Product Name

This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.
  • Name

    Potassium

  • EINECS 231-119-8
  • CAS No. 7440-09-7
  • Article Data347
  • CAS DataBase
  • Density 0.862 g/cm3
  • Solubility reacts with water violently
  • Melting Point 63.38 °C
  • Formula K
  • Boiling Point 759 °C
  • Molecular Weight 39.0983
  • Flash Point
  • Transport Information UN 2257/1420
  • Appearance soft silvery metal
  • Safety 8-43-45-5B-5
  • Risk Codes 14/15-34
  • Molecular Structure Molecular Structure of 7440-09-7 (Potassium)
  • Hazard Symbols FlammableF,CorrosiveC
  • Synonyms Potassium(1+);Losartan Base;Kalium;Potassium, (liquid alloy);Potassium, metal;
  • PSA 0.00000
  • LogP 0.11250

Synthetic route

potassium hydroxide

potassium hydroxide

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With pyrographite In neat (no solvent) reduction of a small amount KOH starts at 700°C (in vac.) and proceeds at 900 °C;;90%
With pyrographite In neat (no solvent) reduction of a small amount KOH starts at 700°C (in vac.) and proceeds at 900 °C;;90%
With pyrographite In neat (no solvent) KOH is reduced by C at lower temp. than by Fe;;
potassium tungstate

potassium tungstate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With zirconium In neat (no solvent) K2WO4 + Zr (1:4), start of react.: 570 °C, calm react. process, yield: about 80% K, no oxide;;80%
With zirconium In neat (no solvent) pressed powder mixture (K2WO4:Zr = 1:4), heating in vac. to 570°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
With Zr In neat (no solvent) pressed powder mixture (K2WO4:Zr = 1:4), heating in vac. to 570°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
potassium chromate

potassium chromate

A

chromium(III) oxide

chromium(III) oxide

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With zirconium In neat (no solvent) react. of pressed powd. K2CrO4/Zr mixt. (weight ratio 1:2 and 1:4) at 800 °C;;A 0%
B 80%
potassium azide
20762-60-1

potassium azide

potassium
7440-09-7

potassium

Conditions
ConditionsYield
In neat (no solvent) byproducts: N; heating 10-12g KN3 (fine powder) to 355°C (high vacuum, electrically heated tube from instrument glass (Jena)), decompn. starts sometimes 3-4h after obtaining temp., synthesis lasts some d;; spectroscopically pure and gas-free K obtained;;80%
In neat (no solvent) byproducts: N; thermal decompn. of KN3 (above 350°C, formation of N);;
In neat (no solvent) byproducts: N; thermal decompn. of KN3 begins at 320°C and proceeds continually at 360°;;
potassium sulfate

potassium sulfate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With iron In neat (no solvent) byproducts: Fe2O3, FeS; heating react. mixture in a special apparatus for 2 h at 1000 °C, 1mm Hg; using of rough Fe-splints possible; further by-products: SO2 and O2;;80%
With iron In neat (no solvent) reductn. of K2SO4 by Fe in a quartz pot at 875 up to 1300 °C;; impured with 10 % sulfide;;60%
With zirconium In neat (no solvent) byproducts: K-oxide, K-sulfide; K2SO4 + Zr (1:4), start of react.: 725 °C, explosion, yield: 20% K, 20% K-oxide, 20% K-sulfide;;20%
zirconium
7440-67-7

zirconium

potassium tungstate

potassium tungstate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
redn. with Zr powder in vac., 570°C;80%
redn. with Zr powder in vac., 570°C;80%
potassium molybdate(VI)

potassium molybdate(VI)

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With zirconium In neat (no solvent) heating of K2MoO4 and Zr powder (1:4) in vac. at 500°C;;70%
With zirconium In neat (no solvent) K2MoO4 + Zr (1:4), start of react.: about 500 °C, calm react. process, yield: about 70% K, no oxide;;70%
With Zr In neat (no solvent) heating of K2MoO4 and Zr powder (1:4) in vac. at 500°C;;70%
With zirconium In neat (no solvent) pressed powder mixture (K2MoO4:Zr = 1:4), heating in vac. to about 500°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
With Zr In neat (no solvent) pressed powder mixture (K2MoO4:Zr = 1:4), heating in vac. to about 500°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
potassium metaarsenate

potassium metaarsenate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With iron In neat (no solvent) byproducts: Fe-oxide, Fe-arsenide; heating of react. mixture in a special apparatus at 900 °C, 1mm Hg for 8h;; very pure and As-free K obtained;;50%
potassium dichromate

potassium dichromate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With zirconium In neat (no solvent) byproducts: K-oxide; K2Cr2O7 + Zr (1:4), start of react.: 370 °C, explosion, yield: 40% K, 30% oxide;;40%
With zirconium In neat (no solvent) pressed powder mixture (K2Cr2O7:Zr = 1:10), heating in vac. to 380°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
With aluminium In neat (no solvent) on ignition of a mixture of K2Cr2O7 and Al; vaporization of K;;
potassium carbonate
584-08-7

potassium carbonate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With iron In neat (no solvent) byproducts: Fe2O3, CO, CO2; heating react. mixture in a special apparatus for 2 h at about 1000 °C, 1mm Hg; sucking off CO, CO2 (formation of explosive compounds possible);;>99
With aluminium In neat (no solvent) byproducts: Al2O3, C; heating of K2CO3 with Al in a stream of H2 to red heat; no potassium carbonyl is formed;;>99
With pyrographite In neat (no solvent) byproducts: CO; reduction of K2CO3 by C; no formation of K2O as intermediate;;
sodium
7440-23-5

sodium

potassium carbonate
584-08-7

potassium carbonate

A

potassium
7440-09-7

potassium

B

sodium carbonate
497-19-8

sodium carbonate

potassium carbonate
584-08-7

potassium carbonate

aluminium
7429-90-5

aluminium

A

aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
In neat (no solvent) byproducts: C; heating equal amounts of carbonate and Al powder to red heat;; powdery product mixture obtained;;
In neat (no solvent) byproducts: C; heating equal amounts of carbonate and Al powder to red heat;; powdery product mixture obtained;;
potassium tartrate

potassium tartrate

A

potassium doped carbon

potassium doped carbon

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With pyrographite
potassium chromate

potassium chromate

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With zirconium In neat (no solvent) pressed powder mixture (K2CrO4:Zr = 1:4), heating in vac. to 800°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
With zirconium In neat (no solvent) K2CrO4 + Zr (1:4), start of react.: 800 °C, calm react.process, yield: up to 80% K, no oxide; especially appropriate for direct preperation of small amount of K in apparatus (at low temp.);;<=80
With Zr In neat (no solvent) pressed powder mixture (K2CrO4:Zr = 1:4), heating in vac. to 800°C; mostly explosive reaction, with great excess of Zr smoothy;; further products;;
potassium fluoride

potassium fluoride

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With magnesium In neat (no solvent) heating a mixt. of 50 g dried KF and 18 g Mg gravel in an iron retort at pressure of 11 mm to 500 - 700 °C;; K distills off at 540 °C into a paraffine filled receiver; yield: 48 g;;
With aluminium In neat (no solvent) at m. p. of KF with Al pieces (use of Al powder is dangerous);; K is distilled off; pure;;
With calcium In neat (no solvent) at red heat;;
potassium fluoride

potassium fluoride

aluminium
7429-90-5

aluminium

A

tripotassium hexafluoroaluminate

tripotassium hexafluoroaluminate

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
In neat (no solvent) on strong heating;;
In neat (no solvent) on strong heating;;
potassium bromide
7558-02-3

potassium bromide

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With iron In neat (no solvent) byproducts: Fe-halogenide; special apparatus used, 900 - 1000 °C, 1mm Hg; yield: small amount of K;;
potassium bromide
7558-02-3

potassium bromide

A

bromine
10097-32-2

bromine

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
Kinetics; Ar-carrier gas, at 3020 K; time-resolved absorption;
sodium
7440-23-5

sodium

potassium bromide
7558-02-3

potassium bromide

A

potassium
7440-09-7

potassium

B

sodium bromide
7647-15-6

sodium bromide

Conditions
ConditionsYield
Kinetics; in system NaBr-K-Na-KBr;
Kinetics; in system NaBr-K-Na-KBr;
aluminium bromide
7727-15-3

aluminium bromide

potassium bromide
7558-02-3

potassium bromide

A

potassium
7440-09-7

potassium

B

aluminium
7429-90-5

aluminium

Conditions
ConditionsYield
In nitrobenzene Electrolysis;A n/a
B 0%
In nitrobenzene Electrolysis;A n/a
B 0%
potassium chloride

potassium chloride

potassium
7440-09-7

potassium

Conditions
ConditionsYield
With barium In neat (no solvent) evapn. of a mixture of a KCl soln. and a 16 % Ba(N3)2 soln. in vac to dryness; residue is heated in high vac.; decompn. of Ba(N3)2 at 100 °C forming finely dispersed Ba which acts as reducing agent: formation of K from KCl on further heating;; small amounts of pure K are obtained quickly;;
With aluminium In neat (no solvent) addn. of Al to molten KCl;;
With aluminium In neat (no solvent) with Al-powder at high temperatures;;
potassium chloride

potassium chloride

A

potassium
7440-09-7

potassium

B

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
Electrochem. Process; Equilibrium potential at 800 °C: 3.32 V.;
potassium chloride

potassium chloride

magnesium
7439-95-4

magnesium

A

potassium
7440-09-7

potassium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) Incomplete reaction.;
In neat (no solvent) Incomplete reaction.;
potassium chloride

potassium chloride

sodium
7440-23-5

sodium

A

potassium
7440-09-7

potassium

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In further solvent(s) Kinetics; solvent: Sn, Bi or Sb;
Kinetics; at 900 °C; in system NaCl-K-Na-KCl;
potassium chloride

potassium chloride

barium
7440-39-3

barium

potassium
7440-09-7

potassium

Conditions
ConditionsYield
evapn. of reaction mixture formed from BaN6 and alkali chloride to dryness, then reaction at temp. of distn. of product; alkali metal distilles off;
evapn. of reaction mixture formed from BaN6 and alkali chloride to dryness, then reaction at temp. of distn. of product; alkali metal distilles off;
potassium chloride

potassium chloride

barium
7440-39-3

barium

A

potassium
7440-09-7

potassium

B

barium(II) chloride

barium(II) chloride

Conditions
ConditionsYield
In further solvent(s) Kinetics; solvent: Sn, Bi or Sb;
hydrogen

hydrogen

potassium chloride

potassium chloride

potassium
7440-09-7

potassium

Conditions
ConditionsYield
In neat (no solvent) in Ar flow; react. of atomic H with solid KCl and its vapors; detd. by emission spectroscopy and resonance fluorescence; atomic potassium obtained;
potassium hydride

potassium hydride

potassium
7440-09-7

potassium

Conditions
ConditionsYield
In neat (no solvent) byproducts: H; decompn. of KH on heating to red heat in vacuum;;
In neat (no solvent) byproducts: H; decompn. of KH on heating to red heat in vacuum;;
potassium hydride

potassium hydride

A

hydrogen
1333-74-0

hydrogen

B

potassium
7440-09-7

potassium

Conditions
ConditionsYield
Kinetics;
bismuth
7440-69-9

bismuth

potassium
7440-09-7

potassium

sulfur
7704-34-9

sulfur

potassium metathiobismuthite

potassium metathiobismuthite

Conditions
ConditionsYield
In neat (no solvent)100%
differential thermal anal.;100%
3(5)-(ferrocen-1-yl)pyrazole

3(5)-(ferrocen-1-yl)pyrazole

potassium
7440-09-7

potassium

K(1+)*{(C5H5)Fe(C5H4C3H2N2)}(1-)=K{(C5H5)Fe(C5H4C3H2N2)}

K(1+)*{(C5H5)Fe(C5H4C3H2N2)}(1-)=K{(C5H5)Fe(C5H4C3H2N2)}

Conditions
ConditionsYield
In benzene a stirred soln. of the Fe-compd. and metallic K was heated to 50-60°C for 4 h; filtn., washed with C6H6, dried, elem. anal.;100%
bis(η5-2,3-dihydro-1H-1,3-diborolyl)platinum

bis(η5-2,3-dihydro-1H-1,3-diborolyl)platinum

potassium
7440-09-7

potassium

2K(1+)*[Pt(C3B2(CH3)(C2H5)4)2](2-)*99C4H8O=K2[Pt(C3B2(CH3)(C2H5)4)2]*99C4H8O

2K(1+)*[Pt(C3B2(CH3)(C2H5)4)2](2-)*99C4H8O=K2[Pt(C3B2(CH3)(C2H5)4)2]*99C4H8O

Conditions
ConditionsYield
In tetrahydrofuran (N2 or Ar); stirring over potassium mirror, 12 h; filtering, concg. in vac.;100%
tellurium

tellurium

potassium
7440-09-7

potassium

cadmium
7440-43-9

cadmium

potassium cadmium(II) telluride

potassium cadmium(II) telluride

Conditions
ConditionsYield
In neat (no solvent, solid phase) under Ar; mixt. was heated to 523 K for 1 d, then heated at 1023 K for 1d, then cooled to 773 K at 2 K/h, kept at 773 K for 3 d, then cooled to 473 K at 2 K/h in 5 d before switching off the furnace; XRD;100%
tellurium

tellurium

potassium
7440-09-7

potassium

potassium zinc(II) telluride

potassium zinc(II) telluride

Conditions
ConditionsYield
In neat (no solvent, solid phase) under Ar; mixt. was heated to 523 K for 1 d, then heated at 973 K for 1 d, then cooled to 773 K at 2 K/h, kept at 773 K for 3 d, then cooled to 473 K at 2 K/h in 5 d before switching off the furnace; XRD;100%
bis(cyclopentadienyl)hafnium dichloride
12116-66-4

bis(cyclopentadienyl)hafnium dichloride

18-crown-6 ether
17455-13-9

18-crown-6 ether

potassium
7440-09-7

potassium

(18-crown-6)*K[Cp2HfCl2]

(18-crown-6)*K[Cp2HfCl2]

Conditions
ConditionsYield
In toluene (N2) Hf complex, K and 18-crown-6 in toluene were stirred for 24 h; pentane was added, ppt. was filtered off; elem. anal.;100%
yttrium(III) chloride triisopropanolate

yttrium(III) chloride triisopropanolate

potassium
7440-09-7

potassium

aluminum isopropoxide
555-31-7

aluminum isopropoxide

isopropyl alcohol
67-63-0

isopropyl alcohol

Y(3+)*Al(3+)*6CH(CH3)2O(1-) = {(Y(OCH(CH3)2)2(Al(OCH(CH3)2)4))}

Y(3+)*Al(3+)*6CH(CH3)2O(1-) = {(Y(OCH(CH3)2)2(Al(OCH(CH3)2)4))}

Conditions
ConditionsYield
In benzene byproducts: KCl; exclusion of moisture, slow addn. of a soln. of KAl(OPr(i))4 (K, Al(OPr(i))3 and OHCH(CH3)2 in C6H6, reflux, 2 h) to a suspension of the Y-salt in C6H6, stirring, 60°C, addn. of KOPr(i) (K, HOCH(CH3)2 in C6H6) stirring, molar ratio 1:1:2 Y:KAl:K; recrystn. (n-hexane) yielding 60%;99%
potassium
7440-09-7

potassium

aluminum isopropoxide
555-31-7

aluminum isopropoxide

isopropyl alcohol
67-63-0

isopropyl alcohol

mercury dichloride

mercury dichloride

mercury bis(tetraisopropoxyaluminate)

mercury bis(tetraisopropoxyaluminate)

Conditions
ConditionsYield
In diethyl ether; isopropyl alcohol byproducts: KCl, Hg(Oi-Pr)2; K dissolved in i-PrOH, Al(Oi-Pr)3 added, this soln. is added to an ether soln. of the metal chloride, mixt. stirred for ca. 2 h at 0 °C, Hg:Al:K=1:1:2; filtered; elem anal.;99%
In diethyl ether; isopropyl alcohol byproducts: KCl; K dissolved in i-PrOH, Al(Oi-Pr)3 added, this soln. is added to an ether soln. of the metal chloride, mixt. stirred for ca. 2 h at 0 °C, Hg:Al:K=1:2:2; filtered; elem anal.;97%
[(CH3)Zn((CH3)3CNCHCHNC(CH3)3)]2
156219-63-5, 159861-02-6

[(CH3)Zn((CH3)3CNCHCHNC(CH3)3)]2

potassium
7440-09-7

potassium

K(1+)*Zn(CH3)((CH3)3CNCHCHNC(CH3)3)(1-)=K[Zn(CH3)((CH3)3CNCHCHNC(CH3)3)]

K(1+)*Zn(CH3)((CH3)3CNCHCHNC(CH3)3)(1-)=K[Zn(CH3)((CH3)3CNCHCHNC(CH3)3)]

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; stirring (room temp., 16 h); evapn. (vac.), washing (Et2O), drying (vac.);99%
In tetrahydrofuran (inert atmosphere); stirring (room temp., 16 h); solvent removal (vac.), washing (hexanes), drying (vac.); elem. anal.;99%
(tetramethylcyclopentadienyl)2UMe2
866338-41-2

(tetramethylcyclopentadienyl)2UMe2

potassium
7440-09-7

potassium

2C5(CH3)4H(1-)*U(3+)*2CH3(1-)*K(1+)=[(C5(CH3)4H)2U(CH3)2K]

2C5(CH3)4H(1-)*U(3+)*2CH3(1-)*K(1+)=[(C5(CH3)4H)2U(CH3)2K]

Conditions
ConditionsYield
In toluene (Ar); Schlenk technique; toluene was added to K; mixt. was vigorously stirred under heating; soln. of U complex in toluene was added dropwise; mixt. was cooled to room temp. for 3 d; solvent removed; residue washed (toluene); washings discarded; residue dried; elem. anal.;99%
C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2
191107-88-7

C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2

potassium
7440-09-7

potassium

2K(1+)*C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2(2-)=K2[C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2]

2K(1+)*C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2(2-)=K2[C2B3(OCH3)(Si(CH3)3)2(C6H(CH3)4)2]

Conditions
ConditionsYield
In diethyl ether99%
Graphite

Graphite

potassium
7440-09-7

potassium

potassium graphite

potassium graphite

Conditions
ConditionsYield
In neat (no solvent) at 130℃; for 3h; Heating;99%
at 120℃; for 2h; Inert atmosphere; Schlenk technique; Heating;
In neat (no solvent, solid phase) at 20℃; Inert atmosphere;
C24H33BO

C24H33BO

potassium
7440-09-7

potassium

C20H25B(2-)*C4H8O*2K(1+)

C20H25B(2-)*C4H8O*2K(1+)

Conditions
ConditionsYield
In tetrahydrofuran at -78 - 20℃; Schlenk technique; Inert atmosphere;99%
zirconocene dichloride
1291-32-3

zirconocene dichloride

potassium
7440-09-7

potassium

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

(η5-C5H5)2Zr(3,5-dimethylphenolato)2

(η5-C5H5)2Zr(3,5-dimethylphenolato)2

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl; anhydrous atmosphere; refluxing K with 3,5-dimethylphenol, then addn. to Zr-complex (molar ratio Zr:phenolate=1:2), refluxing and stirring (12 h, room temp.); KCl filtered off, concentration, recrystn. (THF, hexane); elem. anal.;98%
H(Sb(ClCH2CH(O)CH(O)CH2Cl)2)
139055-84-8

H(Sb(ClCH2CH(O)CH(O)CH2Cl)2)

potassium
7440-09-7

potassium

K(1+)*(Sb(ClCH2CH(O)CH(O)CH2Cl)2)(1-)=K(Sb(ClCH2CH(O)CH(O)CH2Cl)2)

K(1+)*(Sb(ClCH2CH(O)CH(O)CH2Cl)2)(1-)=K(Sb(ClCH2CH(O)CH(O)CH2Cl)2)

Conditions
ConditionsYield
With methanol In methanol refluxing potassium in methanol, addn. of the soln. to a suspn. of the antimony compd., refluxing for 1.5 h; all manipulations under anhydrous atmosphere; concg. under reduced pressure, elem. anal.;98%
yttrium(III) chloride triisopropanolate

yttrium(III) chloride triisopropanolate

potassium
7440-09-7

potassium

aluminum isopropoxide
555-31-7

aluminum isopropoxide

isopropyl alcohol
67-63-0

isopropyl alcohol

{(ClY(Al(OCH(CH3)2)4)2(HOCH(CH3)2))2}

{(ClY(Al(OCH(CH3)2)4)2(HOCH(CH3)2))2}

Conditions
ConditionsYield
In benzene byproducts: KCl; exclusion of moisture, slow addn. of a soln. of KAl(OPr(i))4 (prepared from K, Al(OPr(i))3 and isopropanol in benzene, reflux, 2 h) to a suspension of the Y salt in benzene with stirring, 60°C, 5 h, then stirring overnight, ca 30°C; filtration of KCl, removal of volatiles under reduced pressure (30°C/ 1 Torr), recrystn. (n-hexane-CH2Cl2 (2:1)) yielding ca 60%, elem. anal.;98%
potassium
7440-09-7

potassium

iron(III) chloride
7705-08-0

iron(III) chloride

aluminum isopropoxide
555-31-7

aluminum isopropoxide

FeCl{Al(Oi-Pr)4}2

FeCl{Al(Oi-Pr)4}2

Conditions
ConditionsYield
In isopropyl alcohol; benzene byproducts: KCl; treatment of K with Al(Oi-Pr)3 in mixt. isopropanol/benzene, addn. to suspn. of FeCl3 in benzene (molar ratio K/Al(Oi-Pr)3/FeCl3 2:2:1, stirring), refluxing (12 h); sepn. of pptd. KCl (filtration off), removal of solvent (vac.); elem. anal.;98%
1,4-di-tert-butyl-1,4-diazabutadiene
28227-42-1, 30834-74-3

1,4-di-tert-butyl-1,4-diazabutadiene

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

potassium
7440-09-7

potassium

K(1+)*Zn(CH3)((CH3)3CNCHCHNC(CH3)3)(1-)=K[Zn(CH3)((CH3)3CNCHCHNC(CH3)3)]

K(1+)*Zn(CH3)((CH3)3CNCHCHNC(CH3)3)(1-)=K[Zn(CH3)((CH3)3CNCHCHNC(CH3)3)]

Conditions
ConditionsYield
In tetrahydrofuran; pentane N2-atmosphere; stirring (room temp., 16 h); evapn. (vac.), washing (hexanes or Et2O), drying (vac.); elem. anal.;98%
C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2
191107-87-6

C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2

potassium
7440-09-7

potassium

2K(1+)*C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2(2-)=K2[C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2]

2K(1+)*C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2(2-)=K2[C2B3(N(Si(CH3)3)2)(Si(CH3)3)2(C6H(CH3)4)2]

Conditions
ConditionsYield
In diethyl ether98%
zirconocene dichloride
1291-32-3

zirconocene dichloride

18-crown-6 ether
17455-13-9

18-crown-6 ether

potassium
7440-09-7

potassium

(18-crown-6)*K[Cp2ZrCl2]

(18-crown-6)*K[Cp2ZrCl2]

Conditions
ConditionsYield
In toluene (N2) Zr complex, K and 18-crown-6 in toluene were stirred for 24 h; pentane was added, ppt. was filtered off; elem. anal.;98%
bis(cyclopentadienyl)titanium dichloride
1271-19-8

bis(cyclopentadienyl)titanium dichloride

potassium
7440-09-7

potassium

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

(η5-C5H5)2Ti(3,5-dimethylphenolato)2

(η5-C5H5)2Ti(3,5-dimethylphenolato)2

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl; anhydrous atmosphere; refluxing K with 3,5-dimethylphenol, then addn. to Ti-complex (molar ratio Ti:phenolate=1:2), refluxing and stirring (12 h, room temp.); KCl filtered off, concentration, recrystn. (THF, hexane); elem. anal.;97%

Potassium Consensus Reports

Reported in EPA TSCA Inventory.

Potassium Standards and Recommendations

DOT Classification:  4.3; Label: Dangerous When Wet

Potassium Specification

The IUPAC name of Potassium is potassium. With the CAS registry number 7440-09-7, it is also named as Kalium. The product's categories are Inorganic & Organic Chemicals; Inorganics, and the other registry number is 31079-13-7. Besides, it is soft silvery metal, which should be stored in kerosene or liquid paraffin. It is stable, but spontaneously combustible through the generation and ignition of hydrogen. In addition, its molecular formula is K and molecular weight is 39.09.

The other characteristics of this product can be summarized as: (1)EINECS: 231-119-8; (2)Exact Mass: 38.963707; (3)MonoIsotopic Mass: 38.963707; (4)Topological Polar Surface Area: 0; (5)Heavy Atom Count: 1; (6)Density: 0.862 g/cm3; (7)Melting point: 63.38 °C; (8)Boiling point: 759 °C; (9)Vapor pressure: 0.09 mm Hg ( 260 °C); (10)Triple point: 63 °C.

Preparation of Potassium: this chemical can be prepared by the reaction of Potassium chloride with Sodium. The reaction will occur by heating to 830 °C.

Uses of Potassium: this chemical is important in neuron (brain and nerve) function, and in influencing osmotic balance between cells and the interstitial fluid, with their distribution mediated in all animals (but not in all plants) by the so-called Na+/K+-ATPase pump. It is also used to prevent muscle contraction and the sending of all nerve impulses in animals through action potentials.  Moreover, Potassium ion is a nutrient necessary for human life and health. It is used as reducing agent in organic synthesis. Furthermore, it is widely used in conjunction with loop diuretics and thiazides, classes of diuretics which rid the body of sodium and water in medicine.

When you are using this chemical, please be cautious about it as the following: it reacts violently with water in contact with water liberates extremely flammable gases. Please keep contents under the oil. And you should keep container dry. It also may cause burns. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
(1)SMILES: [K]
(2)InChI: InChI=1/K
(3)InChIKey: ZLMJMSJWJFRBEC-UHFFFAOYAX

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 700mg/kg (700mg/kg)   "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 704, 1948.

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View