[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

Details:

1. Introduction of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) (CAS NO.19978-61-1)

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is one kind of beige powder. The IUPAC Name of this chemical is dichloropalladium;2-diphenylphosphanylethyl(diphenyl)phosphane. Besides, [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) belongs to Metal Compounds; API intermediates; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Pd (Palladium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds; Catalysis and Inorganic Chemistry; Homogeneous Pd Catalysts; Palladium; Catalysts-Ligands; metal-phosphine complexes. [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is insoluble in water.

Our [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is on the purity of 98%～99%. Our Production Capacity is 100 Metric Ton per month. We can send it in 25kg/plastic drum or 200Kg/iron drum by air or by sea from the dongguan port. If you want to buy it, its min order is 1 kilogram. In addition, its price can be 1 USD/Kilogram. We can send them in two days after the order. We can accept the payment such as L/C, D/P, T/T, Westem Unoin, MoneyGram. When comes to store it, please put it in sealed storage in shady and cool warehouse in 20 °C.

2. Basic information of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) (CAS NO.19978-61-1)
1) Properties of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

(1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 7; (4)Exact Mass: 573.976515; (5)MonoIsotopic Mass: 573.976515; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 31; (8)Formal Charge: 0; (9)Complexity: 339; (10)Isotope Atom Count: 0; (11)Defined Atom Stereocenter Count: 0; (12)Undefined Atom Stereocenter Count: 0; (13)Defined Bond Stereocenter Count: 0; (14)Undefined Bond Stereocenter Count: 0; (15)Covalently-Bonded Unit Count: 2.

2) The following information could be converted into the structure:

(1)InChI: InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
(2)InChIKey: LDJXFZUGZASGIW-UHFFFAOYSA-L
(3)Canonical SMILES: C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Pd]Cl

3) Production of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) can be got from the reaction from of K₂PdCl₂ in DMF solution with methylene chloride solution of bis (diphenylphosphino) ethane prepared from, or a phase transfer catalyst Bu4NCl catalyzed by K₂PdCl₂ aqueous solution of bis (diphenylphosphino) ethanechloride solution reaction.

4) Application of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

(1) PdCl₂ (dppe): The main purpose of the carbonylation and double carbonylation reaction between the catalytic halogenated aromatic amine compound.



(2) Halogenated aromatic hydrocarbon with the secondary amine in the PdCl₂ (dppe) catalyzed CO atmosphere can generate α-keto amides and amide compounds.



(3) PdCl₂ (dppe) can be reacted with allyl alcohol, π-allyl palladium complex in the presence of a reducing agent is SnCl₂.



5) Package & Storage of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)

(1) Packing information of [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) could be seen in the following photo information.
(2) This chemical can also be packed according to the customer requirements and packaging specifications.