethenyl]pyridine

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

(E)-N-(2-pyridylmethylene)aniline
7032-25-9, 40468-86-8, 88785-71-1

(E)-N-(2-pyridylmethylene)aniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

aniline
62-53-3

aniline

C

(E)-1,2-bis(2-pyridyl)ethene
13341-40-7

(E)-1,2-bis(2-pyridyl)ethene

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

N-(1-phenylethylidene)aniline
1749-19-5

N-(1-phenylethylidene)aniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

(E)-2-(2-phenylprop-1-en-1-yl)pyridine
70525-38-1

(E)-2-(2-phenylprop-1-en-1-yl)pyridine

C

2-(2-phenylprop-1-en-1-yl)pyridine
70525-39-2

2-(2-phenylprop-1-en-1-yl)pyridine

D

aniline
62-53-3

aniline

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction. Yields of byproduct given;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

(E)-N-cinnamylideneaniline
64859-04-7

(E)-N-cinnamylideneaniline

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

1-phenyl-4-(2-pyridyl)-1,3-butadiene
1466-20-2, 4625-23-4, 5519-95-9, 17105-02-1

1-phenyl-4-(2-pyridyl)-1,3-butadiene

C

aniline
62-53-3

aniline

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THJF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

A

(Z)-2-(2-phenylethenyl)pyridine
538-49-8, 714-08-9, 1519-59-1

(Z)-2-(2-phenylethenyl)pyridine

B

Trimethylsilanol
1066-40-6

Trimethylsilanol

C

methylamine
74-89-5

methylamine

D

2-[(E)-2-phenylethenyl]pyridine
538-49-8

2-[(E)-2-phenylethenyl]pyridine

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction. Yields of byproduct given;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

A

(Z)-2-(2-phenylethenyl)pyridine
538-49-8, 714-08-9, 1519-59-1

(Z)-2-(2-phenylethenyl)pyridine

B

Trimethylsilanol
1066-40-6

Trimethylsilanol

C

aniline
62-53-3

aniline

D

2-[(E)-2-phenylethenyl]pyridine
538-49-8

2-[(E)-2-phenylethenyl]pyridine

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction. Yields of byproduct given;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

aniline
62-53-3

aniline

C

2-[(E)-2-phenylethenyl]pyridine
538-49-8

2-[(E)-2-phenylethenyl]pyridine

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction;
(2-picolyl)trimethylsilane
17881-80-0

(2-picolyl)trimethylsilane

(E)-N-benzylidene-2-methylpropan-2-amine
6852-58-0

(E)-N-benzylidene-2-methylpropan-2-amine

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

tert-butylamine
75-64-9

tert-butylamine

C

2-[(E)-2-phenylethenyl]pyridine
538-49-8

2-[(E)-2-phenylethenyl]pyridine

Conditions
ConditionsYield
With ammonium chloride; lithium diisopropyl amide 1.) THF, -75 deg C 2.) -75 deg C, 1 h and room temp. 2 h; Yield given. Multistep reaction;
1-styrenyloxytrimethylsilane
13735-81-4

1-styrenyloxytrimethylsilane

A

Trimethylsilanol
1066-40-6

Trimethylsilanol

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With sodium hydroxide; formic acid; water; sodium chloride In acetonitrile at 25℃; Rate constant; Mechanism;
Trimethylsilanol
1066-40-6

Trimethylsilanol

trimethylsilylazide
4648-54-8

trimethylsilylazide

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

Conditions
ConditionsYield
With C31H26F6N4O2 In Hexafluorobenzene for 3h;100%
Trimethylsilanol
1066-40-6

Trimethylsilanol

phenylsilane
694-53-1

phenylsilane

1,1,1,5,5,5-hexamethyl-3-phenyl-trisiloxane
27991-58-8

1,1,1,5,5,5-hexamethyl-3-phenyl-trisiloxane

Conditions
ConditionsYield
With C40H36FeN2P2 In tetrahydrofuran at 20℃; for 12h; Reagent/catalyst; Solvent;99%
With [FeCl2(2,9-bis((diphenylphosphino)methyl)-1,10-phenanthroline)]; sodium triethylborohydride In tetrahydrofuran at 20℃; for 12h; Catalytic behavior; Inert atmosphere; Schlenk technique; Glovebox;> 99 %Spectr.
Trimethylsilanol
1066-40-6

Trimethylsilanol

iron(II) bis(trimethylsilyl)amide
14760-22-6

iron(II) bis(trimethylsilyl)amide

iron(II) trimethylsiloxide

iron(II) trimethylsiloxide

Conditions
ConditionsYield
In hexane byproducts: (Me3Si)2NH; (Ar); addn. of soln. of Me3SiOH (2 equiv.) in hexane to soln. of ((Me3Si)2N)2Fe (1 equiv.) in hexane; pptn., filtration, washing with hexane, removal of solvent in vac. at 50°C, elem. anal.;98%
Trimethylsilanol
1066-40-6

Trimethylsilanol

2-phenylheptamethyltrisilane
780-55-2

2-phenylheptamethyltrisilane

A

1,1,1,3-tetramethyl-3-phenyldisiloxane
69552-69-8

1,1,1,3-tetramethyl-3-phenyldisiloxane

B

3-phenyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
546-44-1

3-phenyl-1,1,1,3,5,5,5-heptamethyltrisiloxane

Conditions
ConditionsYield
Mechanism; Irradiation; other silanes;A 96%
B 4%
Trimethylsilanol
1066-40-6

Trimethylsilanol

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane
1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

1-[3-N-(2-aminoethyl)aminopropyl]-1,1-dimethoxy-3,3,3-trimethyldisiloxane
199327-09-8

1-[3-N-(2-aminoethyl)aminopropyl]-1,1-dimethoxy-3,3,3-trimethyldisiloxane

Conditions
ConditionsYield
at 20℃;95.5%
Trimethylsilanol
1066-40-6

Trimethylsilanol

di[methyl(methoxo)(trimethylphosphine)nickel]

di[methyl(methoxo)(trimethylphosphine)nickel]

(CH3Ni(P(CH3)3)OSi(CH3)3)2

(CH3Ni(P(CH3)3)OSi(CH3)3)2

Conditions
ConditionsYield
In pentane95%
Trimethylsilanol
1066-40-6

Trimethylsilanol

1,5-diacetoxy-3,3,7,7,10,10-hexaphenylbicyclo[3.3.3]-1,3,5,7,9-pentasiloxane

1,5-diacetoxy-3,3,7,7,10,10-hexaphenylbicyclo[3.3.3]-1,3,5,7,9-pentasiloxane

C42H48O8Si7

C42H48O8Si7

Conditions
ConditionsYield
With pyridine In toluene at 25℃; for 24h;95%
Trimethylsilanol
1066-40-6

Trimethylsilanol

diphenylsilane
775-12-2

diphenylsilane

1,1,1-trimethyl-3,3-diphenyldisiloxane

1,1,1-trimethyl-3,3-diphenyldisiloxane

Conditions
ConditionsYield
With chlorobis(cyclooctene)-iridium(I) dimer In toluene at 20℃; for 3h; Inert atmosphere;94%
With [FeCl2(2,9-bis((diphenylphosphino)methyl)-1,10-phenanthroline)]; sodium triethylborohydride In tetrahydrofuran at 20℃; for 12h; Catalytic behavior; Inert atmosphere; Schlenk technique; Glovebox;77 %Spectr.
Trimethylsilanol
1066-40-6

Trimethylsilanol

tris{η3-(3-tert-butylpyrazolyl)hydroborato}ZnH

tris{η3-(3-tert-butylpyrazolyl)hydroborato}ZnH

tris{η3-(3-tert-butylpyrazolyl)hydroborato}Zn(OSiMe3)

tris{η3-(3-tert-butylpyrazolyl)hydroborato}Zn(OSiMe3)

Conditions
ConditionsYield
In benzene 70°C (3 d); evapn. (reduced pressure); elem. anal.;93%
Trimethylsilanol
1066-40-6

Trimethylsilanol

dimethoxymethylstibane
54553-25-2

dimethoxymethylstibane

methyl-bis(trimethylsiloxy)stibane
169828-78-8

methyl-bis(trimethylsiloxy)stibane

Conditions
ConditionsYield
In dichloromethane byproducts: MeOH; Ar; org. compd. soln. addn. dropwise to Sb-compd. soln. at room temp., stirring for 30 min, solvent vac. removal; elem. anal.;93%
Trimethylsilanol
1066-40-6

Trimethylsilanol

(HB(C3H(CH3)(C(CH3)3)N2)3)ZnH
220342-04-1

(HB(C3H(CH3)(C(CH3)3)N2)3)ZnH

C27H49BN6OSiZn

C27H49BN6OSiZn

Conditions
ConditionsYield
In benzene at 60℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;93%
Trimethylsilanol
1066-40-6

Trimethylsilanol

2-methyl a l l y l t r i s-(trimethylsiloxy)silane
37611-52-2

2-methyl a l l y l t r i s-(trimethylsiloxy)silane

1,1,1,5,5,5-hexamethyl-3,3-bis(trimethylsiloxy)trisiloxane
3555-47-3

1,1,1,5,5,5-hexamethyl-3,3-bis(trimethylsiloxy)trisiloxane

Conditions
ConditionsYield
With Amberlyst-15 In acetonitrile at 20℃; for 1h; Solvent; chemoselective reaction;93%
Trimethylsilanol
1066-40-6

Trimethylsilanol

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane
1760-24-3

[1-(2-aminoethyl)-3-aminopropyl]trimethoxysilane

3-[3-N-(2-aminoethyl)aminopropyl]-3-methoxy-1,1,1,5,5,5-hexamethyltrisiloxane

3-[3-N-(2-aminoethyl)aminopropyl]-3-methoxy-1,1,1,5,5,5-hexamethyltrisiloxane

Conditions
ConditionsYield
Heating;92.5%
Trimethylsilanol
1066-40-6

Trimethylsilanol

tris(bis(trimethylsilyl)amido)praseodymium(III)

tris(bis(trimethylsilyl)amido)praseodymium(III)

A

tris(trimethylsiloxy)praseodymium

tris(trimethylsiloxy)praseodymium

B

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

Conditions
ConditionsYield
In toluene Addn. of trimethylsilanol soln. to soln. of Pr-complex, heating at 90°c for 1.5-2 h.; Evapn. in vac., addn. of hexane, crystn. at -30 to -50°C, elem. anal.;A 84.6%
B 90.3%
Trimethylsilanol
1066-40-6

Trimethylsilanol

[(CH3COCHCOCH3)2Al(μ-OCH(CH3)2)2Al(OCH(CH3)2)2]

[(CH3COCHCOCH3)2Al(μ-OCH(CH3)2)2Al(OCH(CH3)2)2]

(Al(OSi(CH3)3)2(CH3COCHCOCH3))2

(Al(OSi(CH3)3)2(CH3COCHCOCH3))2

Conditions
ConditionsYield
In pentane Me3SiOH was added rapidly under an inert atmosphere to a pentane soln. of (Al(O-i-Pr)2(acac))2; volatiles were removed, residue was recrystd. from pentane; elem. anal.;90%
Trimethylsilanol
1066-40-6

Trimethylsilanol

(Al(OCH(CH3)2)2(CH3COCHCOOCH2CH3))2

(Al(OCH(CH3)2)2(CH3COCHCOOCH2CH3))2

(Al(OSi(CH3)3)2(CH3COCHCOOCH2CH3))2

(Al(OSi(CH3)3)2(CH3COCHCOOCH2CH3))2

Conditions
ConditionsYield
In pentane Me3SiOH was added rapidly under an inert atmosphere to a pentane soln. of (Al(O-i-Pr)2(etac))2; volatiles were removed, residue was vac. distilled (130°C, >0.1 mm Hg); several isomers are observed in the NMR spectra; elem. anal.;90%
Trimethylsilanol
1066-40-6

Trimethylsilanol

bis(cyclopentadienyl)tin(II)
26078-96-6

bis(cyclopentadienyl)tin(II)

bis[bis(trimethylsilanolato)tin]

bis[bis(trimethylsilanolato)tin]

Conditions
ConditionsYield
In toluene byproducts: cyclopentadiene; (under exclusion of air and moisture) to a soln. of (C5H5)2Sn in toluene is added Me3SiOH, soln. is warmed (2 h); soln. is evapd. under vac., elem. anal.;90%
In not given
Trimethylsilanol
1066-40-6

Trimethylsilanol

[tris(6-tert-butyl-3-thiopyridazinyl)methanide]Zn(N{SiMe3}2)

[tris(6-tert-butyl-3-thiopyridazinyl)methanide]Zn(N{SiMe3}2)

[tris(6-tert-butyl-3-thiopyridazinyl)methanide]Zn(OSiMe3)

[tris(6-tert-butyl-3-thiopyridazinyl)methanide]Zn(OSiMe3)

Conditions
ConditionsYield
In toluene at -40 - 25℃; for 16h; Schlenk technique;90%
Trimethylsilanol
1066-40-6

Trimethylsilanol

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

Conditions
ConditionsYield
Stage #1: Trimethylsilanol; trifluoromethylsulfonic anhydride at 45℃; for 3.5h;
Stage #2: With chloro-trimethyl-silane at 15℃; for 2.5h; Temperature;
89%
Trimethylsilanol
1066-40-6

Trimethylsilanol

phenylsilane
694-53-1

phenylsilane

A

1,1,1,5,5,5-hexamethyl-3-phenyl-trisiloxane
27991-58-8

1,1,1,5,5,5-hexamethyl-3-phenyl-trisiloxane

B

C9H16OSi2

C9H16OSi2

Conditions
ConditionsYield
With [FeCl2(2,9-bis((diphenylphosphino)methyl)-1,10-phenanthroline)]; sodium triethylborohydride In tetrahydrofuran at 20℃; for 12h; Reagent/catalyst; Solvent;A 88.9%
B 8.1%
With nickel(II) bis(2,2,6,6-tetramethylheptane-3,5-dionate) In dichloromethane at 20℃; for 6.5h; Schlenk technique; Inert atmosphere;A 25%
B 50%
With [FeBr2(2,9-bis((dicyclohexylphosphino)methyl)-1,10-phenanthroline)]; sodium triethylborohydride In tetrahydrofuran at 20℃; for 12h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox;A 20 %Spectr.
B 28 %Spectr.
Trimethylsilanol
1066-40-6

Trimethylsilanol

3-(trimethoxysilyl)propan-1-amine
13822-56-5

3-(trimethoxysilyl)propan-1-amine

1,1,1-trimethyl-3,3-dimethoxy-3-(3-aminopropyl)disiloxane
393510-67-3

1,1,1-trimethyl-3,3-dimethoxy-3-(3-aminopropyl)disiloxane

Conditions
ConditionsYield
at 20℃; for 3h;88.8%
Trimethylsilanol
1066-40-6

Trimethylsilanol

3-aminopropyltriethoxysilane
919-30-2

3-aminopropyltriethoxysilane

(3-aminopropyl)tris(trimethylsiloxy)silane
25357-81-7

(3-aminopropyl)tris(trimethylsiloxy)silane

Conditions
ConditionsYield
Heating;88%

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