• Name

  Rhodium(II) octanoate dimer

• EINECS 247-015-0
• CAS No. 73482-96-9
• Article Data4
• CAS DataBase
• Density
• Solubility
• Melting Point
• Formula C₃₂H₆₀O₈Rh₂
• Boiling Point 239.3 °C at 760 mmHg
• Molecular Weight 778.635
• Flash Point 107.4 °C
• Transport Information
• Appearance green powder
• Safety 26-36
• Risk Codes 36/37/38
• Molecular Structure
• Hazard Symbols Xi
• Synonyms Octanoic acid, rhodium complex;Dirhodium tetraoctanoate;Rhodium(II) octanoatedimer;Tetrakis(octanoato)dirhodium;Rhodium,tetrakis[m-(octanoato-O:O')]di-, (Rh-Rh);
• PSA 105.20000
• LogP 9.41760

Synthetic route

rhodium(III) chloride

124-07-2

Octanoic acid

73482-96-9

rhodium (II) octanoate dimer

Conditions

Conditions	Yield
With sodium hydroxide at 70℃; for 4h; Temperature; Large scale;	97.57%

124-07-2

Octanoic acid

tetrasodium rhodium tetracarbonate

73482-96-9

rhodium (II) octanoate dimer

Conditions

Conditions	Yield
In water at 60℃; for 3h;	94.4%

124-07-2

Octanoic acid

rhodium(III) trichloride hydrate

73482-96-9

rhodium (II) octanoate dimer

Conditions

Conditions	Yield
With lithium carbonate In ethanol at 20℃; for 6.5h; Heating;	67%

dirhodium tetraacetate

124-07-2

Octanoic acid

73482-96-9

rhodium (II) octanoate dimer

Conditions

Conditions	Yield
In not given heated at 120°C for 2 h; recrystd. (C7H16); elem. anal.; hot-stage polarizing microscopy; DSC;

73482-96-9

rhodium (II) octanoate dimer

81730-52-1

3-(piperidin-1-yl)-3-thioxopropanenitrile

C48H84N4O8Rh2S2

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Inert atmosphere;	100%

73482-96-9

rhodium (II) octanoate dimer

3-(azepan-1-yl)-3-thioxopropanenitrile

C50H88N4O8Rh2S2

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Inert atmosphere;	100%

73482-96-9

rhodium (II) octanoate dimer

3-(4-benzylpiperidin-1-yl)-3-thioxopropanenitrile

C62H96N4O8Rh2S2

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Inert atmosphere;	100%

73482-96-9

rhodium (II) octanoate dimer

313353-02-5

3-(morpholin-4-yl)-3-thioxopropanenitrile

C46H80N4O10Rh2S2

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Inert atmosphere;	100%

930-36-9

1-methyl-1H-pyrazole

73482-96-9

rhodium (II) octanoate dimer

1268445-96-0

[Rh2(octanoato)4(1-methylpyrazole)]

Conditions

Conditions	Yield
In chloroform (N2); a soln. of ligand added to Rh complex in CHCl3, stirred at room temp. for 1 h; evapd. (vac.); elem. anal.;	99%

930-36-9

1-methyl-1H-pyrazole

73482-96-9

rhodium (II) octanoate dimer

1268445-97-1

[Rh2(octanoato)4(1-methylpyrazole)2]

Conditions

Conditions	Yield
In chloroform (N2); a soln. of ligand added to Rh complex in CHCl3, stirred at room temp. for 1 h; evapd. (vac.); elem. anal.;	99%

73482-96-9

rhodium (II) octanoate dimer

162412-44-4

1-ferrocenyl-2-(4-pyridinyl)acetylene

Rh2(OOC-nC7H15)4(ferrocenyl-4-pyridylacetylene)2

Conditions

Conditions	Yield
In dichloromethane all manipulations under oxygen- and water-free Ar atm.; soln. of Rh complex added to soln. of Fe complex, stirred at room temp. for 2 h; evapd. to dryness in vac., residue washed with n-hexane, recrystd. from Et2O, elem. anal.;	86%

73482-96-9

rhodium (II) octanoate dimer

316807-50-8

1,1’-di(4-(ethynyl)pyridine)ferrocene

[Rh2(OOC-nC7H15)4((pyridylethynyl)ferrocene)]n

Conditions

Conditions	Yield
In dichloromethane all manipulations under oxygen- and water-free Ar atm.; Rh and Fe complexes dissolved in CH2Cl2, stirred at room temp. overnight; filtered, filtrate evapd. to dryness in vac., residue washed with Et2O, recrystd. by diffusion of Et2O into its CH2Cl2 soln., elem. anal.;	86%

73482-96-9

rhodium (II) octanoate dimer

120577-85-7

ferrocenyl-4-pyridine

Rh2(OOC-nC7H15)4(ferrocenyl-4-pyridine)2

Conditions

Conditions	Yield
In dichloromethane all manipulations under oxygen- and water-free Ar atm.; Mo and Fe complexes dissolved in CH2Cl2, stirred at room temp. for 2 h; evapd. to dryness in vac., residue washed with n-hexane, recrystd. from CH2Cl2/n-hexane, elem. anal.;	71%

73482-96-9

rhodium (II) octanoate dimer

1268445-95-9

[Fe(C5(C3H2N2CH3)5)(C5H4PO(t-C4H9)2)]*(chloroform)

[Fe(C5(C3H2N2CH3)5)(C5H4PO(t-C4H9)2)]12[dirhodium(II) tetraoctanoate]30

Conditions

Conditions	Yield
In acetonitrile (N2); Fe complex in MeCN added dropwise to a soln. of Rh complex, stirred at room temp. for 0.5 h; filtered, washed (MeCN, ether), dried in vac. at 60°C overnight; elem. anal.;	64%

73482-96-9

rhodium (II) octanoate dimer

541-42-4

i-propyl nitrite

78184-79-9

benzhydryl 6-aminopenicillanate

129792-01-4

benzhydryl 6-oxopenicillanate

Conditions

Conditions	Yield
With trifluoroacetic acid; methyloxirane In dichloromethane; ethyl acetate; benzene

...Expand

73482-96-9

rhodium (II) octanoate dimer

3S-(1S-hydroxyethyl)-4R-(1R-methyl-3-allyloxycarbonyl-2-oxo-3-diazopropyl)azetidin-2-one

(5 S ,6 S) allyl 6-(1 S-hydroxyethyl)-4 R-methyl-3,7-dioxo-1-azabicyclo[3.2.0]heptane-2-carboxylate

Conditions

Conditions	Yield
In ethyl acetate

73482-96-9

rhodium (II) octanoate dimer

7337-45-3

N-tert-butylaminoborane

A

Rh*2(CH3)3CNH3(1+)*2O2CC7H15(1-)=Rh*2(CH3)3CNH3(O2CC7H15)

B

132820-43-0

BH(NHtBu)2

Conditions

Conditions	Yield
In toluene byproducts: [(CH3)3CNH3][C7H15CO2], B2H6, H2; (N2); solutions of rhodium salt and tert-butylamine-borate in toluene were combinea at 25.0+-0.1°C, stirred for 2 h; concd., cold hexane was added, filtered, washed with hexane, dried in vac., elem. anal.;

...Expand

Rhodium octanoate dimer Specification