Tris(triphenylphosphine)chlororhodium supplier

Name
Chlorotris(triphenylphosphine)rhodium(I)
EINECS 238-744-5
CAS No. 14694-95-2
Article Data51
CAS DataBase
Density 1.363; d 1.379
Solubility insoluble in water
Melting Point 245-250 °C (dec.)
Formula C₅₄H₄₅ClP₃Rh
Boiling Point >170 °C
Molecular Weight 925.231
Flash Point 181.7oC
Transport Information
Appearance magenta crystals
Safety 22-24/25-37/39-28A-26-15
Risk Codes 34-36/38
Molecular Structure
Hazard Symbols Xi,C
Synonyms Rhodium,chlorotris(triphenylphosphine)- (7CI,8CI);Chlorotris(triphenylphosphine)rhodium(I);NSC 124140;Rhodium tris(triphenylphosphine) chloride;Tris(triphenylphosphine)rhodiumchloride;Tris(triphenylphosphine)rhodium(I)chloride;Wilkinson's catalyst;
PSA 40.77000
LogP 11.02390

Tris(triphenylphosphine)chlororhodium Specification

The Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)-, with the CAS registry number 14694-95-2 and EINECS registry number 238-744-5, has the systematic name of chlororhodium; triphenylphosphane. It is a kind of magenta crystals, and belongs to the following product categories: Metal Compounds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Rh (Rhodium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds. And the molecular formula of this chemical is C₅₄H₄₅ClP₃Rh. What's more, it is soluble in benzene and toluene while insoluble in ether or alcohol. And it is often used as hydrogenation catalyst and Wilkinson catalyst. And it should be stored at 2-8°C.

The physical properties of Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)- are as followings: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 9; (4)Polar Surface Area: 40.77 Å².

You should be cautious while dealing with this chemical. It irritates to eyes and skin, and it may also cause burns. Therefore, you had better take the following instructions: Wear suitable gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Do not breathe dust; Avoid contact with skin and eyes; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); Keep away from heat.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Rh].c1ccccc1P(c2ccccc2)c3ccccc3.c1ccccc1P(c2ccccc2)c3ccccc3.c1ccccc1P(c2ccccc2)c3ccccc3
(2)InChI: InChI=1/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1/r3C18H15P.ClRh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2/h3*1-15H;
(3)InChIKey: IXAYKDDZKIZSPV-CMQSVACPAK

Product Name

Chlorotris(triphenylphosphine)rhodium(I)

Tris(triphenylphosphine)chlororhodium Specification

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