solvent green 3 supplier | CasNO.128-80-3

Name
Solvent Green 3
EINECS 204-909-5
CAS No. 128-80-3
Article Data26
CAS DataBase
Density 1.292 g/cm³
Solubility 10μg/L at 25℃
Melting Point 220-221 °C
Formula C₂₈H₂₂N₂O₂
Boiling Point 633.8 °C at 760 mmHg
Molecular Weight 418.495
Flash Point 197 °C
Transport Information
Appearance black fine crystalline powder
Safety 24/25-22-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 1,4-Bis(4'-methylanilino)anthraquinone;1,4-Bis[(4-methylphenyl)amino]anthraquinone;1,4-Di-p-toluidinoanthraquinone;AlizarineCyanine Green G Fat Soluble;Anthraquinone Green G Base;Arlosol Green BS;Brown 921;C.I. 61565;C.I. SolventGreen 3;Cyanine Green G base;C Green No. 6;FD and C Green no. 6;Fat SolubleAnthraquinone Green;Fat Soluble Green Anthraquinone;Green 6;Kayaset Green A-B;NSC 84207;Oil Green 530;Oil Green 5602;Oplas Green 533;Organol Green J;Quinazarin green;Quinizarine Green Base;Solvent Green3;Sumiplast Green G;Waxoline Green6GFW;
PSA 58.20000
LogP 6.71200

Synthetic route

: 81-64-1
1,4-dihydroxy-9,10-anthracenedione

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With leucoquinizarin; boric acid; sodium hydrogensulfite In ethanol; benzene at 62 - 66℃; for 12h; Temperature; Solvent;	97%
With 1-butyl-3-ethyl-1H-imidazolium tetrafluoroborate at 85 - 125℃; Reagent/catalyst; Temperature; Green chemistry; Large scale;	95.9%
With boric acid; calcium carbonate; tin(ll) chloride at 110 - 130℃;

: 602-25-5
1,4-dichloroanthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With potassium phosphate In ethylbenzene at 150℃; for 6h;	90%
at 190℃;

: 6119-74-0
1,4-dimethoxyanthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

: 17648-03-2
9,10-Dihydroxy-2,3-dihydro-anthracene-1,4-dione

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With boric acid
With 1,4-dihydroxy-9,10-anthracenedione

: 128-95-0
1,4-diamino-9,10-anthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With tin(ll) chloride

: 5327-72-0
1,4-diamino-anthracene-9,10-diol

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
Erhitzen unter Luftzutritt auf 150grad;

: 117499-93-1
1-chloro-4-dimethylamino-anthraquinone

: 106-49-0
p-toluidine

A: 128-85-8
1-(methylamino)-4-[(4-methylphenyl)amino]anthraquinone

B: 128-80-3
D and C green 6

Conditions

Conditions	Yield
at 180℃;

...Expand

: 6337-82-2
1-Nitro-4-chloroanthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With boric acid; sodium carbonate; tin(ll) chloride

: 81-66-3
1-methoxy-4-nitro-anthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
at 160 - 180℃;

: 80490-02-4
1-methoxy-4-phenoxy-anthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

: 861083-48-9
1-bromo-4-methoxy-anthraquinone

: 127-09-3
sodium acetate

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
at 180 - 190℃;

...Expand

: 861083-48-9
1-bromo-4-methoxy-anthraquinone

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With sodium acetate at 180 - 190℃;

: 17648-03-2
9,10-Dihydroxy-2,3-dihydro-anthracene-1,4-dione

: 13460-50-9
metaboric acid

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
giesst das Reaktionsprodukt in verd. Salzsaeure;

...Expand

: 81-64-1
1,4-dihydroxy-9,10-anthracenedione

: 17648-03-2
9,10-Dihydroxy-2,3-dihydro-anthracene-1,4-dione

: 13460-50-9
metaboric acid

: 106-49-0
p-toluidine

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
at 110 - 130℃;
at 110 - 130℃;

...Expand

: 13460-50-9
metaboric acid

: 106-49-0
p-toluidine

quinizarine (1/2 mol): quinizarine (1/2 mol)

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
at 130 - 140℃;

...Expand

: 106-49-0
p-toluidine

quinizarinedimethyl ether: quinizarinedimethyl ether

: 128-80-3
D and C green 6

: 106-49-0
p-toluidine

quinizarinediethyl ether: quinizarinediethyl ether

: 128-80-3
D and C green 6

: 128-95-0
1,4-diamino-9,10-anthraquinone

: 106-49-0
p-toluidine

tin dichloride: tin dichloride

: 128-80-3
D and C green 6

...Expand

: 117499-93-1
1-chloro-4-dimethylamino-anthraquinone

: 106-49-0
p-toluidine

A: 128-80-3
D and C green 6

B 1-monomethylamino-4-p-toluidino-anthraquinone: 1-monomethylamino-4-p-toluidino-anthraquinone

Conditions

Conditions	Yield
at 180℃;

...Expand

: 82-39-3
1-methoxyanthracene-9,10-dione

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: nitric acid View Scheme
Multi-step reaction with 2 steps 1: water / beim Bromieren 2: sodium acetate / 180 - 190 °C View Scheme
Multi-step reaction with 2 steps 1: water / beim Bromieren 2: 180 - 190 °C View Scheme

: 82-44-0
1-chloroanthracene-9,10-dione

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: HNO3+H2SO4 2: tin dichloride; sodium carbonate; boric acid View Scheme

: 81-66-3
1-methoxy-4-nitro-anthraquinone

: 128-80-3
D and C green 6

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 110 - 120 °C View Scheme

: 81-64-1
1,4-dihydroxy-9,10-anthracenedione

: 106-49-0
p-toluidine

A: 81-48-1
1-hydroxy-4-(4-methylphenylamino)-9,10-anthraquinone

B: 128-80-3
D and C green 6

Conditions

Conditions	Yield
With LACTIC ACID; Trimethyl borate; 2,3-dihydro-1,4-dihydroxyanthraquinone In 4-butanolide at 100℃; for 13h; Product distribution / selectivity;
With LACTIC ACID; 2,3-dihydro-1,4-dihydroxyanthraquinone; boric acid In 4-butanolide at 100 - 125℃; for 19h; Product distribution / selectivity;

...Expand

: 128-80-3
D and C green 6

: 1,4-bis(4-methyl-2-bromophenyl)aminoanthraquinone

Conditions

Conditions	Yield
With sulfuric acid; bromine at 25℃; for 40h;	100%
With bromine In tetrachloromethane at 3 - 5℃; Temperature;	95.1%

: 128-80-3
D and C green 6

: 75839-23-5
1,4-bis-(4-methyl-2-nitro-anilino)-anthraquinone

Conditions

Conditions	Yield
With nitric acid In acetic acid at 20 - 60℃; for 2h;	95.7%
With acetic acid; sodium nitrite

: 128-80-3
D and C green 6

: solvent violet 38

Conditions

Conditions	Yield
With bromine In tetrachloromethane at 60℃; for 3h;	81.4%

: 128-80-3
D and C green 6

: 143-33-9
sodium cyanide

: 9,10-Dioxo-9,10-dihydro-1,4-bis(p-tolylamino)anthracen-2,3-dicarbonitril

Conditions

Conditions	Yield
With ammonium bicarbonate 1.) DMSO, 100 deg C, 15 h; 2.) water, r.t., 4 h;	50%

: 128-80-3
D and C green 6

: 3443-90-1
quinizarin green

Conditions

Conditions	Yield
With sulfuric acid at 70 - 80℃;
With sulfuric acid at 70 - 80℃;

: 128-80-3
D and C green 6

: 3179-85-9
4-(9,10-dioxo-4-p-toluidino-9,10-dihydro-[1]anthrylamino)-toluene-3-sulfonic acid

Conditions

Conditions	Yield
With sulfuric acid at 70 - 80℃;
With sulfuric acid at 70 - 80℃;

: 128-80-3
D and C green 6

: 7628-56-0
8-(p-Toluidino)-2-methylceramidonine

Conditions

Conditions	Yield
With PPA at 130℃; for 3h;
With sulfuric acid at 120 - 130℃; for 3h;	1.4 g
With sulfuric acid at 0 - 125℃; for 11h;	9.2 g
With sulfuric acid at 140 - 150℃;

: 128-80-3
D and C green 6

: 3,6-di-p-tolyl-2,3,6,7-tetrahydro-anthra[1,9-de;4,10-d'e']bis[1,3]oxazine

: 128-80-3
D and C green 6

: 75839-44-0
1,4-di(3-nitro-4-methylanilino)anthraquinone

Conditions

Conditions	Yield
Yield given. Multistep reaction;

: 128-80-3
D and C green 6

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: C34H34N4O2(2+)*2Cl(1-)

Conditions

Conditions	Yield
With trichlorophosphate In ethanethiol for 0.5h;

: 7664-93-9
sulfuric acid

: 128-80-3
D and C green 6

: 3443-90-1
quinizarin green

solvent green 3 Chemical Properties

Product Name: Solvent green 3 (CAS NO.128-80-3)

Molecular Formula: C₂₈H₂₂N₂O₂
Molecular Weight: 418.49g/mol
Mol File: 128-80-3.mol
Einecs: 204-909-5
Appearance: Black fine crystalline powder
Melting Point: 220-221 °C
Boiling point: 633.8 °C at 760 mmHg
Flash Point: 197 °C
Density: 1.292 g/cm³
Water Solubility: Insoluble
Surface Tension: 63 dyne/cm
Enthalpy of Vaporization: 93.69 kJ/mol
Vapour Pressure: 5.73E-16 mmHg at 25°C
XLogP3-AA: 7.8
H-Bond Donor: 2
H-Bond Acceptor: 4
Product Categories: Aminoanthraquinones; Anthraquinones; Solvent Dyestuff

solvent green 3 Uses

Solvent green 3 (CAS NO.128-80-3) is used for adding greenish coloring to materials. It is used in cosmetics and medications. It is used in some colored smoke formulations, in both old and new ones; when inhaled, it clears very slowly from the lung, with half time of 280 days.

solvent green 3 Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	intratracheal	250mg/kg (250mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1330, 1986.
rat	LD50	oral	3660mg/kg (3660mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1330, 1986.

solvent green 3 Safety Profile

Safety Information of Solvent green 3 (CAS NO.128-80-3):
Hazard Codes: Xi
Risk Statements: 36/37/38
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements: 24/25-22-26
22: Do not breathe dust
24: Avoid contact with skin
25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

solvent green 3 Specification

Solvent green 3 ,its CAS NO. is 128-80-3,the synonyms is Sudan green 4b ; Quinizarin green ss ; Quinazarine green base ; Quinizarin green ; Waxoline green g ; 1,4-Bis((4-methylphenyl)amino)-10-anthracenedione ; 1,4-Bis((4-methylphenyl)amino)-9,10-anthracenedione .

Product Name

Solvent Green 3

Synthetic route

solvent green 3 Chemical Properties

solvent green 3 Uses

solvent green 3 Toxicity Data With Reference

solvent green 3 Safety Profile

solvent green 3 Specification

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