• Name

  N,N,N',N'-Tetrakis[4-(dibutylamino)phenyl]benzene-1,4-diamine

• EINECS 224-057-8
• CAS No. 4182-80-3
• Article Data5
• CAS DataBase
• Density 1.024 g/cm³
• Solubility
• Melting Point 92-94 °C
• Formula C₆₂H₉₂N₆
• Boiling Point 916.7 °C at 760 mmHg
• Molecular Weight 921.453
• Flash Point 340.7 °C
• Transport Information
• Appearance
• Safety
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms 1,4-Benzenediamine,N,N,N',N'-tetrakis[4-(dibutylamino)phenyl]- (9CI);p-Phenylenediamine, N,N,N',N'-tetrakis[p-(dibutylamino)phenyl]-(7CI,8CI);NIR-AM 1;
• PSA 19.44000
• LogP 18.25260

Synthetic route

542-69-8

1-iodo-butane

3283-07-6

N1,N1,N4,N4-tetrakis(4-aminophenyl)-p-phenylenediamine

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

Conditions

Conditions	Yield
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 80 - 93℃; for 4h;	96%
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 80 - 93℃; for 4h; Product distribution / selectivity;	96%

109-65-9

1-bromo-butane

3283-07-6

N1,N1,N4,N4-tetrakis(4-aminophenyl)-p-phenylenediamine

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

Conditions

Conditions	Yield
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 80 - 96℃; for 6h; Product distribution / selectivity;	89%

53358-54-6

1-bromo-4-(N,N-dibutyl)aniline

106-50-3

1,4-phenylenediamine

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

Conditions

Conditions	Yield
With sodium t-butanolate; XPhos; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane at 100℃; for 18h;

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

C62H92N6(2+)*2ClO4(1-)

Conditions

Conditions	Yield
Stage #1: N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene With Oxone In acetonitrile at 20℃; for 3h; Stage #2: With sodium perchlorate In acetonitrile at 20℃; for 1h; Product distribution / selectivity;	98%
Stage #1: N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene With iron(II) perchlorate hydrate In N,N-dimethyl-formamide at 70℃; for 5h; Inert atmosphere; Stage #2: With caesium hexafluorophosphate at 20℃; Inert atmosphere;	98%
With Oxone; potassium perchlorate In water; ethyl acetate; acetonitrile at 20℃; for 3.5h; Product distribution / selectivity;	95%

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

C62H92N6(2+)*2F6P(1-)

Conditions

Conditions	Yield
Stage #1: N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene With silver nitrate In N,N-dimethyl-formamide at 70℃; for 5h; Inert atmosphere; Stage #2: With caesium hexafluorophosphate at 20℃; Inert atmosphere;	96%

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

C62H92N6(2+)*O4S(2-)

Conditions

Conditions	Yield
With Oxone; sulfuric acid In water; ethyl acetate; acetonitrile at 20℃; for 3.5h;	92%

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

244761-29-3

lithium bis[1,2-oxalato(2-)-O,O'] borate

C62H92N6(2+)*2C4BO8(1-)

Conditions

Conditions	Yield
Stage #1: N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene With silver nitrate In N,N-dimethyl-formamide at 70℃; for 5h; Inert atmosphere; Stage #2: lithium bis[1,2-oxalato(2-)-O,O'] borate at 20℃; Inert atmosphere;	90%

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

189114-61-2

silver(I) triflimide

bis(trifluoromethanesulfone)imidate N,N,N',N'-tetrakis(p-dibutylaminophenyl)-p-phenylene diimmonium

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 60℃; for 3h; Product distribution / selectivity;

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

405074-81-9

1-[bis(trifluoromethanesulfonyl)methyl]-2,3,4,5,6-pentafluorobenzene

2C9F11O4S2(1-)*C62H92N6(2+)

Conditions

Conditions	Yield
With silver nitrate In N,N-dimethyl-formamide at 60℃; for 0.5h;

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

60805-12-1

tris-(trifluoromethanesulfonyl)methane acid

2C4F9O6S3(1-)*C62H92N6(2+)

Conditions

Conditions	Yield
With silver nitrate In water; N,N-dimethyl-formamide at 60℃; for 0.5h;

4182-80-3

N,N,N’,N’-tetrakis[p-di(butyl)aminophenyl]-p-phenylene

bis(hexafluoroantimonate) N,N,N',N'-tetrakis {p-di(n-butyl)aminophenyl}-p-phenylene diimmonium

Conditions

Conditions	Yield
With silver hexafluoroantimonate In acetonitrile at 60℃; for 3h;

N,N,N',N'-Tetrakis[4-(dibutylamino)phenyl]benzene-1,4-diamine Chemical Properties

N,N,N',N'-Tetrakis[4-(dibutylamino)phenyl]benzene-1,4-diamine Specification