Diphenylphosphine

Diphenylphosphine

Diphenylphosphine

Min.Order / FOB Price:Get Latest Price

1 Kilogram

FOB Price: USD 1.0000

  • Min.Order :1 Kilogram
  • Purity: 98%~99%
  • Payment Terms : L/C|D/P|T/T|Westem Union|

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Quick Details

  • Appearance:white powder
  • Application:OLED
  • PackAge:25kg/plastic drum
  • ProductionCapacity:100|Metric Ton/Month
  • Storage:sealed storage in shady and cool warehouse in 0℃
  • Transportation:by air or by sea

Superiority:

1. Introduction of Diphenylphosphine (CAS NO.829-85-6) Diphenylphosphine is one kind of white powder. DiphenylphosphineIUPAC Name is Di…

Details:

1. Introduction of Diphenylphosphine (CAS NO.829-85-6)

Diphenylphosphine is one kind of white powder. Diphenylphosphine IUPAC Name is Diphenylphosphane. Diphenylphosphine belongs to Catalysis and Inorganic Chemistry; Phosphorus Compounds; Phosphorus Precursors; organophosphorus ligand; organophosphine ligand. The Solubility of this chemical is insoluble in water. Diphenylphosphine can be used in OLED.

Our Diphenylphosphine can be on the purity of 98%-99% and packaged in 25kg/plastic drum. If you store it, please put it in sealed storage in shady and cool warehouse in 0 °C. If you need, it can be send to you by air or by sea. Its Min. Order is 1Kilogram. Its price is 1-1 USD/Kilogram. We can produce it 100 Metric Ton per month. We can accept the Payment Terms such as L/C, D/P, T/T, Westem Unoin, MoneyGram. Diphenylphosphine can be shipped from dongguan.

2. Basic information of Diphenylphosphine (CAS NO.829-85-6)
1) Properties of Diphenylphosphine

(1)Enthalpy of Vaporization: 49.28 kJ/mol; (2)Boiling Point: 275 °C at 760 mmHg; (3)Vapour Pressure: 0.00875 mmHg at 25 °C; (4)Density: 1.07 g/mL at 25 °C(lit.); (5)Storage temp.: 2-8 °C; (6)Sensitive: Air & Moisture Sensitive; (7)Conformer Sampling RMSD: 0.6; (8)XLogP3-AA: 3; (9)H-Bond Donor: 0; (10)H-Bond Acceptor: 0; (11)Rotatable Bond Count: 2; (12)Exact Mass: 186.059837; (13)MonoIsotopic Mass: 186.059837; (14)Topological Polar Surface Area: 0; (15)Heavy Atom Count: 13; (16)Formal Charge: 0; (17)Complexity: 116; (18)Isotope Atom Count: 0; (19)Defined Atom Stereocenter Count: 0; (20)Undefined Atom Stereocenter Count: 0; (21)Defined Bond Stereocenter Count: 0; (22)Undefined Bond Stereocenter Count: 0; (23)Covalently-Bonded Unit Count: 1; (24)Feature 3D Ring Count: 2; (25)Effective Rotor Count: 2.

2) The following information could be converted into the structure:

(1)Smiles: c1ccccc1Pc1ccccc1
(2)InChI: InChI=1S/C12H11P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H
(3)InChIKey: GPAYUJZHTULNBE-UHFFFAOYSA-N
(4)Canonical SMILES: C1=CC=C(C=C1)PC2=CC=CC=C2

3) Safety information of Diphenylphosphine

Hazard Codes: FlammableF,IrritantXi
Risk Statements: 17-36/37/38 
R17: Spontaneously flammable in air. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing.
RIDADR: UN 2845 4.2/PG 1
WGK Germany: 3
F: 8-10-13-23
HazardClass: 4.2
PackingGroup of Phosphine,diphenyl- (CAS NO.829-85-6): I

4) Production of Diphenylphosphine

Diphenylphosphine can be got from the reaction from the of diphenylphosphine chloride tetrahydro aluminum lithium. The intermediates and the organic phosphorus compound can be prepared Top phosphine ligand.

In addition, Diphenylphosphine can be prepared cheaply from triphenylphosphine. The reaction of it is as follows:

PPh3 + 2 Li → LiPPh2 + LiPh
LiPPh2 + H2O → Ph2PH + LiOH

5) Applications of Diphenylphosphine

Diphenylphosphine is a precursor to organophosphorus ligands for use as catalysts. In the laboratory, diphenylphosphine is a common intermediate. It can be deprotonated to give diphenylphosphide derivatives: Ph2PH + nBuLi → Ph2PLi + nBuH. Diphenylphosphine and especially diphenylphosphide derivatives are nucleophiles, so they add to carbon – heteroatom double bonds. Diphenylphosphine can be used as organic intermediate or catalyst.

6) Package & Storage of Diphenylphosphine

(1) Packing information of Diphenylphosphine could be seen in the following photo information.
(2) This chemical can also be packed according to the customer requirements and packaging specifications.

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