Product Name

  • Name

    2',4',5',7'-TETRABROMO-3,4,5,6-TETRACHLOROFLUORESCEIN

  • EINECS
  • CAS No. 2134-15-8
  • Article Data1
  • CAS DataBase
  • Density 2.6g/cm3
  • Solubility
  • Melting Point
  • Formula C20H4Br4Cl4O5
  • Boiling Point 759°Cat760mmHg
  • Molecular Weight 785.677
  • Flash Point 412.8°C
  • Transport Information
  • Appearance
  • Safety Mutation data reported. When heated to decomposition it emits toxic vapors of Br and Cl.
  • Risk Codes
  • Molecular Structure Molecular Structure of 2134-15-8 (2',4',5',7'-TETRABROMO-3,4,5,6-TETRACHLOROFLUORESCEIN)
  • Hazard Symbols
  • Synonyms nonachloro-2-phenoxyphenol;Phlorin,2'.4'.5'.7'-Tetrabrom-3.4.5.6-tetrachlor-fluorescein;1,2,3,4-tetrachloro-5,6-bis-hydroxymethyl-benzene;3,4,5,6-tetrachloro-1,2-bis(hydroxymethyl)benzene;3,4,5,6-tetrachloro-2-(pentachlorophenoxy)phenol;(perchloro-1,2-phenylene)dimethanol;2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein;1,2-Benzenedimethanol,3,4,5,6-tetrachloro;tetrachlorobenzene-1,2-dimethanol;3,4,5,6-tetrachloro-2-(2,3,4,5,6-pentachlorophenoxy)phenol;3',4',5',6'-tetrachloro-2,4,5,7-tetrabromofluorescein;1,2-Bis-hydroxymethyl-3,4,5,6-tetrachlor-benzol;2,3,4,5-tetrachloro-6-pentachlorophenoxy-phenol;2,3,4,5-Tetrachlor-6-pentachlorphenoxy-phenol;1,2,3,4-Tetrachlor-5,6-bis-hydroxymethyl-benzol;2-hydroxynonachlorodiphenyl ether;
  • PSA 75.99000
  • LogP 9.32940

Synthetic route

1',2',3',4'-tetrachlorofluorescein
13245-63-1

1',2',3',4'-tetrachlorofluorescein

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein
2134-15-8

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein

Conditions
ConditionsYield
With bromine; sodium carbonate In ethanol for 12h; Ambient temperature;78%
tetrachlorophthalic anhydride
117-08-8

tetrachlorophthalic anhydride

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein
2134-15-8

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 60 percent / 2.5 h / 200 °C
2: 78 percent / Br2, 5percent aq. Na2CO3 / ethanol / 12 h / Ambient temperature
View Scheme
recorcinol
108-46-3

recorcinol

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein
2134-15-8

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 60 percent / 2.5 h / 200 °C
2: 78 percent / Br2, 5percent aq. Na2CO3 / ethanol / 12 h / Ambient temperature
View Scheme
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein
2134-15-8

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein

cadmium(II)

cadmium(II)

{Cd(C12H8N2)2}(2+)*Cl4Br4C20H2O5(2-)={Cd(C12H8N2)2}Cl4Br4C20H2O5

{Cd(C12H8N2)2}(2+)*Cl4Br4C20H2O5(2-)={Cd(C12H8N2)2}Cl4Br4C20H2O5

Conditions
ConditionsYield
In water addn. of acetate-ammonia buffer soln. (pH = 3 - 10), 1E-2 M phenanthroline soln. and 1E-2 M fluorescein soln. to aq. soln. of Cd; mixt. was transferred to separatory funnel; addn. of CHCl3; shaken 1 min; sepn. of phases; addn. of acetone to CHCl3 layer; not isolated; only in soln.; detn. by fluorescence spectroscopy;;
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein
2134-15-8

2,4,5,7-tetrabromo-1',2',3',4'-tetrachlorofluorescein

zinc(II) cation

zinc(II) cation

{Zn(C12H8N2)2}(2+)*Cl4Br4C20H2O5(2-)={Zn(C12H8N2)2}Cl4Br4C20H2O5

{Zn(C12H8N2)2}(2+)*Cl4Br4C20H2O5(2-)={Zn(C12H8N2)2}Cl4Br4C20H2O5

Conditions
ConditionsYield
In water addn. of acetate-ammonia buffer soln. (pH = 3 - 10), 1E-2 M phenanthroline soln. and 1E-2 M fluorescein soln. to aq. soln. of Zn; mixt. was transferred to separatory funnel; addn. of CHCl3; shaken 1 min; sepn. of phases; addn. of acetone to CHCl3 layer; not isolated; only in soln.; detn. by fluorescence spectroscopy;;

SOLVENT RED 48 Chemical Properties

IUPAC Name:(2E,4E)-Hexa-2,4-dienal2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3',6'-dihydroxyspiro[2-benzofuran-3,9'-xanthene]-1-one
Synonyms: 2,3,4,5-Tetrachloro-6-(2,4,5,7-tetrabromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)-Benzoicacid ; 2’,4’,5’,7’-Tetrabromo-4,5,6,7-tetrachloro-fluorescei ; Acidphloxineb ; Acidphloxinepb ; Benzoicacid,2,3,4,5-tetrachloro-6,2,4,5,7-tetrabromo-6-hydroxy-3-oxo-3h-xa ; Benzoicacid,2,3,4,5-tetrachloro-6-(2,4,5,7-tetrabromo-6-hydroxy-3-oxo-3h-xant ; C.I.45410:1 ; C.I.45410a
CAS: 2134-15-8
Molecular Formula of Solvent red 48 (CAS NO. 2134-15-8) : C20H4Br4Cl4O5
Molecular Weight of Solvent red 48 (CAS NO. 2134-15-8) : 785.67
Molecular Struture of  Solvent red 48 (CAS NO. 2134-15-8) :
Product Categories: Organics
Mol File: 2134-15-8.mol
Index of Refraction: 1.88
Surface Tension: 117.3 dyne/cm
Density: 2.6 g/cm3
Flash Point: 412.8 °C
Enthalpy of Vaporization: 114.45 kJ/mol
Boiling Point: 759 °C at 760 mmHg
Vapour Pressure: 7.57E-24 mmHg at 25°C

SOLVENT RED 48 Toxicity Data With Reference

1.    

dnr-bcs 2 mg/disc

    TRENAF    Kenkyu Nenpo-Tokyo-toritsu Eisei Kenkyusho. Annual Report of Tokyo Metropolitan Research Laboratory of Public Health. 27 (1976),153.

SOLVENT RED 48 Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of Br and Cl.

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