1,1,1-tri(hydroxymethyl)propane
methacrylic acid methyl ester
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With tetramethylammonium methyl carbonate at 70℃; for 12h; Molecular sieve; Green chemistry; | 92% |
With p-methylanizole; TEMPOL; lithium chloride; calcium oxide at 70 - 115℃; Product distribution / selectivity; Industry scale; |
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With azobisisobutyronitrile In various solvent(s) at 80℃; for 4h; | 100% |
trimethylolpropane trimethacrylate
methacrylic acid methyl ester
polymer, Mn 42200 Da and PDI 18.6 by GPC, Mn 924000 Da by membrane osmometry; monomer(s): trimethylolpropane trimethacrylate; diphenyl phosphate N.N\-diethyl-4-vinylbenzamidine; methyl methacrylate
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In various solvent(s) at 60 - 80℃; for 336h; | 99.5% |
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With azobisisobutyronitrile In toluene at 80℃; for 4h; | 97% |
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With azobisisobutyronitrile In chloroform at 80℃; for 4h; | 97% |
poly(methacrylic acid)
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-methacrylic acid-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 87.2 %mol; trimethylolpropanetrimethacrylate, 7.0 %mol; methacrylic acid, 5.8 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 97% |
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 98.8 %mol; trimethylolpropanetrimethacrylate, 1.2 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 97% |
poly(methacrylic acid)
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-methacrylic acid-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 93.1 %mol; trimethylolpropanetrimethacrylate, 1.7 %mol; methacrylic acid, 5.2 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 96% |
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 98.3 %mol; trimethylolpropanetrimethacrylate, 1.7 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 96% |
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With acetic acid butyl ester; hydroxyethyl cellulose; dibenzoyl peroxide In water at 80℃; for 8h; Product distribution; Further Variations:; Reagents; | 95% |
poly(methacrylic acid)
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-methacrylic acid-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 91.1 %mol; trimethylolpropanetrimethacrylate, 3.5 %mol; methacrylic acid, 5.4 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 94% |
N,N-Dimethylacrylamide
trimethylolpropane trimethacrylate
poly-(N,N-dimethylacrylamide-co-trimethylolpropyltrimethacrylate); monomer(s): N,N-dimethylacrylamide, 99.4 %mol; trimethylolpropanetrimethacrylate, 0.6 %mol
Conditions | Yield |
---|---|
at 20℃; for 24h; γ-Irradiation; | 94% |
trimethylolpropane trimethacrylate
methacrylic acid methyl ester
polymer, Mn 8100 Da and PDI 8.4 by GPC, Mn 162000 Da by membrane osmometry; monomer(s): formic acid N,N\-diethyl-4-vinylbenzamidine complex; trimethylolpropane trimethacrylate; methyl methacrylate
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In various solvent(s) at 60 - 80℃; for 338h; | 89.8% |
trimethylolpropane trimethacrylate
methacrylic acid methyl ester
polymer, Mn 31300 Da and PDI 12.7 by GPC, Mn 472000 Da by membrane osmometry; monomer(s): diphenyl phosphate N,N\-diethyl-4-vinylbenzamidine complex; trimethylolpropane trimethacrylate; methyl methacrylate
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In various solvent(s) at 60 - 80℃; for 336h; | 67.9% |
trimethylolpropane trimethacrylate
Conditions | Yield |
---|---|
With 2,2-dimethoxy-2-phenylacetophenone under 4.62 Torr; for 0.12h; Kinetics; Product distribution; UV-irradiation; | 44% |
trimethylolpropane trimethacrylate
methacrylic acid methyl ester
polymer, Mn 7500 Da and PDI 6.3 by GPC, Mn 112000 Da by membrane osmometry; monomer(s): formic acid N,N\-diethyl-4-vinylbenzamidine complex; trimethylolpropane trimethacrylate; methyl methacrylate
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In various solvent(s) at 60 - 80℃; for 336h; | 34.8% |
Conditions | Yield |
---|---|
at 20℃; for 1h; Polymerization; Irradiation; |
poly(methacrylic acid)
(S)-1-isopropylamino-3-(1-naphthyloxy)-2-propanol
trimethylolpropane trimethacrylate
4-hydroxymethyl-2,5-diphenyloxazole acrylate
Polymer; Monomer(s): (S)-propranolol, 0.7 mmol; methacrylic acid, 1.39 mmol; 4-hydroxymethyl-2,5-diphenyloxazole acrylate, 0.69 mmol; trimethylolpropane trimethacrylate, 1.39 mmol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In toluene at 60℃; for 16h; |
poly(methacrylic acid)
(S)-1-isopropylamino-3-(1-naphthyloxy)-2-propanol
trimethylolpropane trimethacrylate
4-hydroxymethyl-2,5-diphenyloxazole acrylate
Polymer; Monomer(s): (S)-propranolol, 0.6 mmol; methacrylic acid, 0.78 mmol; 4-hydroxymethyl-2,5-diphenyloxazole acrylate, 0.16 mmol; trimethylolpropane trimethacrylate, 0.78 mmol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In toluene at 60℃; for 16h; |
poly(methacrylic acid)
trimethylolpropane trimethacrylate
4-hydroxymethyl-2,5-diphenyloxazole acrylate
Polymer; Monomer(s): methacrylic acid, 1.39 mmol; 4-hydroxymethyl-2,5-diphenyloxazole acrylate, 0.69 mmol; trimethylolpropane trimethacrylate, 1.39 mmol
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) In toluene at 60℃; for 16h; |
The Trimethylolpropane trimethacrylate, with the CAS registry number 3290-92-4, is also known as 2-Ethyl-1,3-dimethacryloxy-2-(methacryloxymethyl)propane. It belongs to the product category of Functional Monomer. Its EINECS registry number is 221-950-4. This chemical's molecular formula is C18H26O6 and molecular weight is 338.40. What's more, both its IUPAC name and systematic name are the same which is called 2,2-Bis(2-methylprop-2-enoyloxymethyl)butyl 2-methylprop-2-enoate. It should be stored in a cool, dry and well-ventilated place. This chemical can be used as crosslinking agents.
Physical properties about Trimethylolpropane trimethacrylate are: (1)ACD/LogP: 3.93; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.93; (4)ACD/LogD (pH 7.4): 3.93; (5)ACD/BCF (pH 5.5): 571.31; (6)ACD/BCF (pH 7.4): 571.31; (7)ACD/KOC (pH 5.5): 3273.17; (8)ACD/KOC (pH 7.4): 3273.17; (9)#H bond acceptors: 6; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 13; (12)Polar Surface Area: 78.9 Å2; (13)Index of Refraction: 1.47; (14)Molar Refractivity: 89.435 cm3; (15)Molar Volume: 320.836 cm3; (16)Polarizability: 35.455×10-24cm3; (17)Surface Tension: 33.72 dyne/cm; (18)Density: 1.055 g/cm3; (19)Flash Point: 181.418 °C; (20)Enthalpy of Vaporization: 67.616 kJ/mol; (21)Boiling Point: 422.051 °C at 760 mmHg; (22)Vapour Pressure: 0 mmHg at 25 °C.
When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1) SMILES: O=C(OCC(COC(=O)\C(=C)C)(CC)COC(=O)\C(=C)C)\C(=C)C
(2) InChI: InChI=1S/C18H26O6/c1-8-18(9-22-15(19)12(2)3,10-23-16(20)13(4)5)11-24-17(21)14(6)7/h2,4,6,8-11H2,1,3,5,7H3
(3) InChIKey: OKKRPWIIYQTPQF-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 2889mg/kg (2889mg/kg) | Journal of Dental Research. Vol. 51, Pg. 526, 1972. | |
rabbit | LD50 | skin | 16mL/kg (16mL/kg) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. | |
rat | LD50 | intraperitoneal | 3100mg/kg (3100mg/kg) | BEHAVIORAL: ATAXIA BEHAVIORAL: TREMOR LUNGS, THORAX, OR RESPIRATION: DYSPNEA | National Technical Information Service. Vol. OTS0571319, |
rat | LD50 | oral | 5660uL/kg (5.66mL/kg) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. |
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