Product Name

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  • Name

    potassium peroxide

  • EINECS
  • CAS No. 17014-71-0
  • Density >1 g/cm3
  • Solubility decomposed by H2O [HAW93]
  • Melting Point 490°C
  • Formula K2O2
  • Boiling Point 150.2°C at 760 mmHg
  • Molecular Weight 110.2
  • Flash Point
  • Transport Information
  • Appearance
  • Safety Dangerous fire hazard by spontaneous chemical reaction. It is a very powerful oxidizer. Fires of this material should be handled like sodium peroxide fires. Moderate explosion hazard by spontaneous chemical reaction. Explodes on contact with water, forming H2O2 and KOH. Violent reactions with air, Sb, As, O2, K. Vigorous reaction on contact with reducing materials. On contact with acid or acid fumes, it can emit toxic fumes. Incompatible with carbon, diselenium dichloride, ethanol, hydrocarbons, metals. When heated to decomposition it emits toxic fumes of K2O. See also PEROXIDES, INORGANIC.
  • Risk Codes
  • Molecular Structure Molecular Structure of 17014-71-0 (potassium peroxide)
  • Hazard Symbols Dangerous fire and explosion risk in contact with organic materials, strong oxidizing agent. Irritant to skin and tissue.
  • Synonyms Dipotassiumperoxide; Potassium oxide (K2(O2)); Potassium peroxide
  • PSA 46.12000
  • LogP -0.23760

POTASSIUM PEROXIDE Chemical Properties

Melting Point: 490°C
Molecular Formula: K2O2
Molecular Weight: 110.2
Appearance: A yellow granular solid
IUPAC Name: Dipotassium peroxide
Enthalpy of Vaporization: 45.09 kJ/mol 
Boiling Point: 150.2 °C at 760 mmHg 
Vapour Pressure: 1.48 mmHg at 25°C 
Air & Water Reactions: Reacts exothermically with water (or moisture in the air) to give oxygen and a caustic solution, potassium hydroxide
Synonyms: Potassium peroxide ; Dipotassio peroxide ; Peroxydipotassium
Following is the molecular structure of Potassium peroxide (17014-71-0):

POTASSIUM PEROXIDE Uses

Potassium peroxide (17014-71-0) is used as a bleach.

POTASSIUM PEROXIDE Production

Reactivity Profile: Potassium peroxide (17014-71-0) is a strong oxidizing agent. Reacts readily with reducing agents, including most organic compounds, to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). A quantity left on a piece of paper in the open air usually starts a fire in the paper spontaneously in a few minutes [Freeman].

POTASSIUM PEROXIDE Consensus Reports

Reported in EPA TSCA Inventory.

POTASSIUM PEROXIDE Safety Profile

Dangerous fire hazard by spontaneous chemical reaction. It is a very powerful oxidizer. Fires of this material should be handled like sodium peroxide fires. Moderate explosion hazard by spontaneous chemical reaction. Explodes on contact with water, forming H2O2 and KOH. Violent reactions with air, Sb, As, O2, K. Vigorous reaction on contact with reducing materials. On contact with acid or acid fumes, it can emit toxic fumes. Incompatible with carbon, diselenium dichloride, ethanol, hydrocarbons, metals. When heated to decomposition it emits toxic fumes of K2O.

POTASSIUM PEROXIDE Standards and Recommendations

DOT Classification:  5.1; Label: Oxidizer

POTASSIUM PEROXIDE Specification


Potassium peroxide (17014-71-0) is an inorganic compound with the molecular formula K2O2. It is formed as potassium reacts with oxygen in the air, along with potassium oxide (K2O) and potassium superoxide (KO2).

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