potassium
Conditions | Yield |
---|---|
With pyrographite In neat (no solvent) reduction of a small amount KOH starts at 700°C (in vac.) and proceeds at 900 °C;; | 90% |
With pyrographite In neat (no solvent) reduction of a small amount KOH starts at 700°C (in vac.) and proceeds at 900 °C;; | 90% |
With pyrographite In neat (no solvent) KOH is reduced by C at lower temp. than by Fe;; |
potassium
Conditions | Yield |
---|---|
With zirconium In neat (no solvent) K2WO4 + Zr (1:4), start of react.: 570 °C, calm react. process, yield: about 80% K, no oxide;; | 80% |
With zirconium In neat (no solvent) pressed powder mixture (K2WO4:Zr = 1:4), heating in vac. to 570°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; | |
With Zr In neat (no solvent) pressed powder mixture (K2WO4:Zr = 1:4), heating in vac. to 570°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; |
Conditions | Yield |
---|---|
With zirconium In neat (no solvent) react. of pressed powd. K2CrO4/Zr mixt. (weight ratio 1:2 and 1:4) at 800 °C;; | A 0% B 80% |
potassium azide
potassium
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: N; heating 10-12g KN3 (fine powder) to 355°C (high vacuum, electrically heated tube from instrument glass (Jena)), decompn. starts sometimes 3-4h after obtaining temp., synthesis lasts some d;; spectroscopically pure and gas-free K obtained;; | 80% |
In neat (no solvent) byproducts: N; thermal decompn. of KN3 (above 350°C, formation of N);; | |
In neat (no solvent) byproducts: N; thermal decompn. of KN3 begins at 320°C and proceeds continually at 360°;; |
potassium
Conditions | Yield |
---|---|
With iron In neat (no solvent) byproducts: Fe2O3, FeS; heating react. mixture in a special apparatus for 2 h at 1000 °C, 1mm Hg; using of rough Fe-splints possible; further by-products: SO2 and O2;; | 80% |
With iron In neat (no solvent) reductn. of K2SO4 by Fe in a quartz pot at 875 up to 1300 °C;; impured with 10 % sulfide;; | 60% |
With zirconium In neat (no solvent) byproducts: K-oxide, K-sulfide; K2SO4 + Zr (1:4), start of react.: 725 °C, explosion, yield: 20% K, 20% K-oxide, 20% K-sulfide;; | 20% |
Conditions | Yield |
---|---|
redn. with Zr powder in vac., 570°C; | 80% |
redn. with Zr powder in vac., 570°C; | 80% |
potassium
Conditions | Yield |
---|---|
With zirconium In neat (no solvent) heating of K2MoO4 and Zr powder (1:4) in vac. at 500°C;; | 70% |
With zirconium In neat (no solvent) K2MoO4 + Zr (1:4), start of react.: about 500 °C, calm react. process, yield: about 70% K, no oxide;; | 70% |
With Zr In neat (no solvent) heating of K2MoO4 and Zr powder (1:4) in vac. at 500°C;; | 70% |
With zirconium In neat (no solvent) pressed powder mixture (K2MoO4:Zr = 1:4), heating in vac. to about 500°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; | |
With Zr In neat (no solvent) pressed powder mixture (K2MoO4:Zr = 1:4), heating in vac. to about 500°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; |
potassium
Conditions | Yield |
---|---|
With iron In neat (no solvent) byproducts: Fe-oxide, Fe-arsenide; heating of react. mixture in a special apparatus at 900 °C, 1mm Hg for 8h;; very pure and As-free K obtained;; | 50% |
potassium
Conditions | Yield |
---|---|
With zirconium In neat (no solvent) byproducts: K-oxide; K2Cr2O7 + Zr (1:4), start of react.: 370 °C, explosion, yield: 40% K, 30% oxide;; | 40% |
With zirconium In neat (no solvent) pressed powder mixture (K2Cr2O7:Zr = 1:10), heating in vac. to 380°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; | |
With aluminium In neat (no solvent) on ignition of a mixture of K2Cr2O7 and Al; vaporization of K;; |
Conditions | Yield |
---|---|
With iron In neat (no solvent) byproducts: Fe2O3, CO, CO2; heating react. mixture in a special apparatus for 2 h at about 1000 °C, 1mm Hg; sucking off CO, CO2 (formation of explosive compounds possible);; | >99 |
With aluminium In neat (no solvent) byproducts: Al2O3, C; heating of K2CO3 with Al in a stream of H2 to red heat; no potassium carbonyl is formed;; | >99 |
With pyrographite In neat (no solvent) byproducts: CO; reduction of K2CO3 by C; no formation of K2O as intermediate;; |
potassium carbonate
aluminium
A
aluminum oxide
B
potassium
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: C; heating equal amounts of carbonate and Al powder to red heat;; powdery product mixture obtained;; | |
In neat (no solvent) byproducts: C; heating equal amounts of carbonate and Al powder to red heat;; powdery product mixture obtained;; |
Conditions | Yield |
---|---|
With pyrographite |
potassium
Conditions | Yield |
---|---|
With zirconium In neat (no solvent) pressed powder mixture (K2CrO4:Zr = 1:4), heating in vac. to 800°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; | |
With zirconium In neat (no solvent) K2CrO4 + Zr (1:4), start of react.: 800 °C, calm react.process, yield: up to 80% K, no oxide; especially appropriate for direct preperation of small amount of K in apparatus (at low temp.);; | <=80 |
With Zr In neat (no solvent) pressed powder mixture (K2CrO4:Zr = 1:4), heating in vac. to 800°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;; |
potassium
Conditions | Yield |
---|---|
With magnesium In neat (no solvent) heating a mixt. of 50 g dried KF and 18 g Mg gravel in an iron retort at pressure of 11 mm to 500 - 700 °C;; K distills off at 540 °C into a paraffine filled receiver; yield: 48 g;; | |
With aluminium In neat (no solvent) at m. p. of KF with Al pieces (use of Al powder is dangerous);; K is distilled off; pure;; | |
With calcium In neat (no solvent) at red heat;; |
Conditions | Yield |
---|---|
In neat (no solvent) on strong heating;; | |
In neat (no solvent) on strong heating;; |
Conditions | Yield |
---|---|
With iron In neat (no solvent) byproducts: Fe-halogenide; special apparatus used, 900 - 1000 °C, 1mm Hg; yield: small amount of K;; |
Conditions | Yield |
---|---|
Kinetics; Ar-carrier gas, at 3020 K; time-resolved absorption; |
Conditions | Yield |
---|---|
Kinetics; in system NaBr-K-Na-KBr; | |
Kinetics; in system NaBr-K-Na-KBr; |
Conditions | Yield |
---|---|
In nitrobenzene Electrolysis; | A n/a B 0% |
In nitrobenzene Electrolysis; | A n/a B 0% |
potassium
Conditions | Yield |
---|---|
With barium In neat (no solvent) evapn. of a mixture of a KCl soln. and a 16 % Ba(N3)2 soln. in vac to dryness; residue is heated in high vac.; decompn. of Ba(N3)2 at 100 °C forming finely dispersed Ba which acts as reducing agent: formation of K from KCl on further heating;; small amounts of pure K are obtained quickly;; | |
With aluminium In neat (no solvent) addn. of Al to molten KCl;; | |
With aluminium In neat (no solvent) with Al-powder at high temperatures;; |
Conditions | Yield |
---|---|
Electrochem. Process; Equilibrium potential at 800 °C: 3.32 V.; |
Conditions | Yield |
---|---|
In neat (no solvent) Incomplete reaction.; | |
In neat (no solvent) Incomplete reaction.; |
Conditions | Yield |
---|---|
In further solvent(s) Kinetics; solvent: Sn, Bi or Sb; | |
Kinetics; at 900 °C; in system NaCl-K-Na-KCl; |
Conditions | Yield |
---|---|
evapn. of reaction mixture formed from BaN6 and alkali chloride to dryness, then reaction at temp. of distn. of product; alkali metal distilles off; | |
evapn. of reaction mixture formed from BaN6 and alkali chloride to dryness, then reaction at temp. of distn. of product; alkali metal distilles off; |
Conditions | Yield |
---|---|
In further solvent(s) Kinetics; solvent: Sn, Bi or Sb; |
Conditions | Yield |
---|---|
In neat (no solvent) in Ar flow; react. of atomic H with solid KCl and its vapors; detd. by emission spectroscopy and resonance fluorescence; atomic potassium obtained; |
potassium
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H; decompn. of KH on heating to red heat in vacuum;; | |
In neat (no solvent) byproducts: H; decompn. of KH on heating to red heat in vacuum;; |
Conditions | Yield |
---|---|
Kinetics; |
Conditions | Yield |
---|---|
In neat (no solvent) | 100% |
differential thermal anal.; | 100% |
potassium
Conditions | Yield |
---|---|
In benzene a stirred soln. of the Fe-compd. and metallic K was heated to 50-60°C for 4 h; filtn., washed with C6H6, dried, elem. anal.; | 100% |
potassium
Conditions | Yield |
---|---|
In tetrahydrofuran (N2 or Ar); stirring over potassium mirror, 12 h; filtering, concg. in vac.; | 100% |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) under Ar; mixt. was heated to 523 K for 1 d, then heated at 1023 K for 1d, then cooled to 773 K at 2 K/h, kept at 773 K for 3 d, then cooled to 473 K at 2 K/h in 5 d before switching off the furnace; XRD; | 100% |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) under Ar; mixt. was heated to 523 K for 1 d, then heated at 973 K for 1 d, then cooled to 773 K at 2 K/h, kept at 773 K for 3 d, then cooled to 473 K at 2 K/h in 5 d before switching off the furnace; XRD; | 100% |
Conditions | Yield |
---|---|
In toluene (N2) Hf complex, K and 18-crown-6 in toluene were stirred for 24 h; pentane was added, ppt. was filtered off; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In benzene byproducts: KCl; exclusion of moisture, slow addn. of a soln. of KAl(OPr(i))4 (K, Al(OPr(i))3 and OHCH(CH3)2 in C6H6, reflux, 2 h) to a suspension of the Y-salt in C6H6, stirring, 60°C, addn. of KOPr(i) (K, HOCH(CH3)2 in C6H6) stirring, molar ratio 1:1:2 Y:KAl:K; recrystn. (n-hexane) yielding 60%; | 99% |
Conditions | Yield |
---|---|
In diethyl ether; isopropyl alcohol byproducts: KCl, Hg(Oi-Pr)2; K dissolved in i-PrOH, Al(Oi-Pr)3 added, this soln. is added to an ether soln. of the metal chloride, mixt. stirred for ca. 2 h at 0 °C, Hg:Al:K=1:1:2; filtered; elem anal.; | 99% |
In diethyl ether; isopropyl alcohol byproducts: KCl; K dissolved in i-PrOH, Al(Oi-Pr)3 added, this soln. is added to an ether soln. of the metal chloride, mixt. stirred for ca. 2 h at 0 °C, Hg:Al:K=1:2:2; filtered; elem anal.; | 97% |
[(CH3)Zn((CH3)3CNCHCHNC(CH3)3)]2
potassium
Conditions | Yield |
---|---|
In tetrahydrofuran N2-atmosphere; stirring (room temp., 16 h); evapn. (vac.), washing (Et2O), drying (vac.); | 99% |
In tetrahydrofuran (inert atmosphere); stirring (room temp., 16 h); solvent removal (vac.), washing (hexanes), drying (vac.); elem. anal.; | 99% |
(tetramethylcyclopentadienyl)2UMe2
potassium
Conditions | Yield |
---|---|
In toluene (Ar); Schlenk technique; toluene was added to K; mixt. was vigorously stirred under heating; soln. of U complex in toluene was added dropwise; mixt. was cooled to room temp. for 3 d; solvent removed; residue washed (toluene); washings discarded; residue dried; elem. anal.; | 99% |
C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2
potassium
Conditions | Yield |
---|---|
In diethyl ether | 99% |
Conditions | Yield |
---|---|
In neat (no solvent) at 130℃; for 3h; Heating; | 99% |
at 120℃; for 2h; Inert atmosphere; Schlenk technique; Heating; | |
In neat (no solvent, solid phase) at 20℃; Inert atmosphere; |
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 20℃; Schlenk technique; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: KCl; anhydrous atmosphere; refluxing K with 3,5-dimethylphenol, then addn. to Zr-complex (molar ratio Zr:phenolate=1:2), refluxing and stirring (12 h, room temp.); KCl filtered off, concentration, recrystn. (THF, hexane); elem. anal.; | 98% |
H(Sb(ClCH2CH(O)CH(O)CH2Cl)2)
potassium
Conditions | Yield |
---|---|
With methanol In methanol refluxing potassium in methanol, addn. of the soln. to a suspn. of the antimony compd., refluxing for 1.5 h; all manipulations under anhydrous atmosphere; concg. under reduced pressure, elem. anal.; | 98% |
Conditions | Yield |
---|---|
In benzene byproducts: KCl; exclusion of moisture, slow addn. of a soln. of KAl(OPr(i))4 (prepared from K, Al(OPr(i))3 and isopropanol in benzene, reflux, 2 h) to a suspension of the Y salt in benzene with stirring, 60°C, 5 h, then stirring overnight, ca 30°C; filtration of KCl, removal of volatiles under reduced pressure (30°C/ 1 Torr), recrystn. (n-hexane-CH2Cl2 (2:1)) yielding ca 60%, elem. anal.; | 98% |
Conditions | Yield |
---|---|
In isopropyl alcohol; benzene byproducts: KCl; treatment of K with Al(Oi-Pr)3 in mixt. isopropanol/benzene, addn. to suspn. of FeCl3 in benzene (molar ratio K/Al(Oi-Pr)3/FeCl3 2:2:1, stirring), refluxing (12 h); sepn. of pptd. KCl (filtration off), removal of solvent (vac.); elem. anal.; | 98% |
1,4-di-tert-butyl-1,4-diazabutadiene
dimethyl zinc(II)
potassium
Conditions | Yield |
---|---|
In tetrahydrofuran; pentane N2-atmosphere; stirring (room temp., 16 h); evapn. (vac.), washing (hexanes or Et2O), drying (vac.); elem. anal.; | 98% |
C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2
potassium
Conditions | Yield |
---|---|
In diethyl ether | 98% |
Conditions | Yield |
---|---|
In toluene (N2) Zr complex, K and 18-crown-6 in toluene were stirred for 24 h; pentane was added, ppt. was filtered off; elem. anal.; | 98% |
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: KCl; anhydrous atmosphere; refluxing K with 3,5-dimethylphenol, then addn. to Ti-complex (molar ratio Ti:phenolate=1:2), refluxing and stirring (12 h, room temp.); KCl filtered off, concentration, recrystn. (THF, hexane); elem. anal.; | 97% |
Reported in EPA TSCA Inventory.
DOT Classification: 4.3; Label: Dangerous When Wet
The IUPAC name of Potassium is potassium. With the CAS registry number 7440-09-7, it is also named as Kalium. The product's categories are Inorganic & Organic Chemicals; Inorganics, and the other registry number is 31079-13-7. Besides, it is soft silvery metal, which should be stored in kerosene or liquid paraffin. It is stable, but spontaneously combustible through the generation and ignition of hydrogen. In addition, its molecular formula is K and molecular weight is 39.09.
The other characteristics of this product can be summarized as: (1)EINECS: 231-119-8; (2)Exact Mass: 38.963707; (3)MonoIsotopic Mass: 38.963707; (4)Topological Polar Surface Area: 0; (5)Heavy Atom Count: 1; (6)Density: 0.862 g/cm3; (7)Melting point: 63.38 °C; (8)Boiling point: 759 °C; (9)Vapor pressure: 0.09 mm Hg ( 260 °C); (10)Triple point: 63 °C.
Preparation of Potassium: this chemical can be prepared by the reaction of Potassium chloride with Sodium. The reaction will occur by heating to 830 °C.
Uses of Potassium: this chemical is important in neuron (brain and nerve) function, and in influencing osmotic balance between cells and the interstitial fluid, with their distribution mediated in all animals (but not in all plants) by the so-called Na+/K+-ATPase pump. It is also used to prevent muscle contraction and the sending of all nerve impulses in animals through action potentials. Moreover, Potassium ion is a nutrient necessary for human life and health. It is used as reducing agent in organic synthesis. Furthermore, it is widely used in conjunction with loop diuretics and thiazides, classes of diuretics which rid the body of sodium and water in medicine.
When you are using this chemical, please be cautious about it as the following: it reacts violently with water in contact with water liberates extremely flammable gases. Please keep contents under the oil. And you should keep container dry. It also may cause burns. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
People can use the following data to convert to the molecule structure.
(1)SMILES: [K]
(2)InChI: InChI=1/K
(3)InChIKey: ZLMJMSJWJFRBEC-UHFFFAOYAX
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 700mg/kg (700mg/kg) | "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 704, 1948. |
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